Applications of a total dissolved gas pressure probe in ground water studies

Measurements of dissolved gases have numerous applications in ground water hydrology, and it is now possible to measure the total dissolved gas pressure in situ using a probe. Dissolved gas pressure is measured by submerging a headspace volume with a gas-permeable membrane, allowing dissolved gases in the water to equilibrate with gases in the headspace, then measuring the pressure in the headspace with a pressure transducer. Total dissolved gas pressure (TGP) probes have many potential uses in ground water studies employing dissolved gases, including: (1) determining approximate excess air levels, which may provide information about the time and location of recharge; (2) screening wells for air contamination, which can compromise the accuracy of dissolved gas tracer techniques: (3) detecting a trapped gas phase, which can significantly reduce hydraulic conductivity and impede the transport of dissolved solutes and gases; (4) enabling the use of gas-filled passive diffusion samplers for determining accurate dissolved gas concentrations; and (5) determining relative concentrations of CH4 and CO2 when they are known to be highly abundant. Although TGP probes designed for surface water have been available for several years, TGP probes suitable for ground water applications have only recently become available. Herein we present what are, to our knowledge, the first reported ground water dissolved gas data collected using a TGP probe. We also explain the basic operating principles of these probes and discuss the potential applications listed.     

Formation,history and energetics of cores in the terrestrial planets

The cores of the terrestrial planets Earth, Moon, Mercury, Venus and Mars differ substantially in size and in history. Though no planet other than the Earth has a conclusively demonstrated core, the probable cores in Mercury and Mars and Earth's core show a decrease in relative core size with solar distance. The Moon does not fit this sequence and Venus may not. Core formation must have been early (prior to ～4 · 10⁹ yr. ago) in the Earth, by virtue of the existence of ancient rock units and ancient paleomagnetism and from UPb partitioning arguments, and in Mercury, because the consequences of core infall would have included extensional tectonic features which are not observed even on Mercury's oldest terrain. If a small core exists in the Moon, still an open question, completion of core formation may be placed several hundred million years after the end of heavy bombardment on tectonic and thermal grounds. Core formation time on Mars is loosely constrained, but may have been substantially later than for the other terrestrial planets. The magnitude and extent of early heating to drive global differentiation appear to have decreased with distance from the sun for at least the smaller bodies Mercury, Moon and Mars.Energy sources to maintain a molten state and to fuel convection and magnetic dynamos in the cores of the terrestrial planets include principally gravitational energy, heat of fusion, and long-lived radioactivity. The gravitational energy of core infall is quantifiable and substantial for all bodies but the Moon, but was likely spent too early in the history of most planets to prove a significant residual heat source to drive a present dynamo. The energy from inner core freezing in the Earth and in Mercury is at best marginally able to match even the conductive heat loss along an outer core adiabat. Radioactive decay in the core offers an attractive but unproven energy source to maintain core convection.     

A three-dimensional discontinuous Galerkin model applied to the baroclinic simulation of Corpus Christi Bay

In this work, we present results of a numerical study of Corpus Christi Bay, Texas and surrounding regions and compare simulated model results to recorded data. The validation data for the year 2000 include the water elevation, velocity, and salinity at selected locations. The baroclinic computations were performed using the University of Texas Bays and Estuaries 3D (UTBEST3D) simulator based on a discontinuous Galerkin finite element method for unstructured prismatic meshes. We also detail some recent advances in the modeling capabilities of UTBEST3D, such as a novel turbulence scheme and the support for local vertical discretization on parts of the computational domain. All runs were conducted on parallel clusters; an evaluation of parallel performance of UTBEST3D is included.     

Global distribution,seasonal, and inter-annual variations of mesospheric semidiurnal tide observed by TIMED TIDI

Based on TIDI mesospheric wind observations, we analyzed the semidiurnal tide westward zonal wavenumber 1 and 2 (SW1 and SW2) component seasonal, inter-annual variations, and possible sudden stratospheric warming (SSW) related changes. Major findings are as follows: (1) The SW1 has a peak near the South Pole during the December solstice and near the North Pole during the March equinox. (2) The SW2 peaks at 60S and 60N mostly during winter solstices. The SW2 also peaks during late summer and early fall in the northern hemisphere. (3) The QBO effect on the semidiurnal tide is much weaker than that on the diurnal tide. The March equinox northern SW1 zonal amplitude appears to be stronger during the westward phase of the QBO, which is opposite of migrating diurnal tide QBO response. (4) Possible SSW event related changes in the semidiurnal tide are significant but not always consistent. Enhancements in the mid-latitude SW2 component during SSWs are observed, which may be related to the increase of total ozone at mid and high latitudes during SSW events. TIDI observations also show a decrease in the SW2 in the opposite hemisphere during a southern SSW event in 2002. Small increases in the high latitude SW1 in both hemispheres during the 2002 southern SSW event were recorded.     

New concepts in ecological risk assessment: where do we go from here?

