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981.
Huu Hieu Ho Rudy Swennen Valérie Cappuyns Elvira Vassilieva Gerda Neyens Mustafa Rajabali Tan Van Tran 《Estuaries and Coasts》2013,36(1):203-219
In the present study, the geochemistry of 49 surficial-bed and 101 core sediment samples is investigated to clarify the origin of trace metals in the Cua Luc Estuary and Ha Long Bay, which is a famous World Natural Heritage Site in Vietnam. Moreover, the potential mobility of trace metals is also assessed and their relationship with reference elements (Al, Fe, and Ca) and organic matter is established in order to make recommendations for sediment management and monitor future pollution. Generally, trace metals display higher concentrations in Ha Long Bay compared to the Cua Luc Estuary. However, this is controlled by the distribution of the fine (clay?+?silt) fraction, and hence the concentrations of Al, Fe, Ca, and organic matter (OM). The comparison of concentrations of trace metals (normalized towards Al) between the surficial sediments and the subsurface core sediments based on 137Cs datings indicates that almost all surficial-sediment data fall inside or deviate slightly from the 95 % prediction interval of a background regression line. In addition, as determined by a Community Bureau of Reference three-step extraction, trace metals mainly dominate in the residual fraction (assumed to relate to crystal lattice of primary and secondary minerals), and this fraction does not change much in recent sediment layers. Therefore, trace metals are supposed to be derived from natural bio/geochemical processes and are characterized by a low potential mobility. Consequently, the established linear regression relationships of trace metal vs. Al or multiple regression relationships of trace metal vs. multi-elements (Al, Fe, Ca, and OM) are useful for the prediction of background levels of trace metals in sediments in future pollution monitoring and assessment programs. 相似文献
982.
The aim of this paper was to compare the stress and strain quantities that are related to the failure–deformation process of hard rock. The data used here was obtained from laboratory uniaxial compression tests performed on different types of Fennoscandian hard rocks. The failure–deformation process quantities were compared at each deformation stage and for each single specimen. Moreover, geological information such as the rock origin process and the rock characteristics of the specimens were studied and linked to the stress and strain quantities. The purpose was to investigate the influence of the rock origin process and rock characteristics on these quantities. The main results of this study showed that the normalized crack damage lateral strain (ε 3cd/ε 3p ) and the volumetric strain (ε crv?ci and ε v?cd) quantities were strongly affected by the grain size. The normalized and volumetric quantities are weakly dependent on the mineral composition. 相似文献
983.
Luísa D.V.Carvalho Tiago Jalowitzki Ricardo Scholz Guilherme O.Gonalves Marcelo Peres Rocha Rogério Silvestre Pereir Cristiano Lana Marco Paulo de Castro Gláucia Queiroga Reinhardt A.Fuck 《地学前缘(英文版)》2022,(1):182-203
We present major and trace element compositions of mineral concentrates comprising garnet xenocrysts,ilmenite,phlogopite,spinel,zircon,and uncommon minerals (ti... 相似文献
984.
Horst R. Marschall Rainer Altherr Katalin Gméling Zsolt Kasztovszky 《Mineralogy and Petrology》2009,95(3-4):291-302
High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H2O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B?/Be and Cl?/Be ratios correlate with H2O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B?/Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl?/Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H2O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies. 相似文献
985.
Suzan Pantaroto de Vasconcellos Elaine Crespim Georgiana Feitosa da Cruz Diego Barbosa Senatore Karen Christina Marques Simioni Eugênio Vaz dos Santos Neto Anita Jocelyne Marsaioli Valéria Maia de Oliveira 《Organic Geochemistry》2009,40(5):574-588
The detection of microorganisms with potential for biodeterioration and biodegradation in petroleum fields is of great relevance, since these organisms may be related to a decrease in petroleum quality in the reservoirs or damage in the production facilities. In this sense, petroleum formation water and oil samples were collected from the Campos Basin, Brazil, with the aim of isolating microorganisms and evaluating their ability to degrade distinct classes of hydrocarbon biomarkers (9,10-dihydrophenanthrene, phytane, nonadecanoic acid and 5α-cholestane). Twenty eight bacterial isolates were recovered and identified by sequencing their 16S rRNA genes. Biodegradation assays revealed that bacterial metabolism of hydrocarbons occurred through reactions based on oxidation, carbon–carbon bond cleavage and generation of new bonds or by the physical incorporation of hydrocarbons into microbial cell walls. Based on the biodegradation results, selective PCR-based systems were developed for direct detection in petroleum samples of bacterial groups of interest, namely Bacillus spp., Micrococcus spp., Achromobacter xylosoxidans, Dietzia spp. and Bacillus pumilus. Primer sets targeting 16S rRNA genes were designed and their specificity was confirmed in silico (i.e. computational analysis) and in PCR reactions using DNA from reference strains as positive and negative controls. Total DNA from oil was purified and the amplification tests revealed the presence of the target bacteria in the samples, unraveling a significant potential for petroleum deterioration in the reservoirs sampled, once proper conditions are present for hydrocarbon degradation. The application of molecular methods for rapid detection of specific microorganisms in environmental samples would be valuable as a supporting tool for the evaluation of oil quality in production reservoirs. 相似文献
986.
