A sediment record of trophic state change in an Arkansas (USA) reservoir

Reservoir sediments are used cautiously in paleolimnological studies because of dating uncertainties, possible sediment disturbances and even concerns that indicators of trophic status may behave differently in reservoirs as opposed to natural lakes. We measured loss on ignition (LOI), carbon to nitrogen ratio (C:N), diatom abundance, total nitrogen (TN), total phosphorus (TP), TN:TP ratio, and carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) in an 83-cm sediment core to track recent trophic status changes in Beaver Reservoir, Northwest Arkansas, USA. Measurements showed that LOI, TN, TP and diatom abundance increased significantly from the bottom to the top of the core (p < 0.001). The C:N ratio and δ¹³C indicated a predominantly algal source for organic matter in the sediments. Increases in TN and TP were positively correlated with human population growth (p < 0.01) and the TN:TP ratio recorded a shift from phosphorus to nitrogen limitation around 1990. This shift may have encouraged cyanobacterial growth that caused episodes of taste and odor problems in the reservoir. This study suggests that despite concerns about sediment dating and disturbance, reservoir sediments can provide valuable information on past water quality changes.     

On the conditions of sheet injections and eruptions in stratovolcanoes

Nearly all eruptions in stratovolcanoes (composite volcanoes, central volcanoes) are supplied with magma through fractures. Consequently, a primary physical condition for an eruption to occur in a stratovolcano is that a magma-driven fracture is able to propagate to the surface. Magma-filled fractures, frozen or fluid, are referred to as sheet intrusions. More specifically, they are named dykes when subvertical, and inclined (or cone) sheets when inclined. Field observations indicate that most sheet intrusions do not reach the surface to feed eruptions but rather become arrested at various crustal depths. For this reason periods of volcanic unrest with sheet injections are much more common than volcanic eruptions. Whether a sheet intrusion becomes arrested or, alternatively, propagates to the surface depends primarily on the stress field in the stratovolcano. A stratovolcano normally consists of layers of contrasting mechanical properties, such as soft (low Youngs modulus) pyroclastic units and stiff (high Youngs modulus) lava flows. We present numerical models indicating that volcanoes composed of such layers commonly develop stress fields encouraging sheet and dyke arrest. The models indicate that a necessary condition for a sheet intrusion to reach the surface and feed a volcanic eruption is that the stress field along the sheet pathway becomes homogenised. We propose that much of the activity in a stratovolcano during a volcanic cycle encourages stress-field homogenisation. Field studies show that the sheet intrusions in individual stratovolcanoes have various dips: some are vertical dykes, others inclined sheets, and still others horizontal sills. Analytical models indicate that the dip of a sheet reaching the surface can have great effects on the magma transport during an eruption. This effect is normally greater for a flat volcano such as a collapse caldera than for a stratovolcano that forms a topographic high. We conclude that the shallower the dip of a sheet intrusion, the less will be its volumetric magma transport to the surface of a stratovolcano.Editorial responsibility: D Dingwell     

Modelling and analysis of attenuation anisotropy in multi-azimuth VSP data from the Clair field

Anisotropic variations in attenuation are of interest since they can give information on the fracture system and may be more amenable to measurement than absolute attenuation values. We examine methods for detecting changes in relative attenuation with azimuth from VSP data, and validate the techniques on synthetic data. Analysis of a multi‐azimuth walkaway VSP data set from a fractured hydrocarbon reservoir indicates that such azimuthal variations in P‐wave attenuation are observable. The effects are localized in the reservoir, and analysis allows the prediction of a fracture strike direction, which agrees with geological information. The observed effects can be modelled under reasonable assumptions, which suggests the validity of the link between the anisotropic attenuation and the fracturing.     

The effect of fluid saturation in an anisotropic multi-scale equant porosity model

It is recognised that exchange of fluid between fractures and the rock matrix can have a strong impact on a rock's anisotropic elastic properties. A recent theoretical advance considers the effect of the scale length of the fractures. We show that under certain circumstances, this model can be simplified. The simplified model matches laboratory data. A prediction of the model is that frequency-dependent effects are important for fluid substitution in the anisotropic case.     

