Sediment-water column exchange of persistent organic pollutants (PAH<Subscript>s</Subscript> and PCB<Subscript>s</Subscript>) and their transport vector in El Bey watershed,Tunisia

El Bey river, which drains 60% of the pollutant load of several urban cities in the northeast of Tunisia, provides a good example of the transfer of organic and metallic pollutants that result from industrial and urban activity, and can be used to show how these charges are transported and discharged into the Gulf of Tunis. Persistent organic pollutants (PAH and PCB) in dissolved, particulate matter, bed sediments, and three wastewater effluents in El Bey watershed were analyzed. PAH (∑14PAHs) concentration ranged from 0.248 to 9.955 mg L^?1 and from 0.836 to 28.539 mg L^?1 in dissolved and particulate fraction respectively. The particulate/dissolved partition coefficient value (Kd) was less than one which confirmed the affinity of PAH to be adsorbed. In sediment, the high-molecular weight PAHs were found principally with percentage between 50 and 100% witch present 239.99 to 5362.19 μg kg^?1, which is relatively higher in comparison with other estuaries river. Contrary to PAH patterns, PCB were bound to dissolve fraction. Kd _(PCB) value (Kd?>?1) reflected this affinity which is related to environment energy. The spatial distribution and profile of analyzed organic pollutants confirmed the direct impact of wastewater effluent on the organic pollution level in three compartment of El Bey watershed and his profiles suggested different transport patterns.     

Analysis of pervasive precipitation in similar gradient areas of Iran

Precipitation is a major climatic element with high spatial variations. Temporal and spatial variations may differ in large and small scales. It is, therefore, of utmost importance to study areas with similar gradients in terms of precipitation patterns in order to shed light on the complexities of precipitation variations. In the present study, attempts were made to identify areas with similar gradients experiencing the same precipitation pattern over a 50-year period (1964–2013). To this end, data were collected from synoptic stations in Iran in two phases (i.e., 1434 stations in the first phase and 673 stations in the second one). Alexanderson’s technique was adopted to examine sudden changes in precipitation patterns. The results showed that five regions with similar gradients could be identified in terms of precipitation patterns: negative and high variations, negative and moderate variations, positive and high variations, positive and moderate variations, and little or no variations. The distribution of such regions indicated that the regions with positive trends experienced more annual variations and had further spatial distribution. Furthermore, the findings revealed that the regions with negative precipitation patterns experienced more sudden changes in comparison with those with positive precipitation patterns. Additionally, more variations were observed in the precipitation patterns in recent years.     

Ion chemistry of groundwater and the possible controls within Lhasa River Basin,SW Tibetan Plateau

In order to study the major ion chemistry and controls of groundwater, 65 groundwater samples were collected and their major ions measured from wells within Lhasa River Basin. Groundwater has the characteristics of slightly alkaline and moderate total dissolved solid (TDS). TDS concentration ranged from 122.0 to 489.9 mg/L with a median value of 271.2 mg/L. Almost all the groundwater samples suited for drinking and irrigation. The major cations of groundwater are Ca²⁺ and Mg²⁺, accounting for 59.6 and 31.3% of the cations, respectively. Meanwhile, HCO₃^? and SO₄^2? constituted about 56.7 and 36.9% of the anions, respectively, in Lhasa River Basin. The hydrochemical type of groundwater is HCO₃-SO₄-Ca-Mg. The chemical composition of groundwater samples located in the middle of Gibbs model, which indicates that the major chemical process of groundwater is controlled by rock weathering. Carbonate weathering was the dominant hydro-geochemical process controlling the concentration of major ions in groundwater within Lhasa River Basin, but silicate weathering also plays an important role.     

