Rapid Determination of Trace and Ultra Trace Level Elements in Diverse Silicate Rocks in Pressed Powder Pellet Targets by LA‐ICP‐MS using a Matrix‐Independent Protocol

A simple, single sample preparation involving pressed rock powder pellets was utilised to determine the trace and ultra trace abundances of petrogenetically important elements including high field‐strength elements and REEs by laser ablation‐ICP‐MS. One of the elements predetermined by XRF spectrometry served as an internal standard. The influence of sample preparation parameters (grain size, pellet compactness and amount of binding media) on analytical performance was also investigated, including sample homogeneity issues at the laser sampling scale. Line scanning with a high repetition frequency (20 Hz) and large beam diameter (200 μm) ensured ablation from a larger sample surface area, eliminating issues related to sample heterogeneity. A median grain size of about 10 μm for silicate rock powders was found to be sufficiently representative at this scale of laser sampling. Granitic rocks or samples containing resistant minerals such as zircon needed extra grinding to achieve grain sizes down to < 5 μm for better precision for elements that are concentrated in these phases. Using ¹³⁷Ba as an internal standard, reasonable accuracies within 15–20% for most of the high mass trace elements were achieved; in the case of low mass elements, it may deviate up to 40%. Precision of measurements rarely exceeded 15% RSD.     

Preparation and Characterisation of Two Geochemical Reference Materials: DG‐H (Granite) and AM‐H (Amphibolite) from the Himalayan Orogenic Belt

Two geochemical reference materials of Himalayan origin named DG‐H (a granite) and AM‐H (an amphibolite) prepared by the Wadia Institute of Himalayan Geology Dehradun are described. Both samples were collected from the NW Himachal Himalaya in India. With the participation of analysts from more than forty international laboratories, element determination data collected during the past 10 years for characterisation of the samples was processed to assign working values using statistical procedures in use for this purpose. Earlier work published on these samples is incorporated in the present communication making it an updated document. The typical chemical and petrological characteristics of these two samples may prove useful for method validation and calibration of analytical instruments used for analysing similar rock types, and for widening the analytical range of several analytical methods used for geochemical analysis.     

Origin of peraluminous minerals (corundum,spinel, and sapphirine) in a highly calcic anorthosite from the Sittampundi Layered Complex,Tamil Nadu,India

The highly calcic anorthosite (An_>95) from the Sittampundi Layered Complex (SLC) develops corundum, spinel and sapphirine that are hitherto not reported from any anorthositic rocks in the world. Petrological observations indicate the following sequence of mineral growth: plagioclase_matrix → corundum; clinopyroxene → amphibole; corundum + amphibole → plagioclase_corona + spinel; and spinel + corundum → coronitic sapphirine. Phase relations in the CaO–Na₂O–Al₂O₃–SiO₂–H₂O (CNASH) system suggest that corundum was presumably developed through vapour present incongruent melting of the highly calcic plagioclase during ultra-high temperature (UHT) metamorphism (T ≥ 1000 °C, P ≥ 9 kbar). Topological constraints in parts of the Na₂O–CaO–MgO–Al₂O₃–SiO₂–H₂O (NCMASH) system suggest that subsequent to the UHT metamorphism, aqueous fluid(s) permeated the rock and the assemblage corundum + amphibole + anorthite + clinozoisite was stabilized during high-pressure (HP) metamorphism (11 ± 2 kbar, 750 ± 50 °C). Constraints of the NCMASH topology and thermodynamic and textural modeling study suggest that coronitic plagioclase and spinel formed at the expense of corundum + amphibole during a steeply decompressive retrograde P–T path (7–8 kbar and 700–800 °C) in an open system. Textural modeling studies combined with chemical potential diagrams (μSiO₂–μMgO) in the MASH system support the view that sapphirine also formed from due to silica and Mg metasomatism of the precursor spinel ± corundum, on the steeply decompressive retrograde P–T path, prior to onset of significant cooling of the SLC. Extremely channelized fluid flow and large positive solid volume change of the stoichiometrically balanced sapphirine forming reaction explains the localized growth of sapphirine.     