Amazon’s deforestation affects citizens from varying information communities. Experts like scientists or journalists acquire
relevant data on-site and publish valuable information on the Web. But different and sometimes conflicting views on reality
impede sharing of information across communities, relevant content remains far too often undiscovered. We introduce rule-based
semantic annotations as solution to facilitate the discovery and evaluation of geographical information. With the distinction
between shared domain and local information source ontologies, the proposed architecture of a semantically supported SDI for
the Amazon also takes the plethora of GI formats into account. Creating semantic annotations is challenging, a recommender
system for semantic annotations enables even the non-IT experts to participate. The benefits of the proposed techniques are
further illustrated by a scenario which spans across information communities of economics, ecology, and ethnology. 相似文献
987.
J. Escuder Viruete A. Pérez-Estaún D. Weis 《International Journal of Earth Sciences》2009,98(2):407-425
The nature of the oceanic crust produced through rifting and oceanic spreading between North and South America during the
Late Jurassic is a key element for the Caribbean plate tectonic model reconstruction. Located in the Cordillera Central of
Hispaniola, the Loma La Monja volcano-plutonic assemblage (LMA) is composed of gabbros, dolerites, basalts, and oceanic sediments,
as well as metamorphic equivalents, which represent a dismembered fragment of this proto-Caribbean oceanic crust. Petrologic
and geochemical data show that the LMA have a relatively broad diversity in composition, which represent the crystallization
products of a typical low-pressure tholeiitic fractionation of mid-ocean ridge basalts (MORB)-type parental magmas, ranging
from N- to E-MORB. Three geochemical groups have been distinguished in the volcanic sequence: LREE-flat to slightly LREE-enriched
basalts of groups II and III occur interlayered in the lower stratigraphic levels; and LREE-depleted basalts of group I in
the upper levels. Mantle melt modeling suggests that group III magmas are consistent by mixing within a mantle melt column
of low-degree (<1%) melts of a deep garnet lherzolite source and high-degree (>15%) melts of a shallow spinel source, and
groups II and I magmas are explained with moderate to high (14–18%) and very high (>20%) fractional melting degrees of a shallower
spinel mantle source, respectively. Thus, upward in the volcanic sequence of the LMA, the magmas represent progressively more
extensive melting of shallower sources, in a plume-influenced spreading ridge of the proto-Caribbean oceanic crust. Nb/Y versus
Zr/Y systematics combined with recent plate tectonic model reconstructions reveal that Caribbean Colombian oceanic plateau
fragments in Hispaniola formed through melting of heterogeneous mantle source regions related with distinct plumes during
at least from Aptian–Albian (>96 Ma) to Late Campanian. 相似文献
988.
Stress Measurement by Overcoring at Shallow Depths in a Rock Slope: the Scattering of Input Data and Results 总被引:1,自引:0,他引:1
C. Clément V. Merrien-Soukatchoff C. Dünner Y. Gunzburger 《Rock Mechanics and Rock Engineering》2009,42(4):585-609
This paper describes a field experiment of stress measurement using the overcoring method performed in a rock slope, called
Rochers de Valabres (located in France’s Southern Alps Region), a field laboratory site prone to rockfalls. Six measurements were conducted at
shallow depths from the surface, moving deeper along a sub-horizontal borehole. The experiment was conducted in heterogeneous
and anisotropic gneiss, with the overcored rock elastic properties, as evaluated by biaxial and uniaxial tests, being widely
scattered. Since stress calculations are sensitive to all input data uncertainties, strain inversion was, thus, performed
using an experimental device and Monte Carlo simulations. The experimental device allows the assessment of rather broad confidence
intervals for both stress magnitude and orientation. The results indicate that the stress state in the surface area is quite
heterogeneous and may be correlated with topography. The measurements show a nonlinear stress distribution with distance to
the free surface, along with high values of principal stresses, despite the vicinity of the surface. Although influenced by
local topography, orientations of the principal computed stresses are characterized by a high turnover due to local heterogeneities.
The results are roughly in accordance to a 2D finite element model of the site. 相似文献
989.
990.
Labour shortage was an integral feature of the communist system of economic management and one that seemed most unlikely to
persist in the face of systemic transformation. A casual examination of the unemployment rates that have emerged throughout
most of Central and Eastern Europe (CEE) during the course of the past decade might suggest that this early assumption was
correct. However, within the region the aggregate rate of joblessness, as well as the behaviour of national output, mask the
fact that certain, major urban centres appear to have weathered well the storms caused by exposure to western markets and
stringent fiscal and monetary policies. In these centres transformation has meant, to a greater or lesser degree, industrial
modernisation and this begs the question of whether the human capital portfolios of the inherited labour force match up to
the requirements of the new environment. This paper examines the meaning of the concept of labour shortage and presents the
findings from a survey of employers in four leading cities of three major CEE economies designed to elicit if, and how, manpower
requirements are being met in the present climate. The results indicate that, somewhat paradoxically, labour shortage persists
in the more flexible markets of the post-communist era and that firms do not expect the situation to change radically in the
near future.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献