Katla volcano,Iceland: magma composition,dynamics and eruption frequency as recorded by Holocene tephra layers

The Katla volcano in Iceland is characterized by subglacial explosive eruptions of Fe–Ti basalt composition. Although the nature and products of historical Katla eruptions (i.e. over the last 1,100 years) at the volcano is well-documented, the long term evolution of Katla’s volcanic activity and magma production is less well known. A study of the tephra stratigraphy from a composite soil section to the east of the volcano has been undertaken with emphasis on the prehistoric deposits. The section records ∼8,400 years of explosive activity at Katla volcano and includes 208 tephra layers of which 126 samples were analysed for major-element composition. The age of individual Katla layers was calculated using soil accumulation rates (SAR) derived from soil thicknesses between ¹⁴C-dated marker tephra layers. Temporal variations in major-element compositions of the basaltic tephra divide the ∼8,400-year record into eight intervals with durations of 510–1,750 years. Concentrations of incompatible elements (e.g. K₂O) in individual intervals reveal changes that are characterized as constant, irregular, and increasing. These variations in incompatible elements correlate with changes in other major-element concentrations and suggest that the magmatic evolution of the basalts beneath Katla is primarily controlled by fractional crystallisation. In addition, binary mixing between a basaltic component and a silicic melt is inferred for several tephra layers of intermediate composition. Small to moderate eruptions of silicic tephra (SILK) occur throughout the Holocene. However, these events do not appear to exhibit strong influence on the magmatic evolution of the basalts. Nevertheless, peaks in the frequency of basaltic and silicic eruptions are contemporaneous. The observed pattern of change in tephra composition within individual time intervals suggests different conditions in the plumbing system beneath Katla volcano. At present, the cause of change of the magma plumbing system is not clear, but might be related to eruptions of eight known Holocene lavas around the volcano. Two cycles are observed throughout the Holocene, each involving three stages of plumbing system evolution. A cycle begins with an interval characterized by simple plumbing system, as indicated by uniform major element compositions. This is followed by an interval of sill and dyke system, as depicted by irregular temporal variations in major element compositions. This stage eventually leads to a formation of a magma chamber, represented by an interval with increasing concentrations of incompatible elements with time. The eruption frequency within the cycle increases from the stage of a simple plumbing system to the sill and dyke complex stage and then drops again during magma chamber stage. In accordance with this model, Katla volcano is at present in the first interval (i.e. simple plumbing system) of the third cycle because the activity in historical time has been characterized by uniform magma composition and relatively low eruption frequency.     

Modelling Watersheds as Spatial Object Hierarchies: Structure and Dynamics

The generation, transport and fate of non-point source pollutants in surface water systems is recognized as a major threat to water supplies, aquatic and coastal ecosystems. The transformation and movement of water, carbon and nutrients through watersheds integrates a set of ecosystem processes along hydrologic flowpaths. Human individual and institutional interactions with these processes involve direct addition or abstraction of these substances, or the alteration of land cover and drainage systems. In natural and developed catchments, these processes often vary at granularities ranging from below the level of a hillslope, up through regional watersheds. This suggests the need for the development of hierarchical analysis tools that can address the integration of a set of biophysical, biogeochemical and socioeconomic processes over a spectrum of scales. We describe and illustrate the use of a watershed model implemented as a spatial object hierarchy, representing successively contained landform classes associated with class specific processes as member functions. The model has been linked in a range of looser and tighter couplings with GRASS and ArcView, supplemented by specific terrain analytical functions. We illustrate the data and model system for an instrumented catchment monitored as part of the Baltimore Ecosystem Study (BES), a Long Term Ecological Research (LTER) site centering on integrated carbon, water and nutrient cycling.     

Comparative ecophysiology of active zoobenthic filter feeding, essence of current knowledge

The present contribution gives an overview of current knowledge of a comprehensive and steadily growing research field. The first section deals with water pumping and particle retention mechanisms in ciliary and muscular filter feeders. The second section examines the biological filter pumps in order to assess adaptation to the environment. Filter-feeding benthic invertebrates have evolved filter pumps to solve common basic problems. This has led to a large degree of similarity between otherwise distant standing species, which makes comparative studies interesting and important. The present review of zoobenthic filter feeding aims at accentuating such recognition.     

