The genesis of sediment-hosted,exhalative zinc + lead deposits

Large sediment-hosted lead+zinc deposits like Mount Isa, McArthur River, Navan, Rammelsberg and Sullivan form a distinctive group characterised by stratiform, syngenetic sulphide ores that formed in local basins on the sea floor as a result of protracted hydrothermal activity accompanying continental rifting. Generally there is a development of a sedimentary pre-ore phase mineralization often featuring manganese followed by zinc±lead, iron and chert. Lower main phase zinc+lead lenses are usually almost devoid of copper but Cu tenors increase toward the middle or top of the ore sequences. Hanging wall trace element haloes are common. These characteristics are accounted for by deriving the ore solutions from subsurface convective circulation of modified highly saline seawater. The circulation is initiated during rifting and driven by a high geothermal gradient. As a result of continued extensional strain and cooling of the rock column the brittle-to-ductile transition zone is depressed and the circulation penetrates to greater depth with time. Of the ore metals the downward-penetrating convection fluids first leach and transport zinc and lead, but with increasing temperature are later able to leach and transport some copper. Unless convective circulation ceases the metal sequence generally reverses as the cooling phase sets in. The minimum distance separating major coeval orebodies of this type is 18 km which is a function of the size of the convective systems.     

Trapping Ionic Mercury Using Different Adsorbents

Of recent, adsorption process has gained a lot of attention as a cheap and effective means of removing trace metals from wastewater prior to discharge into water bodies. Being flexible in design and operation, the process has enabled an optimal recovery of trace metals such that the treated effluents meet the desired standards for waste disposal. Mercury is a toxicant released into the environment from natural and anthropogenic sources. It is notorious for having an unusual tendency to bio‐accumulate and persist in the food chain. Presence of mercury in food, especially those of aquatic sources has drastic implications on human health. Therefore, efforts have been made to develop and optimize low‐cost activated carbon (AC) as adsorbents for scavenging mercury from aqueous effluents. Herein, how mercury accumulates across the food chain, its health implications, and the recent advancement in the use of low‐cost ACs as adsorbent for trapping mercury from wastewater are highlighted. Relationship between the mercury removal efficiency and the surface morphology of the adsorbents as well as the influence of prevailing experimental condition on the sorption process were addressed. Challenges and future prospects of the use of low‐cost adsorbents in addressing mercury pollution in the environment are discussed.     

Issues in sediment toxicity and ecological risk assessment

This paper is based on a facilitated Workshop and Roundtable Discussion of key issues in sediment toxicology and ecological risk assessment (ERA) as applied to sediments that was held at the Conference on Dredged Material Management: Options and Environmental Considerations. The issues addressed included how toxicity is defined and perceived, how it is measured, and how it should be used within the context of ERA to support management decisions. The following conclusions were reached regarding scientific considerations of these issues. Toxicity is a measure of hazard and not a risk per se. Thus, toxicity testing is a means but not the end to understand risks of sediments. Toxicity testing cannot presently be replaced by chemical analyses to define hazard. Toxicity test organisms need to be appropriate to the problem being addressed, and the results put into context relative to both reference and baseline comparisons to understand hazard. Use of toxicity tests in sediment ERAs requires appropriate endpoints and risk hypotheses, considering ecological not just statistical significance, and recognizing that hazard does not equate to risk. Toxicity should be linked to population and community response to support decision-making, assessing possible genotypic adaptations that can influence risk estimates, and addressing uncertainty. Additionally, several key scientific issues were identified to improve future sediment ERAs, including the need to improve basic understanding of ecological mechanisms and processes, recognition of variability in the assessment process, and an improved focus and ability to assess risks to populations and communities.     

Land restoration in food security programmes: synergies with climate change mitigation

Food-insecure households in many countries depend on international aid to alleviate acute shocks and chronic shortages. Some food security programmes (including Ethiopia’s Productive Safety Net Program–PSNP – which provides a case study for this article) have integrated aid in exchange for labour on public works to reduce long-term dependence by investing in the productive capacity and resilience of communities. Using this approach, Ethiopia has embarked upon an ambitious national programme of land restoration and sustainable land management. Although the intent was to reduce poverty, here we show that an unintended co-benefit is the climate-change mitigation from reduced greenhouse gas (GHG) emissions and increased landscape carbon stocks. The article first shows that the total reduction in net GHG emissions from PSNP’s land management at the national scale is estimated at 3.4 million?Mg?CO₂e?y^?1 – approximately 1.5% of the emissions reductions in Ethiopia’s Nationally Determined Contribution for the Paris Agreement. The article then explores some of the opportunities and constraints to scaling up of this impact.

