Treatment of Arsenic Contaminated Groundwater Using Calcium Impregnated Granular Activated Carbon in a Batch Reactor: Optimization of Process Parameters

This paper is an experimental investigation into the removal of arsenic species from simulated groundwater by adsorption onto Ca²⁺ impregnated granular activated carbon (GAC‐Ca) in the presence of impurities like Fe and Mn. The effects of adsorbent concentration, pH and temperature on the percentage removal of total arsenic (As(T)), As(III) and As(V) have been discussed. Under the experimental conditions, the optimum adsorbent concentration of GAC‐Ca was found to be 8 g/L with an agitation time of 24 h, which reduced As(T) concentration from 188 to 10 μg/L. Maximum removal of As(V) and As(III) was observed in a pH range of 7–11 and 9–11, respectively. Removal of all the above arsenic species decreased slightly with increasing temperature. The presence of Fe and Mn increased the adsorption of arsenic species. Under the experimental conditions at 30°C, the maximum percentage removals of As(T), As(III), As(V), Fe, and Mn were found to be ca. 94.3, 90.6, 98.0, 100 and 63%, respectively. It was also observed that amongst the various regenerating liquids used, a 5 N H₂SO₄ solution exhibited maximum regeneration (ca. 91%) of the spent GAC‐Ca.     

Higher order corrections to dust-acoustic ZK-solitons in a magnetized quantum dusty plasma

Nonlinear propagation of two dimensional dust-acoustic solitary waves in a magnetized quantum dusty plasma whose constituents are electrons, ions, and negatively charged heavy dust particles are investigated using quantum hydrodynamic model. The Zakharov-Kuznetsov (ZK) equation is derived by using reductive perturbation technique (RPT). The higher order inhomogeneous ZK-type differential equation is obtained for the correction to ZK- soliton. The dynamical equation for dressed soliton is solved by using renormalization method. The effects of obliqueness (l _x ) of the wave vector, magnetic field strength (B ₀), quantum parameter for ions (H _i ), soliton velocity (θ) and Fermi temperature ratio (σ) on amplitudes and widths of the ZK-soliton and as well as of the dressed soliton are investigated. The conditions for the validity of the higher order correction are described. Suitable parameter ranges for the existence of compressive and rarefactive dressed solitons are also discussed.     

TAOS – The Taiwanese‐American Occultation Survey

The Taiwanese‐American Occultation Survey (TAOS) seeks to determine the number and size spectrum for small (∼3 km) bodies in the Kuiper Belt. This will be accomplished by searching for the brief occultations of bright stars (R ∼ 14) by these objects. We have designed and built a special purpose photometric monitoring system for this purpose. TAOS comprises four 50 cm telescopes, each equipped with a 2048 × 2048 pixel CCD camera, in a compact array located in the central highlands of Taiwan. TAOS will monitor up to 2 000 stars at 5 Hz. The system went into scientific operation in the autumn of 2005. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Effects of convective available potential energy,temperature and humidity on the variability of thunderstorm frequency over Bangladesh

Theoretical and Applied Climatology - The present study examines the effects of convective available potential energy (CAPE), temperature and humidity on the spatiotemporal variation of...     

PGE geochemistry of low-Ti high-Mg siliceous mafic rocks within the Archaean Central Indian Bastar Craton: implications for magma fractionation