Overview on the middle to upper Jurassic sedimentary succession of Gangta Bet in the Kachchh basin,western India,with special emphasis on its lithostratigraphy,biostratigraphy, and palaeoenvironment

The Jurassic succession of Gangta Bet in the Kachchh basin of western India comprises around 130 m of mostly siliciclastic rocks. The strata belong to the Gangta Member of the Gadhada Formation and are herein sub-divided into four units: the Gangta sandstone beds, the lower silty sandstone beds, the upper silty sandstone beds, and the Gangta ammonite beds. These units can be separated by three marker horizons: the Brachiopod bed, the Gangta Conglomerate Bed, and the Gervillella Bed. Ammonites indicate an Oxfordian age for the upper half of the succession, but the scarcity of identifiable fossils in its basal part so far prevented precise biostratigraphic assignments. The shallow-water sediments can be interpreted as parasequences as a result of minor sea-level changes. Deposition took place close to the palaeo-coastline at water depths around the fair-weather wave-base.     

E–W strike slip shearing of Kinwat granitoid at South East Deccan Volcanic Province,Kinwat, Maharashtra,India

We study the margin of South East Deccan Volcanic Province around Kinwat lineament, Maharashtra, India, which is NW extension of the Kaddam Fault. Structural field studies document \(\sim \)E–W strike-slip mostly brittle faults from the basement granite. We designate this as ‘Western boundary East Dharwar Craton Strike-slip Zone’ (WBEDCSZ). At local level, the deformation regime from Kinwat, Kaddam Fault, micro-seismically active Nanded and seismically active Killari corroborate with the nearby lineaments. Morphometric analyses suggest that the region is moderately tectonically active. The region of intense strike-slip deformation lies between seismically active fault along Tapi in NW and Bhadrachalam in the SE part of the Kaddam Fault/lineament. The WBEDCSZ with the surface evidences of faulting, presence of a major lineaments and intersection of faults could be a zone of intraplate earthquake.     

Arsenic distribution along different hydrogeomorphic zones in parts of the Brahmaputra River Valley,Assam (India)

The spatial distribution of arsenic (As) concentrations along three classified hydrogeomorphological zones in the Brahmaputra River Valley in Assam (India) have been investigated: zone I, comprising the piedmont and alluvial fans; zone II, comprising the runoff areas; and zone III, comprising the discharge zones. Groundwater (150 samples) from shallow hand-pumped and public water supply wells (2–60 m in depth) was analysed for chemical composition to examine the geochemical processes controlling As mobilization. As concentrations up to 0.134 mg/L were recorded, with concentrations below the World Health Organization and the Bureau of Indian Standards drinking-water limits of 0.01 mg/L being found mainly in the proximal recharge areas. Eh and other redox indicators (i.e., dissolved oxygen, Fe, Mn and As) indicate that, except for samples taken in the recharge zone, groundwater is reducing and exhibits a systematic decrease in redox conditions along the runoff and discharge zones. Hydrogeochemical evaluation indicated that zone I, located along the proximal recharge areas, is characterized by low As concentration, while zones II and III are areas with high and moderate concentrations, respectively. Systematic changes in As concentrations along the three zones support the view that areas of active recharge with high hydraulic gradient are potential areas hosting low-As aquifers.     

Uncertainty of soil erosion modelling using open source high resolution and aggregated DEMs

