Compression and coordination changes in pyroxenoids: an EXAFS study of MgGeO3 enstatite and CaGeO3 wollastonite

The evolution of the distortion of MgGeO₃ enstatite and CaGeO₃ wollastonite with increasing pressure, has been investigated using X-ray absorption spectroscopy (XAS) in a diamond anvil cell. At room temperature and low pressure (P<7 GPa), the compressibility of the GeO₄ tetrahedron is higher in MgGeO₃ enstatite (K _[GeO4]∼135 GPa) than in CaGeO₃ wollastonite (K _[GeO4]≥ 280 GPa). The compression mechanisms of the two compounds are different: the whole mineral compressibility of Ge-enstatite appears to be very homogeneous, in contrast to that of Ge-wollastonite which exhibits an inhomogeneous tretrahedral compressibility. This result is consistent with the variation of the Debye-Waller factors of the two compounds with increasing pressure. At higher pressures, the coordination of germanium atoms in the two compounds gradually changes from fourfold to sixfold. For CaGeO₃ the coordination change starts at 7 GPa and is complete a 12 GPa, whereas it starts at about 8.5 GPa for MgGeO₃ and is not complete at 31 GPa. The progressive evolution of the measured Ge-O distances as well as the modification in the X-ray absorption near-edge structure indicate two coexisting different sites rather than a progressive site modification. The transformation is found to be partially reversible in CaGeO₃ wollastonite, whereas it is totally reversible in MgGeO₃ enstatite.     

Assessment of loess as parent material for agroecological potential

Due to its physical and chemical properties, areas with a loess mantle of proper thickness favour arable farming. Loess as a parent material promotes the formation of soils of good structure, nutrient supply and water budget. The ongoing land evaluation project places particular emphasis on the consideration of parent material in its scoring system as soil and climatic parameters are assessed in conjunction with the grain size composition of subsurface material and soil texture.A test area most suitable for the presentation of the method seems to be a sandy alluvial fan with loess mantle and this circumstance allows the contrasting of the agroecological potentials of soils developed on the two parent materials of different nature.The favourable water storage properties of loess make this deposit particularly valuable under the conditions of climatic aridification. The geographical information system applied here is capable of simulating the agroecological potential changes caused by reduced precipitation, increased evaporation and dropping groundwater levels.The research for this paper was carried out as part of the MEDALUS II (Mediterranean Desertification and Land Use) collaborative research project. MEDALUS II was funded by the EC under its Environment Progamme, contract no. EV5V 0128/0166. A grant was also provided by the OTKA (Hungarian National Science Foundation), project no 1278. The support is gratefully acknowledged.     

The role of principles and methods in loess-paleosol investigations

In the process of loessification, the development of loess fabric, the role of zonal, regional and partly of local environmental factors is regarded decisive. In the loess sequences various genetic types of loess pockets and paleosols occur and reflect different climatic and paleogeographical conditions.As a consequence, even within a single profile the colour, grain size and mineral composition, CaCO₃ content, degree of weathering and fabric of loess may vary. Zonal, regional or even local variations in such loess properties may equally derive from syngenetic or postgenetic processes. For similar reasons, spatially and temporally different forms, types and subtypes of paleosol also developed.This way, loess and soil formation resulted in various spatial types in the same glacial, interstadial or interglacial phase in the various geographical zones and regions. Although there exist major loess regions where the interglacial soils (eg brown forest soils) are markedly distinct from interstadial steppe soils or from other types of humic soils, continental loess areas can also be observed where the paleosols developed under interglacial and interstadial conditions (eg steppe or forest steppe soils) cannot be referred into different genetic types. In such cases the changes in paleoenvironments are difficult and uncertain to reconstruct.The interregional correlation of paleosols is occasionally hindered by the various terminologies applied to denote them. In addition, there are uncertainties concerning the dating and identification of paleoenvironments of polygenetic soils and of soil complexes consisting of paleosol units: how many soil formation phases they represent and how long erosional gaps can be reckoned with between these phases.     