Key policy insights

• Food security programmes (FSPs) can contribute to climate change mitigation by creating a vehicle for investment in land and ecosystem restoration.

• Maximizing mitigation, while enhancing but not compromising food security, requires that climate projections, and mitigation and adaptation responses should be mainstreamed into planning and implementation of FSPs at all levels.

• Cross-cutting oversight is required to integrate land restoration, climate policy, food security and disaster risk management into a coherent policy framework.

• Institutional barriers to optimal implementation should be addressed, such as incentive mechanisms that reward effort rather than results, and lack of centralized monitoring and evaluation of impacts on the physical environment.

• Project implementation can often be improved by adopting best management practices, such as using productive living livestock barriers where possible, and increasing the integration of agroforestry and non-timber forest products into landscape regeneration.

     

Shallow Water Dissipation Processes for Wind Waves off the Mackenzie Delta

This study focuses on two physical processes for waves in shallow waters off the Mackenzie Delta: bottom friction and depth-induced breaking terms. We use field observations of winds and waves, the state-of-the-art Simulating Waves Nearshore (SWAN) model, and reanalysis wind and wave data. The two field observation periods are an August 2008 field experiment, during which in situ field data were collected, and an Arctic storm when data were recorded by buoy measurements from 4 to 6 August 1991. Wind and wave development processes are analyzed during these two periods with comparisons to observed winds and waves. Our analyses show that bottom friction is the main shallow water physical process during the August 2008 field experiment, whereas depth-induced breaking is the dominant shallow water physical process during the 4–6 August 1991 storm, in conjunction with the effects of bottom friction. The SWAN wave model is used to investigate the shallow water physical processes during these two observation periods. Simulation results indicate that the model can give reasonable results, with an appropriate Collins coefficient of 0.006 and a wave breaking parameter of 0.55 to represent bottom friction and depth-induced breaking physics, respectively.

RÉSUMÉ?[Traduit par la rédaction] Cette étude porte sur deux processus physiques concernant les vagues dans les eaux peu profondes au large du delta du Mackenzie : les termes du frottement contre le fond et du déferlement lié à la profondeur. Nous utilisons des observations du vent et des vagues, le modèle d'avant-garde SWAN (Simulating Waves Nearshore) et des données de vent et de vagues réanalysées. Les deux périodes d'observations sont une expérience sur le terrain réalisée en août 2008, au cours de laquelle des données de terrain ont été recueillies, et une tempête arctique lors de laquelle des mesures faites par bouée du 4 au 6 août 1991 ont été enregistrées. Nous analysons les processus dévolution du vent et des vagues durant ces deux périodes, et comparons avec le vent et les vagues observées. Nos analyses montrent que le frottement contre le fond est le processus physique en eaux peu profondes le plus important durant l'expérience sur le terrain d'août 2008, alors que le déferlement lié à la profondeur est le processus physique en eaux peu profondes dominant pendant la tempête arctique du 4 au 6 août 1991, en combinaison avec les effets du frottement contre le fond. Nous nous servons du modèle de vagues SWAN pour étudier les processus physiques en eaux peu profondes durant ces deux périodes d'observations. Les résultats des simulations indiquent que le modèle peut donner des résultats raisonnables, avec un coefficient de Collins approprié de 0,006 et un paramètre de déferlement de 0,55 pour représenter la physique du frottement contre le fond et du déferlement lié à la profondeur, respectivement.     