Digital Elevation Model (DEM) is one of the important parameters for soil erosion assessment. Notable uncertainties are observed in this study while using three high resolution open source DEMs. The Revised Universal Soil Loss Equation (RUSLE) model has been applied to analysis the assessment of soil erosion uncertainty using open source DEMs (SRTM, ASTER and CARTOSAT) and their increasing grid space (pixel size) from the actual. The study area is a part of the Narmada river basin in Madhya Pradesh state, which is located in the central part of India and the area covered 20,558 km². The actual resolution of DEMs is 30 m and their increasing grid spaces are taken as 90, 150, 210, 270 and 330 m for this study. Vertical accuracy of DEMs has been assessed using actual heights of the sample points that have been taken considering planimetric survey based map (toposheet). Elevations of DEMs are converted to the same vertical datum from WGS 84 to MSL (Mean Sea Level), before the accuracy assessment and modelling. Results indicate that the accuracy of the SRTM DEM with the RMSE of 13.31, 14.51, and 18.19 m in 30, 150 and 330 m resolution respectively, is better than the ASTER and the CARTOSAT DEMs. When the grid space of the DEMs increases, the accuracy of the elevation and calculated soil erosion decreases. This study presents a potential uncertainty introduced by open source high resolution DEMs in the accuracy of the soil erosion assessment models. The research provides an analysis of errors in selecting DEMs using the original and increased grid space for soil erosion modelling.     

Fractal analysis of logs to characterize the hydrocarbon and non-hydrocarbon zones of Bhogpara oil field,Northeast India

Identification with accuracy of prospective and dry zone from well log data is of prime importance in reservoir or hydrocarbon studies. This issue has greater stake, where in return many conventional methods have been established. The purpose of this study is to recognize the hydrocarbon and non-hydrocarbon bearing portion within a reservoir by using a non-conventional technique. Application of rescaled range (R/S) analysis and wavelet-based fractal analysis (WBFA) on the wire-line log data to obtain the pre-defined hydrocarbon (HC) and non-hydrocarbon (NHC) zones by their fractal nature is demonstrated in this paper. Among these two techniques, the WBFA tool has provided more prolific results. Applicability of the proposed approach is tested with the help of the most commonly used well log data like self-potential, gamma ray, and porosity log responses. These are used in the industry to distinguish several HC and NHC zones of all wells in the study region belonging to the Upper Assam Basin, India. The results are found to be of lower fractal dimension in this study for a particular log response having HC-bearing zones, which are mainly situated in a variety of sandstone lithology. On the other hand, NHC-bearing zones correspond to lithology with higher shale content categorized with higher fractal dimension. Hence, the WBFA technique can overcome the chance of misinterpretation, which is quite possible in the case of conventional reservoir characterization.     

The changes in La Niña induced summertime interannual variability of sea level anomaly along the western boundary of the Bay of Bengal

Ocean Dynamics - In this study, interannual variability and associated dynamics of sea level anomaly (SLA) along the western boundary of the Bay of Bengal (WBoB) during the summer...     

Methane flux dynamics in relation to methanogenic and methanotrophic populations in the soil of Indian Sundarban mangroves

The dynamics of methane (CH₄) flux in relation to populations of methanogenic and methanotrophic bacteria was studied under the different biophysical conditions of the Indian Sundarban mangrove ecosystem. Soil depth profile analysis (up to 60 cm) in the lower littoral zone (LLZ) revealed that a methanogenic population of 6.45 ± 0.19 × 10⁴ cells/g dry weight (dry wt) of soil accounted for a CH₄ production rate of 6.23 ± 3.53 × 10³ µmol m^?2 day^?1, whereas in the surface soil, a methanogenic population of 3.34 ± 0.37 × 10⁴ cells/g dry wt of soil accounted for a CH₄ production rate of 31.6 ± 0.57 µmol m^?2 day^?1. The CH₄ oxidation rate at 60 cm depth in the LLZ was 24.42 ± 1.28 µmol m^?2 day^?1, with an average methanotrophic population of 1.33 ± 0.43 × 10⁴ cells/g dry wt of soil, whereas in the surface soil, the oxidation rate and average population were 3.38 ± 1.43 × 10³ µmol m^?2 day^?1 and 12.80 ± 2.54 × 10⁴ cells/g dry wt of soil, respectively. A similar soil profile in terms of CH₄ dynamics and the populations of methanogenic and methanotrophic bacteria was found in the mid‐littoral and upper littoral zones of the studied area. The results demonstrate that most of the produced CH₄ (approximately 60%) was oxidized by methanotrophic bacteria present in the soil, thus revealing their principal role in regulating the CH₄ flux from this unique ecosystem.