Time Variability of Rotation in Solar Convection Zone From soi-mdi

The variation of rotation in the convection zone over a period of two years from mid-1996 is studied using inversions of SOI–MDI data. We confirm the existence of near-surface banded zonal flows migrating towards the equator from higher latitudes, and reveal that these banded flows extend substantially beneath the surface, possibly to depths as great as 70 Mm (10% of the solar radius). Our results also reveal apparently significant temporal variations in the rotation rate at high latitudes and in the vicinity of the tachocline over the period of study.     

Seismic tomography of the near solar surface

Surface gravity waves have been used to probe flows in the two megameters beneath the photosphere using the techniques of timedistance helioseismology. The results suggest that supergranule velocities are smaller than at the surface. The outward flow outside a sunspot penumbra (the moat) is observed, as is an inward flow in the region beyond the moat.     

Base Pliocene velocity inversion on the eastern Vøring margin— causes and implications

The Plio-Pleistocene wedge off mid Norway is characterized by a pronounced increase in sonic velocities versus depth. At its base, a velocity inversion of 0.55 km s⁻¹ exists with respect to the underlying unit. We propose that the inversion may be a result of the stage margin evolution, in which both the pre-depositional physiography of the margin and the depositional history of the wedge itself have been key elements. The glaciation of the uplifted mainland and the cyclic advancement of glaciers over the shelf led to the formation of the Plio-Pleistocene prograding megasequence. Underlying sequences may have been overpressured due to the rapid deposition of the wedge and because shales at the base of the wedge, deposited in a distal deltaic environment, represented a seal for water drainage. Overpressure provides sediment instability, and is an attractive mechanism to explain intra-sequence deformation and partly lateral mass movements.     

Nutrient Budgets and Management Actions in the Patuxent River Estuary,Maryland

Multi-year nitrogen (N) and phosphorus (P) budgets were developed for the Patuxent River estuary, a seasonally stratified and moderately eutrophic tributary of Chesapeake Bay. Major inputs (point, diffuse, septic, and direct atmospheric) were measured for 13 years during which, large reductions in P and then lesser reductions in N-loading occurred due to wastewater treatment plant improvements. Internal nutrient losses (denitrification and long-term burial of particulate N and P) were measured in tidal marshes and sub-tidal sediments throughout the estuary as were nutrient storage in the water column, sediments, and biota. Nutrient transport between the oligohaline and mesohaline zones and between the Patuxent and Chesapeake Bay was estimated using a salt and water balance model. Several major nutrient recycling terms were directly and indirectly evaluated and compared to new N and P inputs on seasonal and annual time-scales. Major findings included: (1) average terrestrial and atmospheric inputs of N and P were very close to the sum of internal losses plus export, suggesting that dominant processes are captured in these budgets; (2) both N and P export were a small fraction (13% and 28%, respectively) of inputs, about half of that expected for N based on water residence times, and almost all exported N and P were in organic forms; (3) the tidal marsh-oligohaline estuary, which by area comprised ~27% of the full estuarine system, removed about 46% and 74% of total annual upland N and P inputs, respectively; (4) recycled N and P were much larger sources of inorganic nutrients than new inputs during warm seasons and were similar in magnitude even during cold seasons; (5) there was clear evidence that major estuarine processes responded rapidly to inter-annual nutrient input variations; (6) historical nutrient input data and nutrient budget data from drought periods indicated that diffuse nutrient sources were dominant and that N loads need to be reduced by about 50% to restore water quality conditions to pre-eutrophic levels.     

