Comparaison d'extractions séquentielles et cinétiques pour la spéciation de As dans des sols sableux contaminés

We compared the results obtained by sequential extraction combined with physical fractionation to those obtained by kinetics for As speciation in slightly polluted soils through irrigation. The soil samples were sieved through a 50-μm mesh. Particulate organic matter was manually sorted and joined to the less than 50-μm fractions. This last fraction was sequentially extracted with phosphates, NaOH and hydroxylamine + acetic acid at 90 °C. Kinetic extractions by EDTA were also performed on whole samples. Results show that As originating from irrigation was rather mobile. The different compartments defined by the sequential extraction were in agreement with those defines by kinetics. To cite this article: S. Cornu et al., C. R. Geoscience 336 (2004).     

Distribution d'un élément trace (Cr) dans un sol développé sur roches métamorphiques : variabilité à l'échelle d'un versantDistribution of chromium in soils developed into metamorphic rocks: variability at the hillslope scale

The influence of pedogenetic factors onto spatial variability of chromium in soil surface horizon was studied in a metamorphic area (Massif Central, France) at the hillside scale. A grid survey was performed. Surface soil horizons were sampled at each point and analysed in Cr. Results show the determinant influence of the rock type on Cr content distribution along the slope. However, surface horizons of these soils exhibit a lower Cr content heterogeneity than the deeper horizons. This was explained by soils' material erosion and deposition along the slope. Tillage and hedges also influence the Cr distribution in surface horizon along the slope. To cite this article: S. Salvador-Blanes et al., C. R. Geoscience 334 (2002) 51–58     

Simulation des changements climatiques au cours du XXIe siècle incluant l'ozone stratosphériqueSimulation of climate changes during the 21st century including stratospheric ozone

Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.     

The diffusion of ICT in France: infrastructures,services, and uses

How does the organization of space interfere in the numerical development of territories? Our hypothesis is that information and communication technologies (ICT) are organized by taking into account the existing spatial structures, compared to constraints of distance, spatial position and urban hierarchy. In the context of the liberalization of the sector of telecommunications, ICT spread according to an economic logic of profitability. The concern of network operators collides with the principle of territorial equity in planning policies. To understand the diffusion of ICT in France, a cartographic analysis of their distribution is proposed. It derives from the notion of networks at three levels: infrastructures, services and uses. The research takes into account the difference between regional configurations to identify the spatial factors of the digital divide. For each level, the diffusion of ICT follows a different logic, and characterizes territories with different orientations. Areas with a high density of population and activities are quickly equipped. The democratization of the use of the Internet, notably with the diffusion of public access to the Internet, is present to a greater degree in low-density areas.     

Barriers perceived to engaging with climate change among the UK public and their policy implications

This paper reports on the barriers that members of the UK public perceive to engaging with climate change. It draws upon three mixed-method studies, with an emphasis on the qualitative data which offer an in-depth insight into how people make sense of climate change. The paper defines engagement as an individual's state, comprising three elements: cognitive, affective and behavioural. A number of common barriers emerge from the three studies, which operate broadly at ‘individual’ and ‘social’ levels. These major constraints to individual engagement with climate change have implications for achieving significant reductions in greenhouse gases in the UK. We argue that targeted and tailored information provision should be supported by wider structural change to enable citizens and communities to reduce their carbon dependency. Policy implications for effective engagement are discussed.     

Reconstitution des apports en éléments traces métalliques et bilan de leur migration dans un Luvisol sableux soumis à 100 ans d'irrigation massive par des eaux usées brutes

Raw wastewaters were massively spread on sandy luvisols near Paris from 1899 to 2002, leading to high trace metals (TM) pollution of soils. Mass balance calculations were performed on a soil profile to assess vertical migration of TM. The contamination was estimated by subtracting the natural pedo-geochemical background of the horizons. TM inputs were estimated using Cr as an invariant. It is shown that Pb and Cr remained in the surface horizon, while Ni, Cd, Cu and Zn migrated downward, being more or less trapped depending on the physicochemical properties of the horizons. To cite this article: C. Dère et al., C. R. Geoscience 338 (2006).     

