A numerical response of the middle atmosphere to the 11-year solar cycle

A two-dimensional numerical model with coupled photochemistry and dynamics has been used to investigate the response of the middle atmosphere (16–116 km) to changes in solar activity over the 11-year solar cycle. Model inputs that vary with solar cycle include solar radiation, cosmic ray and auroral ionization rates and the flux of NO_x at the model's upper boundary.In this study, the results of model runs for solar cycle minimum and maximum conditions are compared. In the stratosphere, using currently accepted estimates of changes in solar radiation at wavelengths longer than 180 nm, only small responses in ozone, temperature and zonal winds are obtained. On the other hand, changes at shorter wavelengths, and the effects of particle precipitation, lead to large variations in the abundances of trace species in the thermosphere and upper mesosphere. In particular, very large abundances of NO_x are produced above 90 km by auroral particle precipitation. Considerable amounts of NO_x are transported subsequently to the stratosphere by the global mean meridional circulation. It is shown that this excess NO_x can lead to significant decreases in ozone concentrations at high latitudes and that it may explain observations of nitrate deposition in Antarctic snow.     

Seismic and Petrophysical Relationships from UK Continental Shelf Rocks at Elevated Pressures

Abstract

There are few published seismic (P- and S-waves) properties for seafloor bedrocks. At low pressures (1 to 10 MPa), velocities and attenuations are determined mainly by open microcracks. At higher pressures, the microcracks close, and the velocities and attenuations depend primarily on the matrix porosity. We have investigated both the relationships between the acoustic, petrophysical, and geological properties of the rocks at 40 MPa pressure and the effect of microcracks on the acoustic properties at 10 MPa pressure. In this paper we discuss the former; the latter will be discussed separately.

P- and S-wave velocity and attenuation measurements were carried out on a suite of seabed sedimentary and igneous rocks at effective pressures from 10 to 40 MPa at ultrasonic frequencies. The porosities and permeabilities of the rocks ranged from 0% to 32% and 0 to 110 mDarcy, respectively. Characterization of the rocks revealed that most of the sandstones have a substantial clay content (kaolinite, illite, and chlorite) and fractures. Most of the igneous rocks are chloritized.

The seismic properties of the rocks are markedly lower than those of similar continental rocks because of the microporosity formed by the alteration of feldspars, micas, and mafic minerals to clays (e.g., chloritization of pyroxenes) and the corresponding reduction of the elastic moduli. The results of this study suggest that the values of velocities and quality factors used for ocean acoustic propagation models are lower than normally assumed.     

Coupling parameters of the MIT OBS at two nearshore sites

A model representing the coupling of an ocean-bottom seismometer (OBS) to the seafloor as a mass-spring-dashpot system satisfactorily explains the results of transient tests performed on different instruments during the Lopez Island intercomparison test. In this paper, we compare the results obtained for the MIT OBS at Lopez Island to results from similar tests at a dockside site at Woods Hole, Massachusetts. The vertical instrument response at the Lopez Island site shows a highly damped resonance at a frequency of 22 Hz, whereas the response at the Woods Hole site shows a marked resonance at 13 Hz. The difference between the responses at the two sites can be qualitatively attributed to the difference between the surficial sediments.     

Attenuation of P- and S-waves in limestones

Ultrasonic compressional- and shear-wave attenuation measurements have been made on 40, centimetre-sized samples of water- and oil-saturated oolitic limestones at 50 MPa effective hydrostatic pressure (confining pressure minus pore-fluid pressure) at frequencies of about 0.85 MHz and 0.7 MHz respectively, using the pulse-echo method. The mineralogy, porosity, permeability and the distribution of the pore types of each sample were determined using a combination of optical and scanning electron microscopy, a helium porosimeter and a nitrogen permeameter. The limestones contain a complex porosity system consisting of interparticle macropores (dimensions up to 300 microns) and micropores (dimensions 5–10 microns) within the ooids, the calcite cement and the mud matrix. Ultrasonic attenuation reaches a maximum value in those limestones in which the dual porosity system is most fully developed, indicating that the squirt-flow mechanism, which has previously been shown to occur in shaley sandstones, also operates in the limestones. It is argued that the larger-scale dual porosity systems present in limestones in situ could similarly cause seismic attenuation at the frequencies of field seismic surveys through the operation of the squirt-flow mechanism.     

