Mapping iron abundances on the surface of Mercury: Predicted spatial resolution of the MESSENGER Gamma-Ray Spectrometer

To illustrate the spatial resolution of measurements of Mercury's surface elemental composition by the Gamma-Ray Spectrometer on the MESSENGER spacecraft after one year of orbital observations, we have simulated a global coverage map of the 846-keV iron gamma-ray count rate. The simulated map suggests that distinct geologic units larger than 800 km in horizontal dimension will be discernable when the difference in Fe abundance between adjacent geologic units exceeds 4 wt%. These results imply that the MESSENGER Gamma-Ray Spectrometer dataset will provide useful information for regional geological studies of the surface of Mercury.     

The transition from complex crater to peak-ring basin on Mercury: New observations from MESSENGER flyby data and constraints on basin formation models

The study of peak-ring basins and other impact crater morphologies transitional between complex craters and multi-ring basins is important to our understanding of the mechanisms for basin formation on the terrestrial planets. Mercury has the largest population, and the largest population per area, of peak-ring basins and protobasins in the inner solar system and thus provides important data for examining questions surrounding peak-ring basin formation. New flyby images from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft have more than doubled the area of Mercury viewed at close range, providing nearly complete global coverage of the planet's surface when combined with flyby data from Mariner 10. We use this new near-global dataset to compile a catalog of peak-ring basins and protobasins on Mercury, including measurements of the diameters of the basin rim crest, interior ring, and central peak (if present). Our catalog increases the population of peak-ring basins by ∼150% and protobasins by ∼100% over previous catalogs, including 44 newly identified peak-ring basins (total=74) and 17 newly identified protobasins (total=32). A newly defined transitional basin type, the ringed peak-cluster basin (total=9), is also described. The new basin catalog confirms that Mercury has the largest population of peak-ring basins of the terrestrial planets and also places the onset rim-crest diameter for peak-ring basins at , which is intermediate between the onset diameter for peak-ring basins on the Moon and those for the other terrestrial planets. The ratios of ring diameter to rim-crest diameter further emphasize that protobasins and peak-ring basins are parts of a continuum of basin morphologies relating to their processes of formation, in contrast to previous views that these forms are distinct. Comparisons of the predictions of peak-ring basin-formation models with the characteristics of the basin catalog for Mercury suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. The relationship between impact-melt production and peak-ring formation is strengthened further by agreement between power laws fit to ratios of ring diameter to rim-crest diameter for peak-ring basins and protobasins and the power-law relation between the dimension of a melt cavity and the crater diameter. More detailed examination of Mercury's peak-ring basins awaits the planned insertion of the MESSENGER spacecraft into orbit about Mercury in 2011.     

Thermal history and evolution of the moon

Possible models for the thermal evolution of the Moon are constrained by a wide assortment of lunar data. In this work, theoretical lunar temperature models are computed taking into account different initial conditions to represent possible accretion models and various abundances of heat sources to correspond to different compositions. Differentiation and convection are simulated in the numerical computational scheme.Models of the thermal evolution of the Moon that fit the chronology of igneous activity on the lunar surface, the stress history of the lunar lithosphere implied by the presence of mascons, and the surface concentrations of radioactive elements, involve extensive differentiation early in lunar history. This differentiation may be the result of rapid accretion and large-scale melting or of primary chemical layering during accretion. Differences in present-day temperatures for these two possibilities are significant only in the inner 1000 km of the Moon and are not resolvable with presently available data.If the Apollo 15 heat flow is a representative value, the average uranium concentration in the moon is 65±15 ppb. This is consistent with achondritic bulk composition (between howardites and eucrites) for the Moon.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Separation of groundwater-flow components in a karstified aquifer using environmental tracers

Groundwater discharges from the intensively karstified Taurus Mountains to the Mediterranean Sea, either along the contact zone between the mountains and the Travertine Plateau (the Kirkgozler Springs, 15 m³/s), or through the travertine (e.g. the Dudenbasi Spring, 18 m³/s) and underneath it (unnamed submarine springs, unknown discharges). In an attempt to identify the hydraulic connections between the various outlet points, groundwater was analyzed for stable and radioactive isotopes, CFCs and He. The upgradient springs, belonging to the Kirkgozler–Dudenbasi system, were proven to be a mixture of recent and older water on the basis of their low ¹⁴C values (12–22.4 pmc), their exceptionally high He content (429–991 μcc/kg) and ³He:⁴He (R:Ra) ratios (1.471–2.602) and their measurable ³H and CFC contents (1.9–5.9 TU and 0.84 to 3.27 pmoles/kg, respectively). The older component probably contains an even lower amount of modern C. However, the undersaturation of the mixture with respect to calcite, its high CO₂ content (up to 83 mg/L) and its enriched ¹³C values (−2.2 to −4.1‰) suggest intensive water/rock interactions, which would contribute ¹⁴C-devoid bicarbonates to the solution. Downgradient springs discharging along the Mediterranean coast contain groundwater contributions from higher altitudes, as evidenced by their depleted δ¹⁸O and δD composition with respect to the local precipitation; however, a larger portion of the recent water component could be contributed from direct precipitation on the travertine. This larger component is reflected in the increased ³H (3.4 to 8.4 TU) and ¹⁴C (32.7–63.6 pmc) contents, atmospheric He (43–82 pmoles/kg), R:Ra values (1.006–1.198) and CFC contamination of the water.     

