Finite element simulations of logging-while-drilling and extra-deep azimuthal resistivity measurements using non-fitting grids

We propose a discretization technique using non-fitting grids to simulate magnetic field-based resistivity logging measurements. Non-fitting grids are convenient because they are simpler to generate and handle than fitting grids when the geometry is complex. On the other side, fitting grids have been historically preferred because they offer additional accuracy for a fixed problem size in the general case. In this work, we analyse the use of non-fitting grids to simulate the response of logging instruments that are based on magnetic field resistivity measurements using 2.5D Maxwell’s equations. We provide various examples demonstrating that, for these applications, if the finite element matrix coefficients are properly integrated, the accuracy loss due to the use of non-fitting grids is negligible compared to the case where fitting grids are employed.     

Origin of salinity in a multilayered aquifer with high salinization vulnerability

The Kaluvelly watershed is a coastal area (Tamil Nadu, India) where water abstraction has resulted in a dramatic fall in the level of the water table and a piezometric depression in the most exploited aquifer, the Vanur aquifer. In addition, intensification/mechanization of agriculture may have affected the quality of recharge water. An initial hydrodynamic study showed that the Vanur aquifer is highly vulnerable to salinization due to potential seawater intrusion, and our aim was to determine the source of salinity recorded in the groundwater of this multilayered aquifer. Our approach involved the use of existing boreholes and of a moderate number of samples, with the aim of developing appropriate water resource management techniques. Major element, ¹⁸O/¹⁶O, ²H/¹H and ⁸⁷Sr/⁸⁶Sr, ratios were measured in rainwater, surface water and groundwater collected during five sampling campaigns over a 2‐year period. Geochemical data indicate that the Vanur aquifer is recharged and that small mixings between aquifers fluctuate according to monsoon intensity. There was no evidence of seawater intrusion. The range of recorded salinity originated mainly from water–rock interaction but a disconnection of some deeper parts of the aquifer was apparent. Strontium isotopic ratios in the recharge area suggest an anthropogenic influence, possibly related to fertilizer use. A high SO₄/Cl ratio was observed in the aquifer; in the deeper parts, the influence of a formation containing lignite is hypothesized, whereas near the surface, sulphate may partly originate from fertilizer use and fossil fuel combustion. Water isotopic data suggest that the origin of precipitation in this region has been unchanged for several hundreds or thousands of years. Copyright © 2011 John Wiley & Sons, Ltd.     

Flotation of fluorite with n-alkylammonium chlorides

Experimental study on the electrokinetic and flotation behaviour of fluorite in solutions of n-alkylammonium chlorides (with 10, 12 and 14 carbon atoms) is given. The zero point of charge (ZPC) of luorite was determined by measuring zeta potential (streaming potential method) as a function of pH. Two conditioning times of the mineral with the solution were used (10 minutes and 48 hours) and the respective ZPC were located at pH 2.2 and 8.4. Decyl-, dodecyl- and tetradecylammonium ions seem to be strongly adsorbed on the interface because they made the zeta potential more positive as the concentration increases. Hallimond tube flotation of fluorite was studied and shown to be influenced by the chain length of the collector and both collector and hydrogen ion concentrations. Flotation recovery for a given concentration of collector increases with the number of carbon atoms of the chain. The results have been discussed in the light of the electrical double-layer theory.     

Winners, losers and curate's eggs: Urban and regional outcomes of Australian economic restructuring 1971–1991

Since the early 1970s the Australian economy has undergone major transformations common to other western industrialised countries. Jobs in manufacturing declined precipitately whilst the service economy grew, most significantly in producer services but also in lower skilled jobs. Tourism and services exports began to rival traditional agricultural and mining staples. Social outcomes, also typical of international trends, included rising unemployment and polarisation of incomes. Australia's changing global context, especially the nation's increasing orientation towards Asian growth economies, have underpinned restructuring. A political climate of economic rationalism has facilitated and accentuated restructuring. The economic shifts of the past quarter century have meant that everywhere the basis for economic growth has changed. Overlaying and reinforcing the re-definition of competitive advantage has been a shift in the pattern of agglomeration economies and diseconomies. New growth regions have emerged, others have had their prospects reinforced, and still others have had their outlook diminished in absolute or, more commonly, relative terms. The paper traces the regional outcomes of national economic restructuring and shifts in the balance of agglomeration economies and diseconomies over the period from 1971 to 1991. The focus is on the top end of the urban hierarchy, on specialised industrial cities where job loss from manufacturing has hit hard, amenity regions where international and domestic tourism have been major factors in growth, and non-metropolitan balances where growth has been uneven but generally low. Demographic, economic sectoral and welfare indicators are woven into a tableau of change expressed at national, intra-state and intrametropolitan scales.     

Establishing constraints on groundwater ages with Cl,C, H,and noble gases: A case study in the eastern Paris basin,France

Groundwaters from the Tithonian/Kimmeridgian, Oxfordian and Upper Dogger aquifers, within the eastern part of the Paris basin (France), were characterised using ³H, ¹⁴C and ³⁶Cl, and noble gases tracers, to evaluate their residence times and determine their recharge period. This information is an important prerequisite to evaluating the confinement properties of the Callovo-Oxfordian clay formation sandwiched between the Oxfordian aquifer and the Dogger aquifer, currently being investigated by the French nuclear waste management agency (Andra) for radioactive waste disposal. Data presented in this paper are used to test 4 hypotheses.     

Mobility of metals in nickel mine spoil materials

An understanding of the biogeochemical behaviour of metals in mine spoil materials is a prerequisite to rehabilitate Ni mining sites. The objective of this study was to characterize the fate of metals in different Ni ore spoil materials as influenced by hydrological conditions and fertilisation practices. In tropical ultramafic complexes, the different stages of lateritic weathering lead to two types of ores, and therefore, to two spoil types. They are mainly either a clay-rich saprolite, so-called “garnierite”, enriched in phyllosilicates, or a limonitic material, enriched in Fe oxides. Lysimeter columns were designed to monitor leaching waters through both spoil materials. The garnieritic spoil released higher concentrations of Mg (mean = 2.25 mg L⁻¹), Ni (0.39 mg L⁻¹) and Cr (1.19 mg L⁻¹) than the limonitic spoil (Mg = 0.5 mg L⁻¹; Ni = 0.03 mg L⁻¹ and Cr = 0.25 mg L⁻¹). Chromium was mainly in an anionic form in leaching solutions. As exchangeable pools of Cr(VI) in limonite (980 mg kg⁻¹ of KH₂PO₄-extractable Cr) are considerable its release in water may still occur in the case of a pH increase. In mixed spoil, metal concentrations were almost as low as in the limonitic one. The effect of mineral-N fertilisation was a strong release of cations (Ni, Mg) into the leachate. Phosphate amendment did not affect the soil solution composition under experimental conditions.