Petrochemistry of sandstones from Neoproterozoic basins of the Bastar craton, Central Indian Shield: Implications for paleoweathering, provenance and tectonic history

Petrographic analysis and chemical analysis of major and trace elements including rare earth elements of the Neoproterozoic sandstones from the Chandarpur Group and the Tiratgarh Formation have been carried out to determine their provenance, tectonic setting and weathering conditions. All sandstone samples are highly enriched in quartz but very poor in feldspar and lithic fragments. Petrographically and geochemically these sandstones are classified as subarkose, sublitharenite and arenite. The Chemical Index of Alteration (CIA mean 68) and Th/U ratios (mean 4.2) for these sandstones suggest their moderate weathering nature. Generally, all sandstone samples are strongly depleted in major elements (except SiO₂), trace elements (except Zr) and REE in comparison with Post Archean Australian Shale (PAAS) and Upper Continental Crust (UCC). Their mineralogy and mean of elemental ratios suitable for determination of provenance and tectonic setting, e.g. Al₂O₃/SiO₂ (0.02), K₂O/Na₂O (10), Eu/Eu* (0.67), (La/Lu)n (10.4), La/Sc (3), Th/Sc (1.2), La/Co (0.22), Th/Co (0.08), and Cr/Th (7.2), support a felsic source and a passive margin tectonic setting for these sandstones. Also these key elemental ratios do not show much variation over a range of SiO₂. Thus we attest their significance in determining source rock characteristics of quartz rich sandstones. Chondrite‐normalized REE patterns with LREE enrichment and a strong negative Eu anomaly are also attributed to felsic source rock characteristics for these sandstones. The source rocks identified are granite and gneiss of the Bastar craton. Minor amounts may have been derived from older supracrustals of the Bastar craton. However, the major element data of the Paleoproterozoic Sakoli schists when compared with those of the Neoproterozoic sandstones indicate that the schists were derived from a mafic source and deposited in an active continental margin tectonic setting. There is, however, little difference in CIA values between the Paleoproterozoic Sakoli schists and Neoproterozoic sandstones, indicating prevailing of similar (moderate‐intense) weathering conditions throughout the Proterozoic in the Bastar craton. Our study also suggests a change in the provenance and tectonic setting of deposition of sediments from dominantly a mafic source and an active continental margin in the Paleoproterozoic to dominantly granite and gneiss (felsic source) and a passive continental margin in the Neoproterozoic in the Bastar craton.     

Palaeocurrent and environmental implications from anisotropy of magnetic susceptibility (AMS): a case study from Talchir and Barakar formations,Raniganj Basin,West Bengal,India

Oriented cylindrical cores of rock samples were collected from the Talchir and Barakar formations of the Lower Gondwana Supergroup of the Raniganj Basin exposed in and around Kalyaneshwari and Maithon areas. The cores (2.54 cm diameter and 2.2 cm height) were studied in the low field anisotropy of magnetic susceptibility (AMS) measurement to determine the nature of magnetic fabrics, to correlate it with the sedimentological characteristics and to determine the palaeocurrent patterns. The results derived from the statistical parameters (especially the q-factor), the shapes of the susceptibility ellipsoids and directional data of the AMS indicate that the magnetic fabrics within the studied units are primary (depositional) and are correlatable form the palaeoenvironmental features. The orientation of the maximum (K₁), intermediate (K₂) and minimum (K₃) susceptibility axes is dispersed on the lower hemisphere equal area diagram rather than strong clusters which is not because of secondary (tectonic) influence but due to the moderate to high-energy environment of deposition of the sediments in the studied units. Based on the q-factor (which is 0.581 for Barakar Formation and 0.565 for Talchir Formation which are both <?0.7), it is suggested the AMS indicates that the imbrication of the K₁ axis is the indicator of palaeocurrent. Also, the magnetic foliation (average value?=?1.255) exceeds the magnetic lineation (average value?=?1.107) and the shape parameter exceeds 0 in most cases pointing towards an oblate fabric. The palaeocurrent in the present study as indicated by the K₁ axis imbrication is very similar in both the units under study and is due SW. However, apart from this precise palaeocurrent direction, there exists a certain degree of randomness of the susceptibility axes which are very clear indication of corresponding depositional environments.     

