Anomalous content of chromium in a Cretaceous sandstone aquifer of the Bauru Basin,state of São Paulo,Brazil

Anomalous and natural concentrations of Cr⁶⁺, occasionally exceeding the permitted limit for human consumption (0.05 mg/L), have been detected in groundwater in the northwestern region of the state of São Paulo. As part of a water-rock interaction investigation, this article describes the chemical and mineralogical characterization of rock samples taken from boreholes in the municipality of Urânia, with the objective of identifying Cr-bearing minerals and determining how chromium is associated with these minerals. Rock sample analysis were performed using X-ray Fluorescence, X-ray Diffraction, Scanning Electron Microscopy, electron microprobe and sequential extraction techniques. Chemical analyses indicated that the quartzose sandstones show a geochemical anomaly of chromium, with an average content of 221 ppm, which is higher than the reported chromium content of generic sandstones (35 ppm). Diopside was identified as the primary Cr-bearing mineral potentially subject to weathering processes, with a chromium content of up to 1.2% as Cr₂O₃. Many of the diopside grains showed dissolution features, confirming the occurrence of weathering. Sequential extraction experiments indicated that 99.3% of the chromium in samples is tightly bonded to minerals, whereas 0.24% is weakly bonded via adsorption. Assuming hypothetically that all adsorbed chromium is released via desorption, the theoretical Cr concentration in water would be one order of magnitude higher than the concentrations of Cr⁶⁺ detected in groundwater.     

A spatter-forming, large-scale paroxysm at Stromboli Volcano (Aeolian Islands, Italy): insight into magma evolution and eruption dynamics

This study focuses on a pyroclastic sequence related to a large-scale paroxysm that occurred during the seventeenth century ad and which can be considered one of the most powerful and hazardous explosive events at the volcano in the past few centuries. Paroxysms are energetic, short-lived explosions which sporadically interrupt normal Strombolian activity at Stromboli and commonly erupt a deep-derived, volatile-rich crystal-poor high-potassium basalt (“low porphyricity” (LP)), together with a shallow, degassed crystal-rich high-potassium to shoshonitic basalt (“high porphyricity” (HP)), which feed normal activity at the volcano. The studied deposit, crops out along the flanks of Sciara del Fuoco and, from base to top, consists of: (1) a layer of HP and LP ash and lapilli; (2) an unwelded layer of coarse HP lapilli and flattened dark scoriae; (3) weakly welded spatter made up of dense HP pyroclasts at the base, overlain by strongly vesicular LP clasts. The textural and chemical zoning of minerals and the glass chemistry of the LP products record repeated mafic recharge events, mixing with an old mushy body and episodes of rapid crystallization due to sudden degassing. Collapse of a foam layer originated by deep degassing probably triggered this large-scale, spatter-forming paroxysm. Decompression induced rapid degassing and vesiculation of the deep volatile-rich magma. The rapid ascent of the foamy magma blob pushed the shallow HP magma out and finally produced a fire fountain that emplaced the LP portion of the spatter.     

Benthic foraminifera and geochemical studies with influence on pollution studies along the coast of Cuddalore,Tamil Nadu-ITS,India

Foraminifers, being sensitive to minute changes, either undergo morphological changes or even disappear from the area completely due to pollution or under unfavourable conditions. The characteristics of foraminifers to incorporate the signature of presence of pollutants are considered to be an effective tool for temporal pollution monitoring studies. Totally, 12 offshore samples (both sediment and water) were taken along a normal profile along the coast of Cuddalore for pollution studies. Apart from foraminiferal studies, geochemical studies of the sediments collected are also undertaken to correlate and substantiate the findings. The near-shore area has a higher concentration of trace elements. If these concentrations exceed or go below permissible limits, it is collateral for the marine community and for those who consume these marine resources. The concentration of trace elements like lead, zinc, manganese, copper, chromium and nickel was illustrated to give an idea of the trace element concentration of the study area. The sedimentological studies reveal the organic matter and calcium carbonate content of the samples, and the bottom water measurements reveal the temperature, salinity and dissolved oxygen of sample locations. These are used to determine whether the conditions prevailing could sustain life. The ratio of living to dead species is also determined and correlated with sedimentological and geochemical parameters. Pollution studies have given way to identify morphological abnormalities in the species mainly in Spiroloculina, Quinqueloculina, Elphidium, etc. but we could not find many effects among the faunal assemblages because of the nature of the sediments found in that area.     