Palaeo-hydrogeological control on groundwater As levels in Red River delta,Vietnam

To study the geological control on groundwater As concentrations in Red River delta, depth-specific groundwater sampling and geophysical logging in 11 monitoring wells was conducted along a 45 km transect across the southern and central part of the delta, and the literature on the Red River delta’s Quaternary geological development was reviewed. The water samples (n = 30) were analyzed for As, major ions, Fe²⁺, H₂S, NH₄, CH₄, δ¹⁸O and δD, and the geophysical log suite included natural gamma-ray, formation and fluid electrical conductivity. The SW part of the transect intersects deposits of grey estuarine clays and deltaic sands in a 15–20 km wide and 50–60 m deep Holocene incised valley. The NE part of the transect consists of 60–120 m of Pleistocene yellowish alluvial deposits underneath 10–30 m of estuarine clay overlain by a 10–20 m veneer of Holocene sediments. The distribution of δ¹⁸O-values (range −12.2‰ to −6.3‰) and hydraulic head in the sample wells indicate that the estuarine clay units divide the flow system into an upper Holocene aquifer and a lower Pleistocene aquifer. The groundwater samples were all anoxic, and contained Fe²⁺ (0.03–2.0 mM), Mn (0.7–320 μM), SO₄ (<2.1 μM–0.75 mM), H₂S (<0.1–7.0 μM), NH₄ (0.03–4.4 mM), and CH₄ (0.08–14.5 mM). Generally, higher concentrations of NH₄ and CH₄ and low concentrations of SO₄ were found in the SW part of the transect, dominated by Holocene deposits, while the opposite was the case for the NE part of the transect. The distribution of the groundwater As concentration (<0.013–11.7 μM; median 0.12 μM (9 μg/L)) is related to the distribution of NH₄, CH₄ and SO₄. Low concentrations of As (?0.32 μM) were found in the Pleistocene aquifer, while the highest As concentrations were found in the Holocene aquifer. PHREEQC-2 speciation calculations indicated that Fe²⁺ and H₂S concentrations are controlled by equilibrium for disordered mackinawite and precipitation of siderite. An elevated groundwater salinity (Cl range 0.19–65.1 mM) was observed in both aquifers, and dominated in the deep aquifer. A negative correlation between aqueous As and an estimate of reduced SO₄ was observed, indicating that Fe sulphide precipitation poses a secondary control on the groundwater As concentration.     

Magmatic Differentiation at an Island-arc Caldera: Okmok Volcano, Aleutian Islands, Alaska

Okmok volcano is situated on oceanic crust in the central Aleutianarc and experienced large (15 km³) caldera-forming eruptionsat 12 000 years BP and 2050 years BP. Each caldera-forming eruptionbegan with a small Plinian rhyodacite event followed by theemplacement of a dominantly andesitic ash-flow unit, whereaseffusive inter- and post-caldera lavas have been more basaltic.Phenocryst assemblages are composed of olivine + pyroxene +plagioclase ± Fe–Ti oxides and indicate crystallizationat 1000–1100°C at 0·1–0·2 GPain the presence of 0–4% H₂O. The erupted products followa tholeiitic evolutionary trend and calculated liquid compositionsrange from 52 to 68 wt % SiO₂ with 0·8–3·3wt % K₂O. Major and trace element models suggest that the moreevolved magmas were produced by 50–60% in situ fractionalcrystallization around the margins of the shallow magma chamber.Oxygen and strontium isotope data (¹⁸O 4·4–4·9,⁸⁷Sr/ ⁸⁶Sr 0·7032–0·7034) indicate interactionwith a hydrothermally altered crustal component, which led toelevated thorium isotope ratios in some caldera-forming magmas.This compromises the use of uranium–thorium disequilibria[(²³⁰Th/ ²³⁸U) = 0·849–0·964] to constrainthe time scales of magma differentiation but instead suggeststhat the age of the hydrothermal system is 100 ka. Modellingof the diffusion of strontium in plagioclase indicates thatmany evolved crystal rims formed less than 200 years prior toeruption. This addition of rim material probably reflects theremobilization of crystals from the chamber margins followingreplenishment. Basaltic recharge led to the expansion of themagma chamber, which was responsible for the most recent caldera-formingevent. KEY WORDS: Okmok; caldera; U-series isotopes; Sr-diffusion; time scales; Aleutian arc