A comparison of two techniques for calculating groundwater arsenic-related lung,bladder and liver cancer disease burden using data from Chakdha block,West Bengal

Calculation of excess disease burden for As exposed populations is becoming increasingly important to enable quantitative estimation of the impacts of various As mitigation options. There are several methods by which such calculations may be carried out. In this study, two methods, recently applied to estimating groundwater As-related health risks in southern Asia, to estimate disease burden arising from lung, bladder and liver cancer from As exposure for an As-effected area of West Bengal have been compared. Both utilized calculated distributions of exposure of the studied population to As from groundwater. Method (I) then entailed calculating disease burden by combining published background rates for death and disability adjusted life years (DALYs) and standard mortality ratios (SMRs) for excess health impacts related to As exposure, whilst for Method (II), disease burden from As exposure was estimated using the basic DALY formula, combined with incidence rates based on the NRC multistage Weibull model. Dose–response data for both methods were based on studies in Taiwan.     

Evolution of the Archean-Palaeoproterozoic Bundelkhand Massif, central India—evidence from granitoid geochemistry

The Bundelkhand massif of Archean-Palaeoproterozoic age is primarily a granite-gneiss complex. Three distinct granitoid suites have been identified within the massif hornblende granitoids, biotite granitoids and leucogranitoids, in order of decreasing age. These granitoids were emplaced in previously deformed basement consisting of gneisses, banded iron formations and other metasediments, mafic to felsic volcanics.
The granitoids exhibit a large compositional range from quartz diorite to syenogranite and show a calc-alkaline trend. They are metaluminous to peraluminous and have I-type characteristics. The SiO₂ content ranges from 49 to 77 wt%. Low K₂O/Na₂O characterizes the granitoids. The oldest hornblende granitoids have low Rb and Yb contents compared to the younger biotite granitoids and leucogranitoids. Rb/Sr values for most of the granitoids are low (< 1). K/Rb ratios range from 95 to 373 which is, in general, comparable with other calc-alkaline suites. Y/Nb ratios of the granitoids are > 1.2 which is a characteristic feature of magmas derived from sources chemically similar to island arc or continental margin basalts.
The features mentioned above coupled with concentrations of Rb, Y, Nb, Yb, Ta and Th indicate a volcanic-arc tectonic setting for the granitoids. It is proposed that the massif represents subduction-related magmatism of an ocean in the southern part of the massif (an Andean plate margin).     

Spectral signatures of dissipative standing shocks and mass outflow in presence of Comptonization around a black hole

Accretion flows having positive specific energy are known to produce outflows and winds which escape to a large distance. According to Two Component Advective Flow (TCAF) model, centrifugal pressure dominated region of the flow just outside the black hole horizon, with or without shocks, acts as the base of this outflow. Electrons from this region are depleted due to the wind and consequently, energy transfer rate due to inverse Comptonization of low energy photons are affected. Specifically, it becomes easier to cool this region and emerging spectrum is softened. Our main goal is to show spectral softening due to mass outflow in presence of Compton cooling. To achieve this, we modify Rankine-Hugoniot relationships at the shock front when post-shock region suffers mass loss due to winds and energy loss due to inverse Comptonization. We solve two-temperature equations governing an accretion flow around a black hole which include Coulomb exchange between protons and electrons and other major radiative processes such as bremsstrahlung and thermal Comptonization. We then compute emitted spectrum from this post-shock flow. We also show how location of standing shock which forms outer boundary of centrifugal barrier changes with cooling. With an increase in disc accretion rate \((\dot{m}_{d})\) , cooling is enhanced and we find that the shock moves in towards the black hole. With cooling, thermal pressure is reduced, and as a result, outflow rate is decreased. We thus directly correlate outflow rate with spectral state of the disc.     