Determination of the Concentration of Carbonic Species in Natural Waters: Results from a World‐Wide Proficiency Test

The results of an international interlaboratory proficiency test for the determination of carbonic species are presented. Eight laboratories analysed twelve water samples (four synthetic waters, one lake water, four geothermal waters, one seawater and two petroleum waters) by two methods: (a) individual laboratory analytical procedure and (b) acid–base titration curves in tabular form following a standardised protocol. In case (b), the concentrations of carbonic species were calculated by the organiser using the (1) Hydrologists' method, (2) Geochemists' method and/or (3) initial pH and total alkalinity method. For synthetic waters, the averaged % trueness and precision of measurement of the two methods were (trueness = 7.6, precision = 9.4) and (9.0, 3.4) for total alkalinity, and (6.6, 31.0) and (7.8, 6.1) for carbonic alkalinity, respectively. This indicates that the total alkalinity calculation procedure is in general correct in the individual laboratory method, but the carbonic alkalinity calculation procedure has serious problems. The measurements of total alkalinity for lake and seawaters were in agreement in both the methods; however, the individual laboratory measurement method for geothermal and petroleum waters was conceptually incorrect. Thus, the analytical procedures for the determination of carbonic species were reviewed. To apply the Hydrologists' and/or Geochemists' methods, the location of NaHCO₃EP and H₂CO₃EP is necessary, even for samples with pH lower than that of NaHCO₃EP, and a backward titration curve after complete removal of CO₂ must be performed. The initial pH and total alkalinity method is appropriate where a complete analysis of species that contribute to the alkalinity is known.     

Soil moisture-temperature feedbacks at meso-scale during summer heat waves over Western Europe

This paper investigates the impact of soil moisture-temperature feedback during heatwaves occurring over France between 1989 and 2008. Two simulations of the weather research and forecasting regional model have been analysed, with two different land-surface models. One resolves the hydrology and is able to simulate summer dryness, while the other prescribes constant and high soil moisture and hence no soil moisture deficit. The sensitivity analysis conducted for all heatwave episodes highlights different soil moisture-temperature responses (1) over low-elevation plains, (2) over mountains and (3) over coastal regions. In the plains, soil moisture deficit induces less evapotranspiration and higher sensible heat flux. This has the effect of heating the planetary boundary layer and at the same time of creating a general condition of higher convective instability and a slight increase of shallow cloud cover. A positive feedback is created which increases the temperature anomaly during the heatwaves. In mountainous regions, enhanced heat fluxes over dry soil reinforce upslope winds producing strong vertical motion over the mountain slope, first triggered by thermal convection. This, jointly to the instability conditions, favors convection triggering and produces clouds and precipitation over the mountains, reducing the temperature anomaly. In coastal regions, dry soil enhances land/sea thermal contrast, strengthening sea-breeze circulation and moist cold marine air advection. This damps the magnitude of the heatwave temperature anomaly in coastal areas, expecially near the Mediterranean coast. Hence, along with heating in the plains, soil dryness can also have a significant cooling effect over mountains and coastal regions due to meso-scale circulations.     

Dynamical downscaling of IPSL-CM5 CMIP5 historical simulations over the Mediterranean: benefits on the representation of regional surface winds and cyclogenesis

The Mediterranean region is identified as one of the two main hot-spots of climate change and also known to have the highest concentration of cyclones in the world. These atmospheric features contribute significantly to the regional climate but they are not reproduced by the Atmosphere–Ocean General Circulation Models (AOGCM), due to their coarse horizontal resolution, which have recently been run in the frame of the 5th Climate Model Intercomparison Project. This article investigates the benefit of dynamically downscaling the Institut Pierre Simon Laplace (IPSL) AOGCM (IPSL-CM5) historical simulation by the weather and research forecasting (WRF) for the representation of the Mediterranean surface winds and cyclonic activity. Indeed, when considering IPSL-CM5 atmospheric fields, the dramatic underestimation of the cyclonic activity in the most cyclogenetic region of the world jeopardizes our ability to investigate in-depth the Mediterranean regional climate and trend in the context of global change. The WRF model shows remarkable skill to reproduce regional cyclogenesis. Indeed, cyclones occurrence is quasi-absent in IPSL-CM5 data but when applying dynamical downscaling their spatial–temporal variability is very close to the re-analysis. This is a clear benefit of dynamical downscaling in regions of strong topographic forcing. This “steady” source of forcing allows the production of lee cyclogenesis and the development of strong cyclones, whatever the quality of the large-scale circulation provided at the WRF’s boundaries by IPSL-CM5. However, dynamical downscaling still presents disadvantages as for instance the fact that large-scale inaccurate features of the IPSL-CM5 regional circulation are replicated by WRF due to the boundary controlled (small domain) simulation. The advantages and disadvantages of dynamical downscaling are thoroughly discussed in this paper revealing its importance for climate research, especially in the context of future scenarios and wind impacts.