Propagation pathways and fluid transport of hydrofractures in jointed and layered rocks in geothermal fields

Palaeofluid-transporting systems, observed as networks of mineral-filled veins in deeply eroded parts of extinct geothermal fields, indicate that hydrofractures commonly supply fluids to geothermal fields. Here we examine well-exposed vein networks that occur at crustal depths of around 1.5 km below the initial surface of the Tertiary lava pile in North Iceland. The veins are located in the damage zone of a major fault zone that dissects basaltic lava flows, the most common host rocks of geothermal fields in Iceland. The lava flows contain numerous weaknesses, particularly columnar (cooling) joints and contacts. For hydrofractures to supply fluids to geothermal fields, the fractures must be able to propagate, and transport fluids, to the surface. We explore hydrofracture pathway formation using boundary-element models of hydrofractures with fluid overpressure varying linearly from 10 MPa at the fracture centre to 0 MPa at the fracture tip (or the fluid front). The hydrofractures propagate through a vertically jointed and horizontally layered pile of lava flows with a general rock-matrix Young’s modulus of 1×10¹⁰ Pa and a Poisson’s ratio of 0.25. The joints and contacts between layers are modelled as internal springs, each with a stiffness (‘strength’) of 6 MPa/m. The location and sizes of discontinuities, as well as the location of the hydrofracture tip, vary between the models. The results indicate that tensile stresses generated at the tip of an overpressured hydrofracture can open up horizontal and vertical discontinuities out to a considerable distance from the tip, and that these discontinuities eventually link up to form the hydrofracture pathway. Analytical models indicate that for a hot spring of a given yield associated with a fault, the dimensions of the fluid-transporting part of the fault are likely to be similar for a typical normal fault and a strike-slip fault. Also, a hot spring of yield 180 l/s (the maximum in the low-temperature fields of Iceland) can be supplied through a hydrofracture of aperture 3 mm and trace length 1.2 m. These dimensions are very similar to those of typical veins in the studied networks. Buoyancy, rather than excess pressure in the fluid source, appears to be the primary driving force of hydrofractures in the geothermal fields of Iceland.     

Isotopic and molecular composition of coal-bed gas in the Amasra region (Zonguldak basin—western Black Sea)

Previous studies on the coal-bed methane potential of the Zonguldak basin have indicated that the gases are thermogenic and sourced by the coal-bearing Carboniferous units. In this earlier work, the origin of coal-bed gas was only defined according to the molecular composition of gases and to organic geochemical properties of the respective source rocks, since data on isotopic composition of gases were not available. Furthermore, in the western Black Sea region there also exist other source rocks, which may have contributed to the coal-bed gas accumulations. The aim of this study is to determine the origin of coal-bed gas and to try a gas-source rock correlation. For this purpose, the molecular and isotopic compositions of 13 headspace gases from coals and adjacent sediments of two wells in the Amasra region have been analyzed. Total organic carbon (TOC) measurements and Rock-Eval pyrolysis were performed in order to characterize the respective source rocks. Coals and sediments are bearing humic type organic matter, which have hydrogen indices (HI) of up to 300 mgHC/gTOC, indicating a certain content of liptinitic material. The stable carbon isotope ratios (δ¹³C) of the kerogen vary from −23.1 to −27.7‰. Air-free calculated gases contain hydrocarbons up to C₅, carbon dioxide (<1%) and a considerable amount of nitrogen (up to 38%). The gaseous hydrocarbons are dominated by methane (>98%). The stable carbon isotope ratios of methane, ethane and propane are defined as δ¹³C₁: −51.1 to −48.3‰, δ¹³C₂: −37.9 to −25.3‰, δ¹³C₃: −26.0 to −19.2 ‰, respectively. The δD₁ values of methane range from −190 to −178‰. According to its isotopic composition, methane is a mixture, partly generated bacterially, partly thermogenic. Molecular and isotopic composition of the gases and organic geochemical properties of possible source rocks indicate that the thermogenic gas generation took place in coals and organic rich shales of the Westphalian-A Kozlu formation. The bacterial input can be related to a primary bacterial methane generation during Carboniferous and/or to a recent secondary bacterial methane generation. However, some peculiarities of respective isotope values of headspace gases can also be related to the desorption process, which took place by sampling.     