The Sudbury Structure (Ontario,Canada): a tectonically deformed multi-ring impact basin

The occurrence of shock metamorphic features substantiates an impact origin for the 1.85 Ga old Sudbury Structure, but this has not been universally accepted. Recent improvements in knowledge of large-scale impact processes, combined with new petrographic, geochemical, geophysical (LITHOPROBE) and structural data, allow the Sudbury Structure to be interpreted as a multi-ring impact structure. The structure consists of the following lithologies: Sudbury Breccia —dike breccias occurring up to 80 km from the Sudbury Igneous Complex (SIC); Footwall rocks and Footwall Breccia — brecciated, shocked crater floor materials, in part thermally metamorphosed by the overlying SIC; Sublayer and Offset Dikes, Main Mass of the SIC and Basal Member of the Onaping Formation (OF) — geochemically heterogeneous coherent impact melt complex ranging from inclusion-rich basal unit through a dominantly inclusion-free to a capping inclusion-rich impact melt rock; Grey Member of OF — melt-rich impact breccia (suevite); Green Member of OF — thin layer of fall back ejecta; Black Member of OF — reworked and redeposited breccia material; Onwatin and Chelmsford Formations — post-impact sediments. Observational and analytical data support an integrated step-by-step impact model for the genesis of these units. Analysis of the present spatial distribution of various impact-related lithologies and shock metamorphic effects result in an estimated original rim-to-rim diameter of the final crater of 200 or even 280 km for the Sudbury Structure, prior to tectonic thrusting and deformation during the Penokean orogeny.     

Long-term change in precipitation in southern Italy

Summary Annual average precipitation values obtained at 765 Italian raingauge stations south of the Rome parallel and in the Italian Isles, are analyzed. The analysis is extended over 18 years and marked variations in precipitation with the Zürich annual relative sunspot numbers are found. It is found furthermore that the magnitude of change appears to depend also on the average altitude of the 5 categories of stations considered.

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Riassunto In questo articolo viene fatta un'analisi sulle variazioni delle precipitazioni medie annue in base ai dati forniti da 765 stazioni pluviometriche dell'Italia meridionale, Sicilia e Sardegna, negli anni dal 1926 al 1943 incluso. Tali variazioni sembrano essere legate al numero medio annuo di macchie solari e dipendono anche dall'altezza delle stazioni.

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Contribution of the Centro Nucleazione Aerosoli of the National Research Council of Italy; Via Vettore 4 (Monte Sacro)     

On the chemical composition of atmospheric aerosols — Part III: Trends of the total annual precipitation with respect to the chemical content of rainwater over the United States

Summary Following a recent hypothesis on the role of activated sodium chloride particles as potential nuclei of atmospheric precipitation, further analysis is made of average annual data due toC. Junge on the chemical composition of rainwater salts, and correlation of some parameters with the total amount of rainfall is attempted. It is found that the results obtained are in agreement with the proposed role of activated sodium chloride as a nucleus of a substantial part of the atmospheric precipitation.     

Variability of annual precipitation in Sweden

Summary Different measures of variability of precipitation are discussed and it is concluded that it is preferable to apply therelative intersequential variability in cases when overall trends are feared in the records. 127 stations in Sweden have been studied for the period 1901–1950 as to the relative interannual variability of precipitation. For a selection of these stations other measures have also been calculated and a comparison has been made between the coefficient of variation and the intersequential variability. As the relation between these measures varies with the existence of serial correlations in the records the serial correlation coefficient for a lag of one element has been calculated. The value of the coefficient has indicated the existence of trends in certain areas of Sweden generally in agreement with earlier investigations byÅngström.The geographical distribution of the relative interannual variability in Sweden is discussed and also the distribution of anomalies of relative variability compared with the world's normal curve completed byConrad. It is shown that the relationship between relative variability and precipitation amount for Swedish stations can be expressed by a hyperbolic function deviating fromConrad's world normal curve only by an additive constant.

