Table of Contents

Table of Contents

Table of Contents     

On the insignificance of aluminium-borate complexes in aqueous solution

The strength of complexation in the system H⁺Al³⁺B(OH)₃ has been studied. It is shown, on the basis of three independent types of measurement (H⁺ potentiometry, ²⁷Al NMR and ¹¹B NMR), that no, or at least very weak, aluminium-borate complexes form. An apparent solubility for freshly precipitated Al(OH)₃(s) is reported.     

Comparison Between Eddy-Correlation and Inertial Dissipation Methods in the Marine Atmospheric Surface Layer

A comparison of momentum fluxes determined by the eddy-correlation method(ECM) and the inertial dissipation method (IDM) has been performed using longterm measurements over the sea. The measurements were made on the island ofÖstergarnsholm in the middle of the Baltic Sea. The results show that a`classical' form of the inertial dissipation method, i.e., assuming that the transportterms are negligible, and using an effective value for the Kolmogorov constant of0.55, can be used with a mean relative difference between the two methods of about15% for -1 < z/L < 0.5 (z being height and L the Obukhov length). The IDMmethod works best for high wind speeds and neutral conditions. For low windspeeds (U < 6 m s^-1) the relation between the two methods is morecomplex. IDM then gives higher values than ECM on the average (about 20%),especially for swell conditions, indicating the need for an imbalance function inthe turbulent kinetic energy budget. Calculations of the effective Kolmogorovconstant, _a, suggest a dependence upon the wave age, _a increasing with increasing wave age, where the value 0.59 fits the data well for saturated waves.     

On the Stability of the <Emphasis Type="Italic">AlOSi</Emphasis>(<Emphasis Type="Italic">OH</Emphasis>)<Stack><Subscript>3</Subscript><Superscript>2+</Superscript></Stack> Complex in Aqueous Solution

Summary The complexation of aluminium(III) and silicon(IV) was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25 °C. The measurements were performed as potentiometric titrations using a hydrogen electrode with OH ⁻ ions being generated coulometrically. The total concentrations of Si(IV) and Al(III) respectively [Si _tot ] and [Al _t ot], and −log[H ⁺] were varied within the limits 0.3 < [Si _tot ] < 2.5 mM, 0.5 < [Al _tot ] < 2.6 mM, and 2 ≤ -log[H ⁺] ≤ 4.2. Within these ranges of concentration, evidence is given for the formation of an AlSiO(OH) ₃ ²⁺ complex with a formation constant log β_1,1-1 = −2.75 ± 0.1 defined by the reaction Al ³⁺+Si (OH)₄ ↔ AlOSi(OH) ₃ ²⁺ +H ⁺ An extrapolation of this value to I=0 gives log β_1,1-1 = −2.30. The calculated value of log K (Al ³⁺+SiO(OH) ₃ ⁻ ↔ AlOSi(OH) ₃ ²⁺ ) = 6.72 (I=0.6 M) can be compared with corresponding constants for the formation of AlF ²⁺ and AlOH ²⁺ , which are equal to 6.16 and 8.20. Obviously, the stability of these Al(III) complexes decreases within the series OH ⁻>SiO(OH) ₃ ⁻  > F ⁻     

Seasonal and interannual variability of the air–sea CO2 flux in the Atlantic sector of the Barents Sea

The seasonal and interannual variability of the air–sea CO₂ flux (F) in the Atlantic sector of the Barents Sea have been investigated. Data for seawater fugacity of CO₂ (fCO₂^sw) acquired during five cruises in the region were used to identify and validate an empirical procedure to compute fCO₂^sw from phosphate (PO₄), seawater temperature (T), and salinity (S). This procedure was then applied to time series data of T, S, and PO₄ collected in the Barents Sea Opening during the period 1990–1999, and the resulting fCO₂^sw estimates were combined with data for the atmospheric mole fraction of CO₂, sea level pressure, and wind speed to evaluate F.The results show that the Atlantic sector of the Barents Sea is an annual sink of atmospheric CO₂. The monthly mean uptake increases nearly monotonically from 0.101 mol C m^− 2 in midwinter to 0.656 mol C m^− 2 in midfall before it gradually decreases to the winter value. Interannual variability in the monthly mean flux was evaluated for the winter, summer, and fall seasons and was found to be ± 0.071 mol C m^− 2 month^− 1. The variability is controlled mainly through combined variation of fCO₂^sw and wind speed. The annual mean uptake of atmospheric CO₂ in the region was estimated to 4.27 ± 0.68 mol C m^− 2.     