Lessons learnt from a collaborative management programme in coastal Tanzania

The Tanga Coastal Zone Conservation and Development Programme, initiated in 1994, was among the first such projects to make livelihoods improvement a key objective, and to use a community-based approach. It developed an approach to coastal management planning that is broadly satisfactory to both communities and the government. Six fisheries management areas and two mangrove management areas were established. Institutional arrangements for the collaborative approach were strengthened and community leaders and local government officers were trained in a range of relevant skills. A coastal environmental education programme for primary schools involved several thousand schoolchildren, and a gender programme built the confidence of women. Implementation of the management measures was noticeably harder than planning, particularly elimination of destructive fishing methods. Fishers and coastal communities now however have a much greater involvement in, and understanding of, coastal management and consequently a greater sense of ownership.     

Eminescu impact structure: Insight into the transition from complex crater to peak-ring basin on Mercury

Peak-ring basins represent an impact-crater morphology that is transitional between complex craters with central peaks and large multi-ring basins. Therefore, they can provide insight into the scale dependence of the impact process. Here the transition with increasing crater diameter from complex craters to peak-ring basins on Mercury is assessed through a detailed analysis of Eminescu, a geologically recent and well-preserved peak-ring basin. Eminescu has a diameter (∼125 km) close to the minimum for such crater forms and is thus representative of the transition. Impact crater size-frequency distributions and faint rays indicate that Eminescu is Kuiperian in age, geologically younger than most other basins on Mercury. Geologic mapping of basin interior units indicates a distinction between smooth plains and peak-ring units. Our mapping and crater retention ages favor plains formation by impact melt rather than post-impact volcanism, but a volcanic origin for the plains cannot be excluded if the time interval between basin formation and volcanic emplacement was less than the uncertainty in relative ages. The high-albedo peak ring of Eminescu is composed of bright crater-floor deposits (BCFDs, a distinct crustal unit seen elsewhere on Mercury) exposed by the impact. We use our observations to assess predictions of peak-ring formation models. We interpret the characteristics of Eminescu as consistent with basin formation models in which a melt cavity forms during the impact formation of craters at the transition to peak ring morphologies. We suggest that the smooth plains were emplaced via impact melt expulsion from the central melt cavity during uplift of a peak ring composed of BCFD-type material. In this scenario the ringed cluster of peaks resulted from the early development of the melt cavity, which modified the central uplift zone.     

Trapping Ionic Mercury Using Different Adsorbents

Of recent, adsorption process has gained a lot of attention as a cheap and effective means of removing trace metals from wastewater prior to discharge into water bodies. Being flexible in design and operation, the process has enabled an optimal recovery of trace metals such that the treated effluents meet the desired standards for waste disposal. Mercury is a toxicant released into the environment from natural and anthropogenic sources. It is notorious for having an unusual tendency to bio‐accumulate and persist in the food chain. Presence of mercury in food, especially those of aquatic sources has drastic implications on human health. Therefore, efforts have been made to develop and optimize low‐cost activated carbon (AC) as adsorbents for scavenging mercury from aqueous effluents. Herein, how mercury accumulates across the food chain, its health implications, and the recent advancement in the use of low‐cost ACs as adsorbent for trapping mercury from wastewater are highlighted. Relationship between the mercury removal efficiency and the surface morphology of the adsorbents as well as the influence of prevailing experimental condition on the sorption process were addressed. Challenges and future prospects of the use of low‐cost adsorbents in addressing mercury pollution in the environment are discussed.