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11.
The tectono-thermal history of the Lewisian Complex in South Harris (South Harris Complex) was inferred from its geologic and metamorphic characteristics. The lithological assemblages and geochemical features of the complex suggest that its precursory rocks were composed of the subduction-related accretionary complex formed in the palaeo convergent margin. The complex has suffered the ultra-high temperature (UHT) metamorphism that was contemporaneous with the igneous activity to make the South Harris Igneous Complex (SHIC) and the subsequent continent-continent collisional activity. A similar complex recording the geological processes of the subduction, the UHT metamorphism and the collision has been recognized in the Lapland-Kola belt and New Quebec in the Palaeoproterozoic. This suggests an assembly of micro-continents to form the Palaeoproterozoic supercontinent in the North Atlantic region. 相似文献
12.
13.
The crater lake water from Maly Semiachik volcano in Kamchatka was used for the international analytical laboratory comparison of major and minor elements, and hydrogen, sulfur, and oxygen isotope data. Eight institutions participated in this program, giving analytical results of 9 major and 20 minor elements mainly by using ICP-AES for cations and IC for anions. Among the major elements, Na, Mg and Si showed coefficients of variation (CV) of 10% or more, whereas B, Al, Fe, Mn had coefficients less than 7%. The CV% of the minor elements Co, Cu, P, Cr, Pb was much greater (>30%) while the V analyses agreed well (<10%). Ti, Sr, Zn, and F were intermediate (between 10 and 20 CV%). The errors observed for these constituents are inherent to the methods applied: large dilutions and spectrometric interferences. Even the major anions such as Cl (>2000 ppm) and SO4 (>5000 ppm) gave considerable ranges (5.1 and 8.8 CV%, respectively) as did the obtained pH values (22 CV%). The measured δ18O of the water samples and δ34S of sulfate are in excellent agreement but the δD values had CV% of 8. Technical recommendations are presented to improve the analytical results for these elements with significant deviations from the mean values. 相似文献
14.
Katsumi Marumo Tetsuro Urabe Akiko Goto Yoshinori Takano Miwako Nakaseama 《Resource Geology》2008,58(3):220-248
This report presents mineralogical, geochemical and isotopic data on samples obtained using the Benthic Multi‐coring System (BMS) to drill a submarine hydrothermal deposit developed in a caldera on the summit of the Suiyo Seamount in the Izu–Bonin Island Arc, south of Japan. This deposit is regarded as the first example of Kuroko‐type sulfide mineralization on a volcano at the volcanic front of an island arc. The mineralization and hydrothermal alteration below the 300 × 150‐m area of active venting was investigated to depths of 2–9 m below the sea floor. Drilling beneath the area of active venting recovered a sequence of altered volcanic rocks (dacite lavas, pyroclastic rocks of dacite–rhyolite compositions and pumice) associated with sulfide veining and patches/veins of anhydrite. No massive sulfide was found, however, and the subsea‐floor mineralization to 10 m depth is dominated by anhydrite and clay minerals with some sulfides. Sulfide‐bearing samples contained high Au (up to 42 ppm), Ag (up to 263 ppm), As (up to 1550 ppm), Hg (up to 55 ppm), Sb (up to 772 ppm), and Se (up to 24 ppm). Electron probe microanalyzer indicated that realgar, orpiment, and mimetite were major As‐bearing minerals. The sulfides were also characterized by high Zn (>10%) compared to Cu (<6.3%) and Pb (<0.6%). The δ202Hg/198Hg, δ202Hg/199Hg and δ202Hg/200Hg of the sulfide‐bearing dacite samples and a sulfide chimney decreased with increasing Hg/Zn concentration ratio. The variation of the δ202Hg/198Hg ranged from ?2.8 to +0.5‰ to relative to S‐HG02027. The large range of these δ202Hg/198Hg was greater than might be expected for such a heavy element and may be due to a predominance of kinetic effects. The variation of δ202Hg/198Hg of sulfide‐bearing dacite samples suggested that light Hg isotope in the vapor mixed with oxygenated seawater near sea floor during mineralization. Lead isotope ratios of the sulfide were very similar to those of the dacite lava, suggesting that lead is of magmatic origin. The 87Sr/86Sr ratio (0.70872) of anhydrite was different from that of the dacite lava, and suggests an Sr derivation predominantly from seawater. Hydrothermal alteration of