A diagnosis of groundwater quality from a semiarid region in Rajasthan,India

A diagnosis of the groundwater quality of 70 wells sampled during two climatic regimes (dry and raining seasons) from a semiarid area in Rajasthan, India, had been carried out using standard methods. Analysis of the results for various hydrochemical parameters wherein the geological units are alluvium, quartzite and granite gneisses showed that all the parameters did not fall within the World Health Organisation’s acceptable limits for irrigation and drinking water purposes. The order of major cations and anions obtained during the dry and raining seasons are Na⁺ ? Mg²⁺ ? Ca²⁺ ? K⁺ and Cl^?? HCO₃ ^? ? SO₄ ^2?? CO₃ ^?> F^? ? NO₃ ^?, respectively. A maximum value of nitrate of 491.6 mg/l has been examined and its contamination is due to discriminated highly impacted groundwater samples by agricultural activity and small-scale urbanization. Fluoride (F^?) concentration is 6.50 mg/l as a maximum value, whereas values in about 26 % of the samples are more than the permissible limit (1.5 mg/l) for drinking water. The cumulative probability distributions of the selected ions show two individual intersection points with three diverse segments, considered as regional threshold values and highly impacted threshold values for differentiating the samples with the effects of geogenic, anthropogenic and saline water mixing. The first threshold values indicate the background hydrochemical constituents in the study area. The second threshold value of 732 mg/l for bicarbonate indicates that sandy aquifer is being dissolved during wet period, whereas NO₃ ^? concentration of more than the initial threshold value (=75 mg/l) indicates discriminated highly impacted groundwater samples by agricultural activity and urbanization in dry season. Various parameters such as soluble sodium percentage (SSP), salinity (electrical conductivity (EC)), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), Kelley’s ratio (KR), permeability index (PI), residual sodium bicarbonate (RSB) and magnesium absorption ratio (MAR) for the well samples show that, overall, 46 % of groundwater samples are not suitable for irrigation. Further, chloro-alkaline indices (CAIs) were used for distinguishing regional recharge and discharge zones whereas corrosivity ratio (CR) utilized for demarcating areas to use metallic pipes for groundwater supply. In general, groundwater quality is mainly controlled by the chemical weathering of rock-forming minerals. The information obtained represents a base for future work that will help to assess the groundwater condition for periodical monitoring and managing the groundwater from further degradation.     

Expulsion of magnetic flux lines from the growing superconducting core of a magnetised quark star

The expulsion of magnetic flux lines from a growing superconducting core of a quark star has been investigated. The idea of impurity diffusion in molten alloys and an identical mechanism of baryon number transport from hot quark-gluon-plasma phase to hadronic phase during quark-hadron phase transition in the early universe, micro-second after big bang has been used. The possibility of Mullins-Sekerka normal-superconducting interface instability has also been studied.     

Gold - sulphide mineralization in ultramafic-mafic-granite complex of Jashpur,Bastar craton,central India: Evidences from geophysical studies

Time Domain Induced Polarization (TDIP) investigation in conjunction with high resolution electrical resistivity tomography surveys carried out at seven sites along a 5.2 km line in Jashpur and Raigarh districts of Chhattisgarh State yielded promising results leading to the demarcation of mineralized zones. These sites are confined to ultramafic-mafic-felsic intrusive complexes representing gabbro-pyroxenite-granite sequences characterized by gold - sulphide mineralization. Two dimensional (2D) geophysical datasets yielded interesting results and a good correlation is found between 2D inverted resistivity tomography and time domain induced polarization (IP) models. Both high resistivity-high chargeability as well as low resistivity-high chargeability conditions have been inferred from these datasets. This observation is consistent with conductive metallic mineralization. Interpretation of the Pharsabahar-Pandripani site, reveals a chargeability magnitude of 9-14 mV/V, which represents a strong metallic conductor associated with gold-sulphide ore body. The results at Samarkachar site are equally significant, showing a good correlation with the presence of a low resistivity and high chargeability zone. Hence, the present study suggests a new scope for application of resistivity and IP tomography surveys for mineral prospecting in favourable geological settings.     

Impact of Higher Frequency Content of Input Motion Upon Equivalent Linear Site Response Analysis for the Study Area of Delhi

While travelling through the subsoil layers, earthquake generated bedrock motions get modified significantly due to local soil and should be quantified using ground response analysis. Present study concentrates on equivalent linear method of site response analysis in SHAKE2000 software. It is a frequency based analysis tool having default frequency set to 15 Hz. While due consideration is given to amplitude, no to very limited information about the frequency content of the input motion to be considered in ground response analysis is available. In the present work, the effect of the maximum frequency of ground motion in site response analysis using SHAKE2000 is examined. Two sets of analyses are carried out in this work based on 30 globally recorded input motions. In the first analyses, input motion up to 15 Hz maximum frequency, which is a default value in SHAKE2000 is considered while second analyses are based on considering each of the 30 input motions up to the Nyquist frequency. Comparing the results from the two sets of analyses highlight that selection of maximum frequency in SHAKE2000 has considerable effect in ground motion amplification at different depths. As a result, even the peak ground acceleration which controls the building behavior and damage scenario, is going to change considerably even in case same input motion is used in the analysis.