Reef development on a deepening platform: two Early Cretaceous coralgal patch reefs (Catí, Llàcova Formation, eastern Spain) compared

Two coralgal patch reefs of the Hauterivian Llàcova Formation (Maestrat Basin, eastern Spain), exposed at two consecutive stratigraphic levels within a single section, have been studied to document taxonomic implications of a changing environment. These two reefal palaeocommunities differ substantially in coral taxonomic composition, microbialite formation pattern and in abundance and composition of encrusters and bioeroders. Of a total of 14 coral species, just one (Stylina parvistella) occurs in both reefs, yet is abundant in the (lower) reef A and rare, occurring near the reef base, in the reef B assemblage. Reef A is dominated by a phototrophic fauna and coral species with small corallites and imperforate septa (a stylinid-thamnasteriid-heterocoeniid-actinastreid association), along with an encruster association dominated by Bacinella and Lithocodium. Reef B is characterised by a balanced phototrophic-heterotrophic fauna that gradually passes into a heterotrophic-dominated assemblage. During this latest growth stage, microsolenid corals dominated the assemblage. The encruster fauna is characterised by sponges, polychaetes and bryozoans. Moderate deepening during a transgressive systems tract (TST) depositional sequence and elevated nutrient supply are interpreted to represent the driving environmental parameters that caused faunal compositions to differ between these two reefal palaeocommunities. Nine coral taxa, previously known only from younger (Barremian–Cenomanian) strata, have been identified, namely Dimorphocoenia? rudis, Eocomoseris raueni, Eocomoseris sp., Holocoenia jaccardi, Latusastrea irregularis, Mesomorpha sp., Microsolena kugleri, Polyphylloseris mammillata and Polyphylloseris sp. This observation emphasises the importance of the Hauterivian Stage as a period of evolutionary transition in Late Jurassic–Cretaceous coral faunas.     

Anaerobic ammonium oxidation by nitrite (anammox): Implications for N2 production in coastal marine sediments

The respiratory reduction of nitrate (denitrification) is acknowledged as the most important process that converts biologically available nitrogen to gaseous dinitrogen (N₂) in marine ecosystems. Recent findings, however, indicate that anaerobic ammonium oxidation by nitrite (anammox) may be an important pathway for N₂ formation and N removal in coastal marine sediments and in anoxic water columns of the oceans. In the present study, we explored this novel mechanism during N mineralization by ¹⁵N amendments (single and coupled additions of ¹⁵NH₄⁺, ¹⁴NO₃⁻ and ¹⁵NO₃⁻) to surface sediments with a wide range of characteristics and overall reactivity. Patterns of ^29/30N₂ production in the pore water during closed sediment incubations demonstrated anammox at all 7 of the investigated sites. Stoichiometric calculations revealed that 4% to 79% of total N₂ production was due to this novel route. The relative importance of anammox for N₂ release was inversely correlated with remineralized solute production, benthic O₂ consumption, and surface sediment Chl a. The observed correlations indicate competition between reductants for pore water nitrite during early diagenesis and that additional factors (e.g. availability of Mn-oxides), superimposed on overall patterns of diagenetic activity, are important for determining absolute and relative rates of anammox in coastal marine sediments.     

Scaled amplification equation: A key to the folding history of buckled viscous single-layers

The presented equation describes amplitude growth during viscous single-layer folding (buckling) up to high amplitudes. The equation relates the dimensionless fold amplitude (i.e. ratio of amplitude to wavelength) to the stretch (ratio of initial wavelength to instantaneous wavelength) for given values of the viscosity contrast between layer and surrounding material and the initial ratio of amplitude to wavelength. The amplification equation is suitably scaled so that all amplitude versus stretch curves for different values of viscosity contrasts and initial amplitudes fall onto essentially a single curve. The scaled amplification equation allows for representing fold amplification of viscous single-layers by a singular curve. The scaling parameter is the crossover strain, which is an estimate for the amount of strain that is accumulated during the initial stages of folding where the amplitude grows exponentially with strain. The singular curve allows quantifying the universal boundaries between the three folding stages, namely nucleation, amplification and kinematic growth. The scaled amplification equation is verified by numerical (finite element method) simulations of folding of single layers with initial random perturbations of the layer interfaces. The amplification equation describes the amplification of single folds within fold trains successfully, although the folds are neither regular nor periodic and vary considerably in shape. The easily measurable parameters, vertical and horizontal hinge distance, are shown to be good approximations for the analytical parameters amplitude and wavelength, respectively.     

