Spatial patterns of groundwater‐lake exchange – implications for acid neutralization processes in an acid mine lake

Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m^‐2 d^‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m^‐2 d^‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g^‐1 d^‐1) compared to alternating sites (<220 nmol g^‐1 d^‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.     

The impact of uncertain emission trading markets on interactive resource planning processes and international emission trading experiments

Interactive resource planning is an increasingly important aspect of emission trading markets. The conferences of Rio de Janeiro, 1992, and Kyoto, 1997, originally focusing on environmental protection at both macro- and micro-economic levels, called for new economic instruments of this kind. An important economic tool in this area is Joint Implementation (JI), defined in Article 6 of the Kyoto Protocol. Sustainable development can be guaranteed only if JI is embedded in optimal energy management. In this contribution we describe and evaluate one international procedure within uncertain markets which helps to establish optimal energy management and interactive resource planning processes within uncertain emission trading markets.     

North Atlantic climate impact on early late‐glacial climate oscillations in the south‐eastern Alps inferred from a multi‐proxy lake sediment record

High‐resolution multi‐proxy analyses of a sediment core section from Lake Jeserzersee (Saissersee) in the piedmont lobe of the Würmian Drau glacier (Carinthia, Austria) reveal pronounced climatic oscillations during the early late glacial (ca. 18.5–16.0k cal a BP). Diatom‐inferred epilimnetic summer water temperatures show a close correspondence with temperature reconstructions from the adjacent Lake Längsee record and, on a hemispheric scale, with fluctuations of ice‐rafted debris in the North Atlantic. This suggests that North Atlantic climate triggered summer climate variability in the Alps during the early late glacial. The expansion of pine (mainly dwarf pine) between ca. 18.5 and 18.1k cal a BP indicates warming during the so‐called ‘Längsee oscillation’. The subsequent stepwise climate deterioration between ca. 18.1 and 17.6k cal a BP culminated in a tripartite cold period between ca. 17.6 and 16.9k cal a BP with diatom‐inferred summer water temperatures 8.5–10 °C below modern values and a shift from wet to dry conditions. This period probably coincides with a major Alpine glacier advance termed the Gschnitz stadial. A warmer interval between ca. 16.9 and 16.4k cal a BP separates this cold phase from a second, shorter and less pronounced cold phase between ca. 16.4 and 16.0k cal a BP, which is thought to correlate with the Clavadel/Senders glacier advance in the Alps. The following temperature increase, coupled with wet (probably snow‐rich) conditions, caused the expansion of birch during the transition period to the late glacial interstadial. Copyright © 2011 John Wiley & Sons, Ltd.     

How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.     

Winter precipitation variability and large-scale circulation patterns in Romania

Summary The spatial and temporal variability of winter precipitation and its links to the large-scale atmospheric circulation patterns in Romania are examined. The data set is composed of observed rainfall at 30 meteorological stations during the 1961–1996 period. The large-scale field is represented by the observed geopotential height at 500 hPa (Z500) over the same period, covering the latitudinal belt between 20° N–90° N (resolution 2.5°×2.5°).The Standard Normal Homogeneity Test (SNHT) is applied to detect inhomogeneities in the data, and the Mann-Kendall and Pettitt non-parametric tests are used in order to identify trends and change points in the winter precipitation time series. The empirical orthogonal functions (EOF) technique is used for data reduction in order to highlight the basic patterns of rainfall variability in Romania. The covariance map between precipitation EOF time series (PCs) and the Z500 field, as well as the correlation coefficients between the PCs and circulation indices are calculated in order to identify the influence of large-scale circulation patterns on winter precipitation in Romania.A significant decreasing trend is identified in winter precipitation with a downward shift in winter 1969/1970, most significant from a statistical point of view in the extra-Carpathian region. This change seems to be real since the SNHT test does not reveal any inhomogeneity during the period tested. Significant relationships are found between winter precipitation variability in Romania and the large-scale circulation pattern, such as the North Atlantic Oscillation and the blocking phenomenon in the Atlantic-European sector. The positive phase of the NAO and the reduction in blocking activity could be one of the causes of the decrease in winter precipitation in Romania.     

An Approach for Classification of Groundwaters by Synchronous Fluorescence Spectroscopy and Discriminant Analysis

Monitoring and evaluation of groundwater quality in drinking water protectorates is of particular interest if the uncontrolled entry of pollutants, for example by infiltrating river water, cannot be excluded. A fluorescence spectroscopic method is presented as possible alternative to the conventional expensive hydrochemical investigations. This method uses the information yielded by synchronous fluorescence spectra. After a Fourier transformation of the original spectra and a following discriminant analysis, the samples can be classified in different groups corresponding to the different types of groundwater. The method was tested in the drinking water protectorate of a waterworks of a German metropolis (Halle, Sachsen-Anhalt). We found a prediction rate of about 90% in the investigated case.     

Alpen: Verkehr und fremdenverkehr

Alpen: Verkehr und fremdenverkehr     

On the energy content of the atmosphere

Summary Vertical profiles of the content of sensible heat, potential energy, and latent heat in the atmosphere between 1000 and 100 mb, during January and July, are derived for the latitude circles 0, 10, 20, 30, 40, 50, and 60°N. Contrasts between oceans and continents are found to vary significantly with latitude and season.

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Zusammenfassung Vertikalprofile des Gehalts an fühlbarer Wärme, potentieller Energie und latenter Wärme in der Atmosphäre zwischen 1000 and 100 mb werden für Januar und Juli und die Breitenkreise 0, 10, 20, 30, 40, 50, und 60°N abgeleitet. Gegensätze zwischen Land und See ändern sich mit geographischer Breite und Jahreszeit.

     

Big Earth data: disruptive changes in Earth observation data management and analysis?

ABSTRACT

Turning Earth observation (EO) data consistently and systematically into valuable global information layers is an ongoing challenge for the EO community. Recently, the term ‘big Earth data’ emerged to describe massive EO datasets that confronts analysts and their traditional workflows with a range of challenges. We argue that the altered circumstances must be actively intercepted by an evolution of EO to revolutionise their application in various domains. The disruptive element is that analysts and end-users increasingly rely on Web-based workflows. In this contribution we study selected systems and portals, put them in the context of challenges and opportunities and highlight selected shortcomings and possible future developments that we consider relevant for the imminent uptake of big Earth data.