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Zusammenfassung Der Verfasser erörtert verschiedene Maße für die Variabilität des Niederschlages und kommt zu der Feststellung, daß in den Fällen, in denen eine einseitige Tendenz in den Beobachtungsreihen zu befürchten ist, die Verwendung derrelativen reiheninternen Variabilität am geeignetsten ist. 127 Stationen in Schweden sind für die Periode 1901–1950 im Hinblick auf die relative interannuelle Variabilität des Niederschlags untersucht worden. Für eine Auswahl dieser Stationen wurden auch andere Maße berechnet und der Schwankungskoeffizient mit der reiheninternen Variabilität verglichen. Da die Beziehung zwischen diesen Maßen mit dem Auftreten von Serienkorrelationen in der Beobachtungsreihe variiert, wurde der Serienkorrelationskoeffizient für eine Verschiebung eines Elements berechnet. Die erhaltenen Werte des Koeffizienten deuten auf das Vorhandensein gesetzmäßiger Tendenzen in gewissen Gebieten Schwedens hin und stehen im allgemeinen in guter Übereinstimmung mit älteren Untersuchungen vonÅngström.Die geographische Verteilung der relativen interannuellen Variabilität in Schweden sowie die Verteilung der Anomalien der relativen Variabilität, verglichen mit der vonConrad aufgestellten Weltnormalkurve, werden erörtert. Schlie\lich wird gezeigt, daß es möglich ist, den Zusammenhang zwischen relativer Variabilität und Niederschlagsmenge für schwedische Stationen durch eine hyperbolische Funktion zu beschreiben, die vonConrads Weltnormalkurve nur durch eine additive Konstante abweicht.

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Résumé L'auteur mentionne différentes mesures de la variabilité des précipitations et conclut qu'il est préférable d'appliquer la variabilité relative interséquentielle lorsqu'une tendance unilatérale des séries d'observations est à craindre. Il a étudié la variabilité relative interannuelle des précipitations pour 127 stations suédoises (1901/50) ainsi que d'autres mesures de variabilité pour un choix restreint de stations et il a comparé le coefficient de variation à la variabilité relative interséquentielle. Comme la relation entre ces mesures varie avec l'existence de corrélations de série dans les séries d'observations, le coefficient de corrélation de série a été calculé pour un déplacement d'un terme; la valeur de ce coefficient indique l'existence de tendances générales dans certaines régions de Suède, ce qui confirme les résultats anciens deÅngström.La distribution géographique de la variabilité relative interannuelle en Suède ainsi que celle des anomalies de la variation relative comparée à la courbe normale mondiale dressée parConrad fait l'objet d'un examen. Enfin on montre qu'il est possible d'exprimer la relation entre la variabilité relative et la quantité de précipitations en Suède par une fonction hyperbolique qui ne diffère de la courbe normale deConrad que par une constante additive.

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With 5 Figures

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Dedicated to Dr.Anders K. Ångström on the occasion of his 70th birthday.     

L'analogie des moyennes mensuelles du niveau de la Méditerranée

Résumé Dans l'article est examinée la question de l'analogie du niveau moyen mensuel de la mer pour un nombre de stations marégraphiques sur les côtes italiennes ct françaises de la Méditerranean. On peut constater que la variation de la quantité de l'eau dans la mer est le facteur principal à ce rapport, mais qu'on doit aussi tenir compte de la distance reciproque entre les stations, de l'influence de la force de Coriolis et de l'effet des éléments météorologiques.

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Summary In the paper it is studied the question of the analogy between the average monthly sea-levels for a few tide gauge stations on the Italian and French coasts of the Mediterranean. It could be established that the variation of the water amount in the sea is the principal factor in this regard, but that the distance between the stations, the influence of the Coriolis force and the effect of meteorological elements must be considered, too.