Evaluation of In Situ Heterogeneity of Elements in Solids: Implications for Analytical Geochemistry

A general method for the evaluation of in situ heterogeneity of geochemical materials is described and the significance of the results discussed, by using three case studies and earlier data sets. The heterogeneity of Pb in soil (expressed as RSD due to sampling, RSD_samp) varies from < 5 to > 100% between different sites, in a way that relates to the mode of deposition of the element. The heterogeneity of an element also varies systematically as a function of the distance scale at some sites. This variation can be modelled using linear regression, accounting for over 90% of the experimental variance, at seven scales over three orders of magnitude. Variation in heterogeneity between elements at the same site, seems to be somewhat diagnostic of the origin of the element, lithogenic being less than anthropogenic, although the later is also being modified by the mode of deposition. Where the heterogeneity is large (RSD > 30%), it is proposed that it can be expressed more accurately as a heterogeneity factor (10^GSDsamp), to reflect its frequency distribution, which is positively skewed towards higher concentration values.     

Groundwater study using remote sensing and geographic information systems (GIS) in the central highlands of Eritrea

Remote sensing, evaluation of digital elevation models (DEM), geographic information systems (GIS) and fieldwork techniques were combined to study the groundwater conditions in Eritrea. Remote sensing data were interpreted to produce lithological and lineament maps. DEM was used for lineament and geomorphologic mapping. Field studies permitted the study of structures and correlated them with lineament interpretations. Hydrogeological setting of springs and wells were investigated in the field, from well logs and pumping test data. All thematic layers were integrated and analysed in a GIS. Results show that groundwater occurrence is controlled by lithology, structures and landforms. Highest yields occur in basaltic rocks and are due to primary and secondary porosities. High yielding wells and springs are often related to large lineaments, lineament intersections and corresponding structural features. In metamorphic and igneous intrusive rocks with rugged landforms, groundwater occurs mainly in drainage channels with valley fill deposits. Zones of very good groundwater potential are characteristic for basaltic layers overlying lateritized crystalline rocks, flat topography with dense lineaments and structurally controlled drainage channels with valley fill deposits. The overall results demonstrate that the use of remote sensing and GIS provide potentially powerful tools to study groundwater resources and design a suitable exploration plan.An erratum to this article can be found at     

The Arctic Coastal Dynamics Database: A New Classification Scheme and Statistics on Arctic Permafrost Coastlines

Arctic permafrost coasts are sensitive to changing climate. The lengthening open water season and the increasing open water area are likely to induce greater erosion and threaten community and industry infrastructure as well as dramatically change nutrient pathways in the near-shore zone. The shallow, mediterranean Arctic Ocean is likely to be strongly affected by changes in currently poorly observed arctic coastal dynamics. We present a geomorphological classification scheme for the arctic coast, with 101,447?km of coastline in 1,315 segments. The average rate of erosion for the arctic coast is 0.5?m? year^?1 with high local and regional variability. Highest rates are observed in the Laptev, East Siberian, and Beaufort Seas. Strong spatial variability in associated database bluff height, ground carbon and ice content, and coastline movement highlights the need to estimate the relative importance of shifting coastal fluxes to the Arctic Ocean at multiple spatial scales.     

Decoding dispossession: Eviction and urban regeneration in Johannesburg's dark buildings

In January 2012 the residents of an inner‐city tenement building in Doornfontein, Johannesburg, were evicted on a court order. The building was situated in a post‐industrial neighbourhood in which thousands of South Africans and foreign nationals, many blind or disabled, live in unlawfully occupied buildings without access to water, basic sanitation, electricity and waste management services. Such buildings are known in policy discourse as ‘bad buildings’, and informally as ‘dark buildings’, invoking both a sense of developmental failure and spiritual insecurity. In this paper I analyse how urban renewal policies created social divisions and alliances not only among the residents of Chambers, which were channelled along nationalist lines, but also between the able‐bodied and disabled, and produced new social alliances. In particular, I document how a group of blind Zimbabweans experienced threats of violence and accusations of betrayal, as they were offered alternate accommodation by the evicting company because of their disability. I argue here that the pressures of private‐sector housing developments intersected with the insecurities and divisions of inner‐city social spaces and also fostered new alliances. Following the work of Deleuze and Guattari, I invoke the concept of ‘decoding dispossession’, proposing that ongoing evictions and dispossessions are characterized by simultaneous movements of ‘decoding and deterritorialization’ and ‘overcoding‐reterritorialization’.     