Internal constitution and evolution of the moon

The composition, structure and evolution of the moon's interior are narrowly constrained by a large assortment of physical and chemical data. Models of the thermal evolution of the moon that fit the chronology of igneous activity on the lunar surface, the stress history of the lunar lithosphere implied by the presence of mascons, and the surface concentrations of radioactive elements, involve extensive differentiation early in lunar history. This differentiation may be the result of rapid accretion and large-scale melting or of primary chemical layering during accretion; differences in present-day temperatures for these two possibilities are significant only in the inner 1000 km of the moon and may not be resolvable. If the Apollo 15 heat-flow result is representative of the moon, the average uranium concentration in the moon is 0.05–0.08 p.p.m.Density models for the moon, including the effects of temperature and pressure, can be made to satisfy the mass and moment of inertia of the moon and the presence of a low-density crust inferred from seismic refraction studies only if the lunar mantle is chemically or mineralogically inhomogeneous. The upper mantle must exceed the density of the lower mantle at similar conditions by at least 5%. The average mantle density is that of a pyroxenite or olivine pyroxenite, though the density of the upper mantle may exceed 3.5 g/cm³. The density of the lower mantle is less than that of the combined crust and upper mantle at similar temperature and pressure, thus reinforcing arguments for early moon-wide differentiation of both major and minor elements. The suggested density inversion is gravitationally unstable and implies stresses in the mantle 2–5 times those associated with the lunar gravitational field, a difficulty that can be explained or avoided by: (1) adopting lower values for the moment of inertia and/or crustal thickness, or (2) postulating that the strength of the lower mantle increases with depth or with time, either of which is possible for certain combinations of composition and thermal evolution.A small iron-rich core in the moon cannot be excluded by the moon's mass and moment of inertia. If such a core were molten at the time lunar surface rocks acquired remanent magnetization, then thermal-history models with initially cold interiors strongly depleted in radioactive heat sources as a primary accretional feature must be excluded. Further, the presence of ～||pre|40 K in a FeFeS core could significantly alter the thermal evolution and estimated present-day temperatures of the deep lunar interior.     

Velocities of compressional and shear waves in limestones

Carbonate rocks are important hydrocarbon reservoir rocks with complex textures and petrophysical properties (porosity and permeability) mainly resulting from various diagenetic processes (compaction, dissolution, precipitation, cementation, etc.). These complexities make prediction of reservoir characteristics (e.g. porosity and permeability) from their seismic properties very difficult. To explore the relationship between the seismic, petrophysical and geological properties, ultrasonic compressional‐ and shear‐wave velocity measurements were made under a simulated in situ condition of pressure (50 MPa hydrostatic effective pressure) at frequencies of approximately 0.85 MHz and 0.7 MHz, respectively, using a pulse‐echo method. The measurements were made both in vacuum‐dry and fully saturated conditions in oolitic limestones of the Great Oolite Formation of southern England. Some of the rocks were fully saturated with oil. The acoustic measurements were supplemented by porosity and permeability measurements, petrological and pore geometry studies of resin‐impregnated polished thin sections, X‐ray diffraction analyses and scanning electron microscope studies to investigate submicroscopic textures and micropores. It is shown that the compressional‐ and shear‐wave velocities (V_p and V_s, respectively) decrease with increasing porosity and that V_p decreases approximately twice as fast as V_s. The systematic differences in pore structures (e.g. the aspect ratio) of the limestones produce large residuals in the velocity versus porosity relationship. It is demonstrated that the velocity versus porosity relationship can be improved by removing the pore‐structure‐dependent variations from the residuals. The introduction of water into the pore space decreases the shear moduli of the rocks by about 2 GPa, suggesting that there exists a fluid/matrix interaction at grain contacts, which reduces the rigidity. The predicted Biot–Gassmann velocity values are greater than the measured velocity values due to the rock–fluid interaction. This is not accounted for in the Biot–Gassmann velocity models and velocity dispersion due to a local flow mechanism. The velocities predicted by the Raymer and time‐average relationships overestimated the measured velocities even more than the Biot model.     

Phodong (Sikkim) earthquake of 14 February 2006 and its aftershocks—Coulomb stress analysis

The 14 February 2006 Phodong (Sikkim) earthquake of moderate magnitude (Mw 5.3) triggered several aftershocks that were recorded by a local seismic network. The thrust earthquake is part of the continuing earthquake activity in the Himalayan seismic belt region that occurs on the detachment or ramp under the Higher Himalaya. The aftershocks of the earthquake occurred in increased stress regions caused by the earthquake rupture. Triggering of aftershocks by such a moderate magnitude earthquake implies that the faults in the Himalaya are critically stressed and even a small change of stress, about 0.001–0.002 MPa, can trigger earthquakes on such faults.