the dacite in the Suiyo hydrothermal field was characterized by Fe‐sulfides, anhydrite, barite, montmorillonite, chlorite/montmorillonite mixed‐layer minerals, mica, and chlorite with little or no feldspar or cristobalite. Hydrothermal clay minerals changed with depth from montmorillonite to chlorite/montmorillonite mixed‐layer minerals to chlorite and mica. Hydrogen isotope ratios of chlorite/montmorillonite and mixed‐layer, mica‐chlorite composites obtained below the active venting sites ranged from ?49 to ?24‰, suggesting seawater as the dominant fluid causing alteration. Oxygen isotope ratios of anhydrite ranged from 9.2 to 10.4‰ and anhydrite formation temperatures were calculated to be 188–207°C. Oxygen isotope ratios ranged from +5.2 to +9.2‰ for montmorillonite, +3.2 to +4.5‰ for chlorite/montmorillonite mixed‐layer minerals, and +2.8 to +3.8‰ in mixtures of chlorite and mica. The formation temperatures of montmorillonite and of the chlorite–mica mixture were 160–250°C and 230–270°C, respectively. The isotope temperatures for clay minerals (220–270°C) and anhydrite (188°C) were significantly lower than the borehole temperature (308.3°C) measured just after the drilling, suggesting that temperature at this site is now higher than when clay minerals and anhydrite were formed. 相似文献
15.
Gary L Rowe Jr Shinji Ohsawa Bokuichiro Takano Susan L Brantley Jose F Fernandez Jorge Barquero 《Bulletin of Volcanology》1992,54(6):494-503
Monitoring of crater lake chemistry during the recent decline and disappearance of the crater lake of Poás Volcano revealed that large variations in SO4/Cl, F/Cl, and Mg/Cl ratios were caused by the enhanced release of HCl vapor from the lake surface due to increasing lake temperature and solution acidity. Variation in the concentration of polythionic acids (H2SxO6, x=4–6) was the most reliable predictor of renewed phreatic eruptive activity at the volcano, exhibiting sharp decreases three months prior to the initiation of phreatic eruptions in June 1987. Polythionic acids may offer a direct indicator of changing subsurface magmatic activity whereas chloride-based element ratios may be influenced by surface volatilization of HCl and subsequent recycling of acidic fluids in crater lake volcanoes. 相似文献
16.
Kenzo Takano 《Journal of Oceanography》1974,30(2):91-95
A current measurement by four Savonius current meters is done for a little longer than eight days in the north-western Pacific. The result of a preliminary analysis of the records is described. Periods around twenty-four hours are dominant. The energy spectra match the -5/3 law for the frequency range up to the diurnal frequency. 相似文献
17.
Biogenic amino acids, taken as representative of organic matter, were analyzed to determine the apparent degradation rate constant in boreal terrestrial sediment. Age determination using 14C dating gave two rate constants: the initial degradation rate constant for glycine (kGLY 1), the simplest amino acid, was 1.5 × 10−3 yr−1 (r = 0.97) until about 2200 yr BP. After the inflection point, the rate constant kGLY 2 was 9.1 × 10−5 yr−1 (r = 0.73). The degradation of amino acids in the labile organic matter in the sediment was markedly affected by rapid processes. After the inflection point, the rate constant profiles for sub-surface amino acids were shown to have discontinuous relationships with sediment age. One pattern which emerged in the vertical distribution is that the biogenic amino acid degradation rate constant k was far greater in the labile organic matter phase than that in the refractory organic matter over the past 10,000 years. 相似文献
18.
Guodong Zheng Yuhua Lang Bokuichiro Takano Motoyuki Matsuo Akihito Kuno Haruaki Tsushima 《Journal of Asian Earth Sciences》2002,20(8)
It has been often observed that black mud recently formed and accumulated in slip planes that are closely associated with a progressing landslide in Japan. Mössbauer spectroscopy revealed that the composition of Fe species in the sliding mud is different from those in the debris rock and bedrock. The sliding mud contains more ferrous iron species, which indicates a relatively stronger reducing condition within the sliding zone than within the host rocks. In addition, the composition of Fe species, the total Fe and the volume of sliding mud also change with landslide development. Therefore, detailed Fe speciation in landslide profiles can be a useful approach to understanding the progress of a landslide and may also predict future sliding as well. 相似文献
19.