天然气中氮的地球化学特征

本文研究了天然气中氮的地球化学特征，并讨论了氮的成因。     

Climate action for food security in South Asia? Analyzing the role of agriculture in nationally determined contributions to the Paris agreement

The Nationally Determined Contributions (NDCs) submitted under the Paris Agreement propose a country’s contribution to global mitigation efforts and domestic adaptation initiatives. This paper provides a systematic analysis of NDCs submitted by South Asian nations, in order to assess how far their commitments might deliver meaningful contributions to the global 2°C target and to sustainable broad-based adaptation benefits. Though agriculture-related emissions are prominent in emission profiles of South Asian countries, their emission reduction commitments are less likely to include agriculture, partly because of a concern over food security. We find that income-enhancing mitigation technologies that do not jeopardize food security may significantly augment the region’s mitigation potential. In the case of adaptation, analysis shows that the greatest effort will be directed towards protecting the cornerstones of the ‘green revolution’ for ensuring food security. Development of efficient and climate-resilient agricultural value chains and integrated farming bodies will be important to ensuring adaptation investment. Potentially useful models of landscape level climate resilience actions and ecosystem-based adaptation are also presented, along with estimates of the aggregate costs of agricultural adaptation. Countries in the region propose different mixes of domestic and foreign, and public and private, adaptation finance to meet the substantial gaps.

Key policy insights

• Though substantial potential for mitigation of agricultural emissions exists in South Asia, governments in the region do not commit to agricultural emissions reductions in their NDCs.

• Large-scale adoption of income-enhancing technologies is the key to realizing agricultural mitigation potential in South Asia, whilst maintaining food security.

• Increasing resilience and profitability through structural changes, value chain interventions, and landscape-level actions may provide strong options to build adaptive capacity and enhance food security.

• Both private finance (autonomous adaptation) and international financial transfers will be required to close the substantial adaptation finance gap

     

Laminated tufa sediments formed from overflow karst springs: Controls on their deposition and carbon–oxygen isotope records

Tufa sediments are freshwater carbonates that precipitate in karst regions after degassing of carbon dioxide from groundwater in contact with the atmosphere. When laminated, these carbonates can provide high‐resolution records for the study of climate, hydrological and environmental conditions at the time of their precipitation. The formation of these carbonates directly depends on the hydrological regime, and in karst regions discontinuous discharges are often recorded. This study investigates the record of recent laminated tufa sediments precipitated downstream overflow springs in Trabaque Canyon (central Spain). The hydrological dynamics of the karst system were monitored for over three years and a stable isotope record was obtained from laminated tufa carbonates precipitated from an overflow spring. Additionally, a hydrological model of overflow springs was generated and a tufa δ¹⁸O record under constrained parameters was simulated. Temperature is the dominant control of the variation in tufa δ¹³C and δ¹⁸O values within each lamina, although when comparing different laminae, δ¹³C_DIC and δ¹⁸O of river water are also major controls. The positive correlation between tufa δ¹³C values and water temperature is caused by the fractionation occurred by carbon dioxide degassing due to the thermal dependence of carbon dioxide solubility. Additionally, the system recorded a temperature‐independent degassing process caused by the large gradient between groundwater and atmospheric carbon dioxide that is limited to the proximity of the spring. This study cautions on the risk of assuming continuous deposition when studying laminated tufa sediments and highlights the potential of their stable isotope records to provide hydrological information of their aquifers during the past.