Boninite-norite (BN) suites emplaced in an intracratonic setting in Archaean Cratons, are reported from many parts of the world. Such high-Mg low-Ti siliceous rocks are emplaced during Neoarchaean-Paleoproterozoic. The Archaean central Indian Bastar Craton also contains such a boninite-norite suite, which occurs in the form of dykes and volcanics. The spatial and temporal correlation of these high-Mg low-Ti siliceous rocks with similar rocks occurring around the northern Bastar and Dharwar Cratons probably represent a Bastar-Dharwar Large Igneous Province during the Neoarchaean-Paleoproterozoic. Platinum group element (PGE) abundances in these rocks provide constraints on their geochemical evolution during the Neoarchaean-Paleoproterozoic. The PGE geochemistry of the boninite-norite suite from the southern part of the central Indian Bastar Craton is presented to understand their behaviour during magma fractionation. In primitive mantle-normalized plots all samples have similar PGE fractionated patterns that are enriched in Pd, Pt and Rh relative to Ru. The Pd/Ru ratios for eight samples range from 2.0 to 7.0 which is higher than primitive mantle (primitive mantle Pd/Ru ≈1.2). The Pd/Pt ratios range between 0.2–2.5 with an average value of 0.7 which is near chondritic (primitive mantle Pd/Pt ≈0.5). PGE variations in these rocks together with those of major and other trace elements are consistent with a model involving olivine fractionation along with chromite as a cotectic phase. The Pt fractionation from Pd and Rh is controlled by both olivine and chromite crystallization at an early stage during high temperature crystal fractionation when the Pt was strongly compatible and Pd and Rh were incompatible. Strong negative correlations of the S content with iron and TiO₂ plus lithophile element contents of the rock suggest a decrease of the S solubility in the parental high-Mg magma and separation of an immiscible sulfide liquid with decreasing temperature. Palladium plus other available chalcophile elements (e.g., Re, Au, Ag) have been fractionated in this immiscible sulfide liquid after considerable olivine fractionation of the magma.     

Long waves due to a symmetrical wind stress on the surface of a rotating ocean

Abstract

The problem of unsteady long waves generated by any horizontal and symmetrically distributed, time-periodic surface wind on a rotating ocean is analysed for large times and distances. Uniform asymptotic estimates of the surface displacement in the unsteady state are obtained. The steady-state wave and velocity fields at any distance are also determined. Some characteristics of the unsteady and steady motions are described. Also noted are the features that distinguish the motion from its one-dimensional analogue for which a non-uniform analysis in the unsteady state along with a large-distance form of the surface elevation are already known.     

Studies of accretion flows around rotating black holes – II. Standing shocks in the pseudo-Kerr geometry

Standing, propagating or oscillating shock waves are common in accretion and winds around compact objects. We study the topology of all possible solutions using the pseudo-Kerr geometry. We present the parameter space spanned by the specific energy and angular momentum and compare it with that obtained from the full general relativity to show that the potential can work satisfactorily in fluid dynamics also, provided the polytropic index is suitably modified. We then divide the parameter space depending on the nature of the solution topology. We specifically study the nature of the standing Rankine–Hugoniot shocks. We also show that as the Kerr parameter is increased, the shock location generally moves closer to the black hole. In future, these solutions can be used as guidelines to test numerical simulations around compact objects.     

Integrated approach for identification of potential groundwater zones in Seethanagaram Mandal of Vizianagaram District,Andhra Pradesh,India

Identifying a good site for groundwater exploration in hard rock terrain is a challenging task. In hard rocks, groundwater occurs in secondary porosity developed due to weathering, fracturing, faulting, etc., which is highly variable within short distance and contributing to near-surface inhomogeneity. In such situations topographic, hydrogeological and geomorphological features provide useful clues for the selection of suitable sites. Initially, based on satellite imagery, topographical, geomorphological and hydrogeological features, an area of about 149 km² was demarcated as a promising zone for groundwater exploration in the hard rock tract of Seethanagaram Mandal, Vizianagaram District, Andhra Pradesh, India. A total of 50 Vertical Electrical Soundings (VES) were carried out using Wenner electrode configuration. An interactive interpretation of the VES data sharpened the information inferred from geomorphological and hydrogeological reconnaissance. Ten sites were recommended for drilling. Drilling with Down-The-Hole Hammer (DTH) was carried out at the recommended sites down to 50 to 70 m depths. The interpreted VES results matched well with the drilled bore well lithologs. The yields of bore wells vary from 900 to 9000 liters per hour (lph).