Kinetics of batch microbial degradation of phenols by indigenous Pseudomonas fluorescence

The potential of various organisms to metabolize organic compounds has been observed to be a potentially effective means in disposing of hazardous and toxic wastes. Phenols and their compounds have long been recognized as one of the most recalcitrant and persistent organic chemicals in the environment. The bioremediation potential of an indigenous Pseudomonas fluorescence was studied in batch culture using synthetic phenol in water in the concentration range of (100–500) mg/L as a model limiting substrate. The effect of initial phenol concentration on the degradation process was investigated. Phenol was completely degraded at different cultivation times for the different initial phenol concentrations. Increasing the initial phenol concentration from 100 mg/L to 500 mg/L increased the lag phase from 0 to 66 h and correspondingly prolonged the degradation process from 84 h to 354 h. There was decrease in biodegradation rate as initial phenol concentration increased. Fitting data into Monod kinetic model showed the inhibition effect of phenol The kinetic parameters have been estimated up to initial phenol concentration of 500 mg/ L. The r_smax decreased and K_s increased with higher concentration of phenol. The r_smaxhas been found to be a strong function of initial phenol concentration. The culture followed substrate inhibition kinetics and the specific phenol consumption rates were fitted to Haldane, Yano and Koga, Aiba et al., Teissier and Webb models. Between the five inhibition models, the Haldane model was found to give the best fit. Therefore, the biokinetic constants estimated using these models showed good potential of the Pseudomonas fluorescence and the possibility of using it in bioremediation of phenol waste effluents.     

Spatial and temporal variability of shoreline change in the Beaufort-Mackenzie region, northwest territories, Canada

Aerial photographs from 1972, 1985 and 2000 were analyzed to obtain measurements of coastal change in the Mackenzie Delta region of the Beaufort Sea. Changes from 1972 to 2000 are dominated by retreat of the shoreline with average annual retreat rates of –0.6 m a^–1, but ranging as high as –22.5 m a^–1. Rates vary significantly both between and within zones of similar exposure, morphology and coastal geology with the highest average rates located in areas that are most exposed to northwest winds. In general, decadal-scale rates of change have remained constant during the 28 years encompassed by this study.     

Quantifying stream-loss recovery in a spring using dual-tracer injections in the Snake Creek drainage,Great Basin National Park,Nevada, USA

Simultaneous short-pulse injections of two tracers (sodium bromide [Br^–] and fluorescein dye) were made in a losing reach of Snake Creek in Great Basin National Park, Nevada, USA, to evaluate the quantity of stream loss through permeable carbonates that resurfaces at a spring approximately 10 km down drainage. A revised hydrogeologic cross section for a possible flow path of the infiltrated Snake Creek water is presented, and the results may inform water management in the region. First arrival and peak concentration of the two tracers occurred at 9.5 and 12.7 days after injection, respectively. Fracture transport simulations indicate that Br^– preferentially diffuses into immobile regions of the aquifer, and this diffusive flux is likely responsible for the major differences in the breakthrough curves. When considering the diffusive tracer flux, total apparent Br^– and fluorescein dye recoveries were 16.9–22.1% and 21.7–24.3%, respectively. These findings imply that consideration of diffusive flux and long-term monitoring in fracture-dominated flow may support accurate quantification of tracer recovery. In addition, the apparent power law slopes of the breakthrough tails for both tracers were steeper at early times than have been attributed to heterogeneous advection or channeling in meter-scale tests, but the late-time Br^– power law slope becomes less steep than has been attributed to diffusive exchange. These deviations may reflect fracture transport patterns that occur at larger scales.

     

On the possible role of Rossby waves in the formation of the long-period Kuroshio meander off of Kumano Nada and Enshu Nada

It is pointed out that the rate of advance of a small transient meander east of Kyushu, which (according to the meager evidence available) seems to precede the formation of the large stable Kuroshio meander south of Kumano Nada and Enshu Nada, shows order of magnitude agreement with the barotropic Rossby wave velocity calculated on the assumption that the entire contiguous downstream flow (not merely the strong near-axis flow) behaves as a unified dynamical entity.     

Fall and recovery of the Noblesville (Indiana,U.S.A.) H chondrite

Abstract We describe the circumstances of fall of a 0.5-kg meteorite that landed in Noblesville, Indiana, USA, 3.6 m in front of two witnesses on 1991 August 31. Provisional assessment of Noblesville as an H chondrite is confirmed by data reported elsewhere which demonstrate that it is a regolith breccia with unusual properties.