Soil and groundwater pollution of an urban catchment by trace metals: case study of the Addis Ababa region, central Ethiopia

Analysis of the total heavy metal (Cr, Cd, Pb, As, Cu, Ni, Zn, Co) concentration was performed on 33 soil samples taken from different profiles and soil types in a highly urbanized and industrial sector of Addis Ababa, central Ethiopia. They were analyzed using aqua regia extraction coupled with a four-stage sequential extraction (SE) procedure. The objectives of the analysis were to investigate the degree of soil heavy metal contamination, its binding forms, mobility and the implications for the groundwater resource. The results show a relatively high content of the analyzed trace metals in the soil attributed to anthropogenic and geogenic sources. Although most of the trace metals are found in the upper few centimeters of the residual soils, because of churning processes within the black cotton soils, vertical distribution of the trace metals is complex. According to the heavy metal SE analysis, the major heavy metal contribution is from the residual followed by the hydroxide phases. Groundwater heavy metal contamination is present with more than 90 and 50% of the analyzed groundwater samples exceeding WHO guidelines for Cr and Cd, respectively. Since the degree of soil heavy metal contamination has apparently not surpassed the soil’s buffering capacity, it appears that the transport path of these toxic metals to the groundwater is through fractures, joints, and related preferential flow paths.     

Remote Sensing Methods to Investigate Boundary-layer Structures relevant to Air Pollution in Cities

Simultaneous surface-based remote sensing with optical (Ceilometer) and acoustic (Sodar) methods allows the diurnal variation of the structure of the atmospheric boundary layer to be deduced with high temporal resolution. Primarily the convective boundary layer, the nocturnal stable surface layer, and the residual layer can be identified from the measured vertical profiles of aerosol concentration and thermal fluctuations. The ability of the two remote sensing techniques is shown in different examples from two different locations and two seasons. The impact on urban air quality assessment is addressed.     

Beach Comfort Index – a new approach to evaluate the thermal conditions of beach holiday resorts using a South African example

The climatic conditions of seven beach holiday resorts in South Africa (Alexander Bay, Cape Town, George, Port Elizabeth, East London, Durban and Richard's Bay) have been examined with regard to the thermal perception of beach holiday makers. The evaluation of the thermal conditions is based on the human energy balance calculations which have been adapted to the requirements of beach goers. A model has been developed to calculate the missing radiation input data and parameters such as ‘beach day’ and ‘beach hour’ are introduced and defined. The average monthly number of beach days is calculated for every location showing the highest amounts in Durban and Richard's Bay and the highest annual variations in Cape Town. The Beach Comfort Index Map of South Africa shows the maximum, minimum and average number of beach days per month and the probability of beach days and thus providing understandable and interpretable information on the thermal conditions of the sites from the point of view of beach holiday makers. This revised version was published online in July 2006 with corrections to the Cover Date.     

Irrigation in Bulgaria

Agriculture in Bulgaria entered a severe crisis in 1989 following the collapse of the central planning system. Since then it has been going through a transition towards market-based system and a structural transformation from large state cooperatives to smaller privately owned and operated farms and cooperatives. Irrigation, a major water use until recently, has been strongly affected by these processss, and has dropped to a point where less than 15% of the areas equipped for irrigation are actually irrigated. Heavy state investments in the irrigation subsector and its vital importance for the economy make it imperative to up-grade and restructure irrigated agriculture to reflect new forms of land ownership and farming, as well as the current and future organizational patterns of the