Through the use of safety factors, the use of single-species test data has been adequate for use in protective hazard assessments and criteria setting but, because hazard quotients do not consider the presence of multiple species each with a particular sensitivity or the interactions that can occur between these species in a functioning community, they are ill-suited to environmental risk assessment. Significant functional redundancy occurs in most ecosystems but this is poorly considered in single-species tests conducted under laboratory conditions. A significant advance in effects assessment was the use of the microcosm as a unit within which to test interacting populations of organisms. The microcosm has allowed the measurement of the environmental effect measures such as the NOAEC(community) under laboratory or field conditions and the application of this and other similarly derived measures to ecological risk assessment (ERA). More recently, distributions of single-species laboratory test data have been used for criteria setting and, combined with distributions of exposure concentrations, for risk assessment. Distributions of species sensitivity values have been used in an a priori way for setting environmental quality criteria such as the final acute value (FAV) derived for water quality criteria. Similar distributional approaches have been combined with modeled or measured concentrations to produce estimates of the joint probability of a single species being affected or that a proportion of organisms in a community will be impacted in a posteriori risk assessments. These techniques have not been widely applied for risk assessment of dredged materials, however, with appropriate consideration of bioavailability and spatial and nature of the data these techniques can be applied to soils and sediments.     

Modeling Dynamic Vegetation Response to Rapid Climate Change Using Bioclimatic Classification

Modeling potential global redistribution of terrestrial vegetation frequently is based on bioclimatic classifications which relate static regional vegetation zones (biomes) to a set of static climate parameters. The equilibrium character of the relationships limits our confidence in their application to scenarios of rapidly changing climate. Such assessments could be improved if vegetation migration and succession would be incorporated as response variables in model simulations. We developed the model MOVE (Migration Of VEgetation), to simulate the geographical implications of different rates of plant extirpation and in-migration. We used the model to study the potential impact on terrestrial carbon stocks of climate shifts hypothesized from a doubling of atmospheric greenhouse gas concentration. The model indicates that the terrestrial vegetation and soil could release carbon; the amount of this carbon pulse depends on the rate of migration relative to the rate of climate change. New temperate and boreal biomes, not found on the landscape today, increase rapidly in area during the first 100 years of simulated response to climate change. Their presence for several centuries and their gradual disappearance after the climate ceases to change adds uncertainty in calculating future terrestrial carbon fluxes.     

Global CO2 emissions trading: Early lessons from the U.S. acid rain program

The U.S. Environmental Protection Agency is implementing a program of SO₂ emission allowance trading as part of the Acid Rain Program authorized by the Clean Air Act Amendments of 1990. Electric utilities may use allowance trading as part of their compliance strategy to meet SO₂ emission reduction requirements, which begin in 1995. In the interest of a free market in emission credits, some utilities began trading in 1992. A strict but essential requirement for continuous-emissions monitoring was developed to support the trading program. This program is being widely watched and will be evaluated as part of an effort to determine if market concepts can be successfully extended to other environmental issues. One such issue is greenhouse gas emissions and their link with global warming and climate change. This paper focuses on the early lessons learned, issues, and challenges involved in going from a domestic electric utility SO₂ emissions trading program to inter-industry, inter-gas and international as well as national emissions trading and offsets programs. Prominent among these issues are CO₂ allowance allocations, equity, emissions monitoring, enforcement, and cost-effectiveness.Paper presented at the90th Annual Meeting of the Association of American Geographers, San Francisco, April 2, 1994, at the Air & Waste Management Association International Specialty Conference onGlobal Climate Change, Tempe, Arizona, April 8, 1994, and at a Cornell University Center for the Environment seminar on global climate change, April 25, 1994. I thank Michael Grubb, Joe Kruger, Elliot Lieberman, Brian McLean, Renee Rico, Richard Schuler and two anonymous referees for helpful comments on previous drafts of this paper. The views and opinions expressed herein are those of the author alone, and do not necessarily represent the policies of the U.S. Environmental Protection Agency.     

Limitations of single-basket trading: lessons from the Montreal Protocol for climate policy

Numerous policy options exist to reduce future greenhouse gas emissions. A single-basket approach, which controls aggregate emissions, was adopted by the Kyoto Protocol. Such an approach allows emissions reductions of one gas to be traded with those of other gases in the “basket”, with the trade “price” determined by some weighting metric like the Global Warming Potential. To reduce stratospheric ozone depletion, the Montreal Protocol also dealt with controlling many compounds, but did so employing an alternative, multi-basket scheme. Trading was allowed within each basket, but not among baskets. While the Montreal Protocol has been highly successful using this approach, we show that if a single-basket approach had been adopted the short-term success could have been at risk due to the non-unique relationship between controls and environmental impacts when using a single basket. Using climate policy as an example, and without considering technological and economic constraints, we further show that the magnitude of the ambiguities in impacts associated with a single-basket approach depends on the rapidity of the emission phaseout. Fast phaseouts lead to less ambiguity than do slow ones. These results suggest that for each set of greenhouse gas control policies considered, the benefit of additional flexibility associated with a single-basket approach should be weighed against the associated increased uncertainties in the impacts to ascertain whether a single- or a multi-basket approach has the greater chance of successfully mitigating climate change.