Mechanical behavior and micro-structure of cement kiln dust-stabilized expensive soil

In this study, the effects of cement kiln dust (CKD) on the swelling properties, strength properties, and microstructures of CKD-stabilized expansive soil were investigated. Samples were prepared and stabilized with different CKD content ratios, ranging from 0 to 18% by dry mass. The results obtained show that the maximum swelling pressures decrease exponentially with increases in CKD content. Both the cohesion and unconfined compressive strength (UCS) increase at ratios below 10% CKD and then decrease slightly, above that ratio. CKD can also improve the strength of saturated, expansive soil. There is no visible change of UCS for soil without CKD when cured, while the UCS of a sample with 10% CKD content after curing for 90 days is higher than that after curing for only 1 day. This indicates that CKD can improve the long-term strength of expansive soil. Finally, microstructure analysis reveals that the addition of CKD reduces the montmorillonite content of expansive soil and decreases its swelling properties. The addition of CKD also changes the pore volume distribution, both the size and amount of macro-pores and micro-pores decrease with increase in CKD content. For saturated samples, the size of macro-pores is obviously reduced, while that of micro-pores is slightly increased for both treated and untreated soils. Hydration and saturation processes make the soil structure become dispersive which results in a lower strength, and adding CKD can restrain this process. The suggested optimal CKD content is between 10 and 14% and with a curing time of more than 27 days.     

Influence of physico-mechanical properties of Indian dimension stones on cutting rate of diamond wire saw

Cutting performance of diamond wire saw is a key factor influencing mine planning, production scheduling, and equipment selection for dimension stone quarries. It is normally measured in terms of cutting rate. Rock samples collected from various granite and marble quarries in India were tested in laboratory to determine their physico-mechanical properties. Cutting rate of diamond wire saw was measured in the field studies during the actual cutting process in quarries. Using these laboratory determined properties and the cutting rate, a multiple linear regression model has been developed to predict the cutting rate of diamond wire saw. Physico-mechanical properties of rocks determined in laboratory are used as independent variables and cutting rate as predictor variable in the regression model. The study indicates that the cutting rate increases with a decrease in most of the hardness and strength parameters of rock. The final model is tested for its goodness of fit indicating a significant linear relation between cutting rate and physico-mechanical properties, namely tensile strength, slake durability index, and Cerchar hardness index with regression coefficient of 94%. The resulting model can be used suitably for different types of hard to medium hard and soft dimension stones. The generalized model for estimating the cutting rate becomes a handy tool for mining engineers to work out operating efficiency, expenses, planning etc. of the dimension stone block cutting.     

Assessment of water inrush risk using the principal component logistic regression model in the Pandao coal mine,China

In order to improve the accuracy of floor water inrush assessment, the risk prediction model of floor water inrush was established by combining the principal component logistic regression analysis (PCLRA) and GIS spatial geographic analysis. In this paper, the geological data of Pandao coal mine was taken as the engineering background. First of all, main controlling factors of floor water inrush were determined and quantified. Next, PCLRA was used to determine the weight of each factor and establish the mathematical model for predicting the floor water inrush. And then, GIS’s spatial analysis and data processing function was used to draw related single factor thematic maps. Related thematic maps were weighted superposed to draw a floor water inrush zoning map based on PCLRA mathematical model. The study areas were divided into five levels by Jenks optimization method and vulnerability index initial model. And the corresponding threshold range was determined. The results show that (1) the high sensitivity factors in floor failure depth were added to evaluate the water inrush, and the fault fractal dimension was used to replace the fault structure related factors, and the main controlling factors of floor water inrush are more comprehensive; (2) the fitting degree of PCLRA model is high and the test accuracy is 83.3%; (3) the prediction results were well fitted to the actual position of water inrush (three water inrush points are located in the dangerous area, and two water inrush points are located in the relatively dangerous area).     