Fluvial to bay sequence stratigraphy and seismic facies of the Cretaceous to Paleogene successions in the MITI Sanriku‐oki well and the vicinities,the Sanriku‐oki forearc basin,northeast Japan
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This paper describes the significant depositional setting information derived from well and seismic survey data for the Upper Cretaceous to Lower Eocene forearc basin sediments in the central part of the Sanriku‐oki basin, which is regarded as a key area for elucidating the plate tectonic history of the Northeast Japan Arc. According to the results of well facies analysis utilizing cores, well logs and borehole images, the major depositional environments were of braided and meandering fluvial environments with sporadically intercalated marine incursion beds. Seismic facies, reflection terminations and isopach information provide the actual spatial distributions of fluvial channel zones flowing in a north–south trending direction. The transgression and regression cycles indicate that the Upper Cretaceous to Lower Eocene successions can be divided into thirteen depositional sequences (Sequences SrCr‐0 to SrCr‐5, and SrPg‐1 to SrPg‐7). These depositional sequences demonstrate three types of stacking patterns: Types A to C, each of which shows a succession mainly comprising a meandering fluvial system, a braided fluvial system with minor meandering aspects in the upper part, and major marine incursion beds in the middle part, respectively, although all show an overall transgressive to regressive succession. The Type C marine incursion beds characteristically comprise bay center and tidal‐dominated bay margin facies. Basin‐transecting long seismic sections demonstrate a roll up structure on the trench slope break (TSB) side of the basin. These facts suggest that during the Cretaceous to Eocene periods, the studied fluvial‐dominated forearc basin was sheltered by the uplifted TSB. The selective occurrences of the Type C sequences suggest that when a longer‐scale transgression occurred, especially in Santonian and early Campanian periods, a large bay basin was developed, creating accommodation space, which induced the deposition of the Cretaceous Kuji Group along the arc‐side basin margin. 相似文献
20.
M. Kusakabe Y. Komoda B. Takano T. Abiko 《Journal of Volcanology and Geothermal Research》2000,97(1-4)
Sulfur isotope effects during the SO2 disproportionation reaction to form elemental sulfur (3SO2+3H2O→2HSO4−+S+2H+) at 200–330°C and saturated water vapor pressures were experimentally determined. Initially, a large kinetic isotopic fractionation takes place between HSO4− and S, followed by a slow approach to equilibrium. The equilibrium fractionation factors, estimated from the longest run results, are expressed by 1000 ln αHSO4−–S=6.21×106/T2+3.62. The rates at which the initial kinetic fractionation factors approach the equilibrium ones were evaluated at the experimental conditions.δ34S values of HSO4− and elemental sulfur were examined for active crater lakes including Noboribetsu and Niseko, (Hokkaido, Japan), Khloridnoe, Bannoe and Maly Semiachik (Kamchatka), Poás (Costa Rica), Ruapehu (New Zealand) and Kawah Ijen and Keli Mutu (Indonesia). ΔHSO4−–S values are 28‰ for Keli Mutu, 26‰ for Kawah Ijen, 24‰ for Ruapehu, 23‰ for Poás, 22‰ for Maly Semiachik, 21‰ for Yugama, 13‰ for Bannoe, 9‰ for Niseko, 4‰ for Khloridonoe, and 0‰ for Noboribetsu, in the decreasing order. The SO2 disproportionation reaction in the magmatic hydrothermal system below crater lakes where magmatic gases condense is responsible for high ΔHSO4−–S values, whereas contribution of HSO4− produced through bacterial oxidation of reduced sulfur becomes progressively dominant for lakes with lower ΔHSO4−–S values. Currently, Noboribetsu crater lake contains no HSO4− of magmatic origin. A 40-year period observation of δ34SHSO4− and δ34SS values at Yugama indicated that the isotopic variations reflect changes in the supply rate of SO2 to the magmatic hydrothermal system. This implies a possibility of volcano monitoring by continuous observation of δ34SHSO4− values. The δ18O values of HSO4− and lake water from the studied lakes covary, indicating oxygen isotopic equilibration between them. The covariance gives strong evidence that lake water circulates through the sublimnic zone at temperatures of 140±30°C. 相似文献