A Tube Seepage Meter for In Situ Measurement of Seepage Rate and Groundwater Sampling

We designed and evaluated a “tube seepage meter” for point measurements of vertical seepage rates (q), collecting groundwater samples, and estimating vertical hydraulic conductivity (K) in streambeds. Laboratory testing in artificial streambeds show that seepage rates from the tube seepage meter agreed well with expected values. Results of field testing of the tube seepage meter in a sandy‐bottom stream with a mean seepage rate of about 0.5 m/day agreed well with Darcian estimates (vertical hydraulic conductivity times head gradient) when averaged over multiple measurements. The uncertainties in q and K were evaluated with a Monte Carlo method and are typically 20% and 60%, respectively, for field data, and depend on the magnitude of the hydraulic gradient and the uncertainty in head measurements. The primary advantages of the tube seepage meter are its small footprint, concurrent and colocated assessments of q and K, and that it can also be configured as a self‐purging groundwater‐sampling device.     

3H/3He age data in assessing the susceptibility of wells to contamination

Regulatory agencies are becoming increasingly interested in using young-ground water dating techniques, such as the 3H/3He method, in assessing the susceptibility of public supply wells (PSWs) to contamination. However, recent studies emphasize that ground water samples of mixed age may be the norm, particularly from long-screened PSWs, and tracer-based "apparent" ages can differ substantially from actual mean ages for mixed-age samples. We present age and contaminant data from PSWs in Salt Lake Valley, Utah, that demonstrate the utility of 3H and 3He measurements in evaluating well susceptibility, despite potential age mixing. Initial 3H concentrations (measured 3H + measured tritiogenic 3He) are compared to those expected based on the apparent 3H/3He age and the local precipitation 3H record. This comparison is used to determine the amount of modern water (recharged after approximately 1950) vs. prebomb water (recharged before approximately 1950) samples might contain. Concentrations of common contaminants were also measured using detection limits generally lower than those used for regulatory purposes. A clear correlation exists between the potential magnitude of the modern water fraction and both the occurrence and concentration of contaminants. For samples containing dominantly modern water based on their initial 3H concentrations, potential discrepancies between apparent 3H/3He ages and mean ages are explored using synthetic samples that are random mixtures of different modern waters. Apparent ages can exceed mean ages by up to 13 years for these samples, with an exponential age distribution resulting in the greatest discrepancies.     

Characterisation of marine and lacustrine sediments in a drowned thermokarst embayment, Richards Island, Beaufort Sea, Canada

A multidisciplinary study was made of lakes and lagoons in a thermokarst embayment on Richards Island, Canadian Beaufort Sea, in order to investigate the response of the Mackenzie Delta shoreline to changing hydrological influences. Seismo-acoustic profiles made from an amphibious vehicle, combined with sediment core data, show that the deepest lakes contain up to 10 m of transparent or stratified silty mud overlying the Kittigazuit sand basement. Palynological and microfossil data from 21 surface samples allow delineation of freshwater, saltmarsh, tidal flat and subtidal assemblages. These modern reference data allow distinction of freshwater and marine facies in the cores and subsequent interpretation of geochemical content (carbon, ammonia, sulphate). Radiocarbon dates and ¹³⁷ Cs show that sedimentation rates have increased by an order of magnitude since drowning of the embayment during the past millennium, and that most of this sediment is from the Mackenzie River plume.     

Impacts of climate change on August stream discharge in the Central-Rocky Mountains

In the snowmelt dominated hydrology of arid western US landscapes, late summer low streamflow is the most vulnerable period for aquatic ecosystem habitats and trout populations. This study analyzes mean August discharge at 153 streams throughout the Central Rocky Mountains of North America (CRMs) for changes in discharge from 1950–2008. The purpose of this study was to determine if: (1) Mean August stream discharge values have decreased over the last half-century; (2) Low discharge values are occurring more frequently; (3) Climatic variables are influencing August discharge trends. Here we use a strict selection process to characterize gauging stations based on amount of anthropogenic impact in order to identify heavily impacted rivers and understand the relationship between climatic variables and discharge trends. Using historic United States Geologic Survey discharge data, we analyzed data for trends of 40–59 years. Combining of these records along with aerial photos and water rights records we selected gauging stations based on the length and continuity of discharge records and categorized each based on the amount of diversion. Variables that could potentially influence discharge such as change in vegetation and Pacific Decadal Oscillation (PDO) were examined, but we found that that both did not significantly influence August discharge patterns. Our analyses indicate that non-regulated watersheds are experiencing substantial declines in stream discharge and we have found that 89% of all non-regulated stations exhibit a declining slope. Additionally our results here indicate a significant (α?≤?0.10) decline in discharge from 1951–2008 for the CRMs. Correlations results at our pristine sites show a negative relationship between air temperatures and discharge and these results coupled with increasing air temperature trends pose serious concern for aquatic ecosystems in CRMs.