A direction-dependent shear strength criterion for rock joints with two new roughness parameters

The surface morphology of a rock joint is closely related to its mechanical properties. To reasonably characterize a rock surface, two new roughness parameters were proposed in this paper. One is related to the average slope angle of asperities that contribute to the shear strength, and the other reflects the frictional behavior of asperities that is defined as the maximum possible contact area in the shear direction. Taking the standard joint roughness coefficient profiles as example, these two roughness parameters can be applied to describe the directional characteristics of shear strength. Based on their relationships with initial dilation angles, the proposed roughness parameters were incorporated into a peak shear strength criterion. It is shown that the predicted peak shear strength is consistent with experimental data, and there is a power–law relationship. The application range of new roughness parameters was determined, which may facilitate a measurement process.     

Tectono-geomorphic development of intra-continental Cenozoic depressions within Cretaceous rocks of the Interior Homocline,Central Arabia

Intra-continental depressions occurred in Central Arabia, within the evaporite-bearing Sulaiy Formation, and extends for over 550 km along N-S arcuate belt, passing through eastern Ar Riyadh, Saudi Arabia. They mark Jurassic/Cretaceous contact within the Interior Homocline of Central Arabia, accommodating Neogene and Quaternary deposits. Two en echelon major depressional areas were discovered, the northern major depressional area and the southern major depressional area. The first depressional area occurs between Al Artawiyah and Ad Dilam towns, following the arcuate Jurassic/Cretaceous contact. It contains five depressions: N-S Al Artwaiyah depression; NW-SE Ath Thumamah depression, northeast of Riyadh; NW-SE Jinadriyah depression, east of Riyadh; E-W Al Kharj depression; and N-S Ad Dilam depression. All five depressions seems to be formed by tectonic and subsequent geomorphic events, except for Al Artawiyah and Jinadriyah depression, which developed mainly by tectonic events. Southern major depressional area steps over to southwest of Ad Dilam, and occurs from Hawtat bani tamim to Layla towns. This Hawtah-Layla major depression trends N-S, and Cretaceous units strike NNE, which is a slightly oblique relationship, suggesting expression of deep-seated structures. Tectonic features were part of the Alpine-Himalayan orogeny, developing during Eocene. They followed by a geomorphic event (karsts and subsequent collapse) that took place during Mid Pleistocene. Ad Dilam depression is a surface expression of three oil and gas fields, while the southern major depression between Hawtat Bani Tamim and Layla towns is a surface expression of four oil and gas fields. Yet, other several depressional areas are also accommodating Quaternary desert sediments, and they contain economic resources, which therefore, worth further detailed studies.     

Gold deposits associated with the gabbroic rocks at Tirek area,western Hoggar,Algeria: fluid inclusion study

The Tirek gold deposit hosted in the Archean shield is one of the richest sources of mined gold for Algeria. The deposit is controlled by the East Ouzzal shear zone (EOSZ), a transcurrent N–S lithospheric fault. The EOSZ is a late Pan-African dextral-ductile shear zone separating two contrasting Precambrian domains: the Archean In Ouzzal block to the west (Orthogenesis with subordinate metasediments reworked and granulitized during the ca. 2 Ga Eburnean event) and a middle Proterozoic block to the east involved in the ca. 600 Ma Pan-African event. The auriferous quartz veins are mainly oriented in two directions, N–S veins hosted in mylonitic rocks and NE–SW veins hosted in gabbroic or gneissic bands. The NE–SW veins contain the richest ore. Gold ore is found in a system of veins and lenticular quartz veinlets arranged in anastomosing networks. The hydrothermal alteration associated with these veins is characteristically a carbonate-sericite-albite-pyrite assemblage. Gold is the main metal of economic importance; it is disseminated in the quartz as grains or fibers along microcracks and as microscopic grains in the host rocks. Microthermometric results and Raman laser data from fluid inclusions demonstrate that the ore-forming fluids contained H₂O-CO₂±CH₄ and were low salinity. Homogenization temperatures are commonly 250–310 °C. In the Tirek deposit, the role of the shear zone that hosts the mineralization was to drain the hydrothermal fluid. Interactions between the fluid and the mafic host rocks and CO₂ also contributed to the formation of the hydrothermal gold deposit at Tirek.