A Note on Velocity Spectra in the Marine Boundary Layer

Spectra of longitudinal and vertical velocity have been studied at a marine site, östergarnsholm, in the Baltic Sea during a period of six days with near-neutral or slightly unstable conditions, when the wave state gradually changed from pure wind sea to strong swell having approximately the same direction as the wind. During the pure wind sea phase, spectra are shown to adhere closely to general forms for the neutral atmospheric surface layer obtained from a new theory. As soon as the wave age goes slightly beyond that representative of pure wind sea conditions, the spectra deviate in shape from the ideal forms. The spectral modification appears to start at a frequency typical of the swell component. As the wave age increases, it progresses in frequency as a downscale cascade, which is particularly prominent in the spectrum of the vertical component but which is also observed in the longitudinal component. In addition, there is a strong effect in the low-frequency part of the spectra. It is interpreted as an indirect effect of large-scale inactive turbulence, which becomes progressively more important as wave-age increases. It is found that the ratio of the spectrum of the vertical component and the spectrum of the corresponding longitudinal component attains the theoretically predicted value of 4/3 for cases of developing sea (gale force wind) for frequencies above approximately 4 Hz but never much exceeds unity for cases with swell. It is argued that this is an indication of local anisotropy and that the inertial-dissipation method for determination of the momentum flux is inappropriate in the case of mixed seas or swell.     

Organic Geochemical Microanalysis by Time‐of‐Flight Secondary Ion Mass Spectrometry (ToF‐SIMS)

Time‐of‐flight secondary ion mass spectrometry (ToF‐SIMS) is a powerful method for the chemical analysis of solid surfaces. In this paper, the capabilities and limitations of this technique and the potential for its use in geochemical research are outlined. Using ToF‐SIMS, the chemical composition of sample structures down to 10–100 μm can be determined, without the need for pre‐selection or labelling of the analysed substances. In addition, the lateral distribution of organic and inorganic compounds can be mapped in geochemical samples at a resolution in the micrometre range. The capabilities of the technique in geochemistry are illustrated by two examples. In the first example, it is shown that ToF‐SIMS can be used to detect biomarkers in oil samples, making it a promising method for the analysis of biomarkers in fluid inclusions. In the second example, a number of specific lipid biomarkers were identified and mapped on the surface of a microbial mat cryosection surface. Post‐measurement optical microscopy correlated the localisation of the lipids with the presence of methanotrophic archaea in the microbial mat.     

The influence of experimental design on the rate of calcite dissolution

A rotating disc system has been constructed to study calcite dissolution kinetics. The disc system is shown to obey the Levich theory and to satisfy the stringent chemical controls required by the calcite dissolution system at neutral to alkaline pH values. The errors involved in using a CO₂-free atmosphere are shown to be insignificant. It is shown that the stirring dependence of systems which are not hydrodynamically well-defined is variable and dependent on the shape of the reaction vessel. Extrapolation of such results into natural systems involves very large uncertainties.     

Governing Large Carnivores—Comparative Insights from Three Different Countries

The governance of large carnivores is often surrounded by conflicts. Along with the difficulties of governing large carnivores through centralized, top-down governing and a general shift towards participatory approaches in natural resource governance, this has led many countries to establish various collaborative measures in large carnivore governance – often presented as a catch-all solution to problems of legitimacy, democratic deficit and effectiveness. However, the field of large carnivore governance currently lacks a coherent understanding of strengths and weaknesses of different kinds of collaborative arrangements. In this paper, we address this knowledge gap. Using the framework of modes of governance to categorize and compare the governance of large carnivores in Norway, Sweden and Finland, we discuss the potential and limitations of various governance modes and identify gaps in contemporary research literature. The main conclusion is that all three governance systems need to incorporate more interactive governance elements.