Influence of the hyporheic zone on the phosphorus dynamics of a large gravel‐bed river,Garonne River,France

Phosphorus (P) concentrations in sediments and in surface and interstitial water from three gravel bars in a large river (Garonne River, southern France) were measured daily, downstream of a wastewater treatment plant for a city of 740 000 inhabitants (Toulouse). Measurements were made of vertical hydraulic gradient (VHG), total dissolved phosphorus (TDP), soluble reactive phosphorus (SRP) and total phosphorus (TP) in water and of three extractable forms of phosphorus (water extractable, NaOH extractable and H₂SO₄ extractable) in hyporheic sediments from the gravel bars. Dissolved phosphorus was the major contributor to TP (74–79%) in both interstitial and surface waters on all sampling dates, and in most cases surface water P concentrations were significantly higher than interstitial concentrations. Hyporheic sediment TP concentrations ranged between 269 and 465 µg g^?1 and were highest in fine sediment fractions. Acid‐extractable P, a non‐bioavailable form, represented at least 95% of sediment TP. A positive relationship was observed between VHG and TP in two of the gravel bars, with wells that were strongly downwelling having lower TP concentrations. These results suggest that in downwelling zones, hyporheic sediments can trap surface‐derived dissolved P, and that much of this P becomes stored in refractory particulate forms. Bioavailable P is mainly present in dissolved form and only occupies a small fraction of total P, with particulate P comprising the majority of total P. Copyright © 2009 John Wiley & Sons, Ltd.     

GIS-based spatial prediction of debris flows using logistic regression and frequency ratio models for Zêzere River basin and its surrounding area,Northwest Covilhã, Portugal

Landslide susceptibility mapping (LSM) is important for catastrophe management in the mountainous regions. They focus on generating susceptibility maps beginning from landslide inventories and considering the main predisposing parameters. The aim of this study was to assess the susceptibility of the occurrence of debris flows in the Zêzere River basin and its surrounding area using logistic regression (LR) and frequency ratio (FR) models. To achieve this, a landslide inventory map was created using historical information, satellite imagery, and extensive field works. One hundred landslides were mapped, of which 75% were randomly selected as training data, while the remaining 25% were used for validating the models. The landslide influence factors considered for this study were lithology, elevation, slope gradient, slope aspect, plan curvature, profile curvature, normalized difference vegetation index (NDVI), distance to roads, topographic wetness index (TWI), and stream power index (SPI). The relationships between landslide occurrence and these factors were established, and the results were then evaluated and validated. Validation results show that both methods give acceptable results [the area under curve (AUC) of success rates is 83.71 and 76.38 for LR and FR, respectively]. Furthermore, the AUC results for prediction accuracy revealed that LR model has the highest predictive performance (AUC of predicted rate?=?80.26). Hence, it is concluded that the two models showed reasonably good accuracy in predicting the landslide susceptibility in the study area. These two models have the potential to aid planners in development and land-use planning and to offer tools for hazard mitigation measures.     

Analysis of a GPS Network Based on Functional Data Analysis

This paper demonstrates the usefulness of approaching the dynamic study of the precise positioning of a network of permanent global positioning system (GPS) stations through functional data analysis. The displacement data for each GPS station, obtained from observations of the global navigation satellite system, are a discrete sample of the positioning curve. The aim of this paper is to reconstruct the original functions in order to use them as functional data. In the method presented in this paper, the geodetic series are obtained first by processing the GPS data with respect to a reference station. Second, for each station, a cleaning process is applied to eliminate the values considered as outliers, and the missing values are imputed by using a Kalman filter. Finally, the original functions are reconstructed by using smoothing techniques and by evaluating several bases of functions. Moreover, these functions are treated with statistical techniques for functional data. This procedure is applied to the permanent stations of the south of the Iberian peninsula and the north of Africa (SPINA) network. The topocentric series: east, north and up are analysed. In the analysis of the positioning curves, there is observed a synchronized behaviour of the functions in those periods of time with important seismic activity. This behaviour also appears in the analysis of the second principal component of the East and up dimensions. Furthermore, the first two principal components of the East coordinate enable us to make a classification of the stations in the SPINA network. The classification made is consistent with the previous knowledge of the tectonic plates in the studied area.