Organic matter accumulation during the Holocene in the Guadalquivir marshlands (SW Spain)

The distribution of biomarker compounds and magnetic susceptibility observed in the sediment from a 20 m core drilled in the marshlands of the estuarine region of the Guadalquivir River (southwest coast of Spain) has allowed us to reconstruct the palaeoenvironmental evolution of this area during the Holocene. Several organic compounds (n‐alkanes, n‐ketones, n‐alkanols, n‐alkanoic acids and organic sulphur), as well as different biomarker ratios, have been used to show changing environmental conditions through time. These geochemical proxies suggest good preservation of the organic matter, although some diagenesis has occurred to particular organic compounds, especially the n‐alkanoic acids. Our data indicate a major allochthonous supply of terrestrial plants, with less influence from aquatic plants or algae through the core. There are markedly different palaeoenvironmental conditions between the uppermost 5 m (last 6 ka cal. B.P.) and the rest of the core. From 5 m (ca 6 ka cal. B.P.) to 19 m (ca 8 ka cal. B.P.) depth the palaeoenvironmental conditions were almost constant. Based on organic sulphur content and n‐alkane content logs, anoxic conditions prevailed from 8 to 6 ka cal. B.P., while oxic conditions with enhanced convection of water (prevalence of fluvial input), and consequently a greater organic matter supply, predominated in the upper 5 m of the core. Similarly, little variation in the magnetic susceptibility profile below 5 m indicates stable environmental conditions, while in the upper 5 m conditions shifted to one with elevated water input and clastic sediment supply. This is linked to palaeofloral alterations in the Guadiamar/Guadalquivir drainage basins and/or anthropogenic effects. We propose that from ca 8 to 6 ka cal. B.P. a stable landscape physiognomy in the surroundings of the estuarine area of the Guadalquivir River, with a predominance of pines and grassland. However, over the last 6 ka cal. B.P. a variation in the terrestrial plant biomarker compounds suggests an alternation of relatively dry and humid phases and/or the impact of human populations on altering the vegetation community have occurred. Copyright © 2007 John Wiley & Sons, Ltd.     

Luminous efficacy of global solar radiation on a horizontal surface for overcast and intermediate skies

Summary  In the first part of this research two models for the luminous efficacy of global solar radiation on horizontal surfaces and overcast skies have been developed. The first of these models is developed using a method similar to that proposed by Littlefair (1988). The second model has been obtained from the corresponding illuminance and irradiance models in an, apparently, new approach to the subject. In the second part of this research, a model for the luminous efficacy of global solar radiation for intermediate skies and horizontal surfaces is developed from the corresponding illuminance and irradiance models. The model for intermediate skies is given by the same mathematical function as that of the analogous model for overcast skies, and only the empirical constants change. In all the cases the only independent variables used are the solar altitude and the brightness index. The models proposed in the present paper have been statistically tested, and their prediction accuracy compared with other models available in the scientific literature. Received June 26, 2000 Revised December 9, 2000     

A paleomagnetic and rock-magnetic study of a neogene lava flow sequence in La Gomera (Canary Islands,Spain)

We present rock-magnetic and paleomagnetic results obtained on samples belonging to a Neogene sequence of 11 successive lava flows and a dyke from La Gomera (Canary Islands, Spain). Analysis of thermomagnetic curves allows to distinguish three types of samples: (i) Type H samples with low-Ti titanomagnetite as the only carrier of remanence; (ii) type M samples with a main intermediate Curie-temperature phase (T_C = 450°C) and low-Ti titanomagnetite; (iii) type L curves with a low Curie-temperature phase (T_C = 120 to 200°C) and an intermediate Curie-temperature phase (T_C = 400°C). Analysis of hysteresis parameters suggests that the grain size of most studied samples corresponds to pseudo single-domain particles, which can be also interpreted as a mixture of single-domain and multi-domain particles. Paleomagnetic experiments reveal only a single paleomagnetic component. Characteristic remanence of all studied lava flows and the dyke shows reverse polarity. The mean direction of the whole sequence is D = 188.2°, I =−35.4° (k = 46.9; α₉₅ = 6.4°) and the calculated paleomagnetic pole yields a longitude λ= 150.7° and a latitude ϕ= 78.8° (k = 59.4; A₉₅ = 5.7°). Secular variation is analysed through the scatter of virtual geomagnetic poles (VGP). A VGP angular scatter S_B = 5.9 with an upper confidence limit S_up = 8.0 and a lower confidence limit S_low = 4.6 are obtained. This scatter is clearly smaller than the average for this latitude obtained for the last 5 Ma. The studied lava flows were probably emitted in a relatively short time interval.     

Attenuation of small-amplitude oscillations in a prominence–corona model with a transverse magnetic field

Observations show that small-amplitude prominence oscillations are usually damped after a few periods. This phenomenon has been theoretically investigated in terms of non-ideal magnetoacoustic waves, non-adiabatic effects being the best candidates to explain the damping in the case of slow modes. We study the attenuation of non-adiabatic magnetoacoustic waves in a slab prominence embedded in the coronal medium. We assume an equilibrium configuration with a transverse magnetic field to the slab axis and investigate wave damping by thermal conduction and radiative losses. The magnetohydrodynamic equations are considered in their linearised form and terms representing thermal conduction, radiation and heating are included in the energy equation. The differential equations that govern linear slow and fast modes are numerically solved to obtain the complex oscillatory frequency and the corresponding eigenfunctions. We find that coronal thermal conduction and radiative losses from the prominence plasma reveal as the most relevant damping mechanisms. Both mechanisms govern together the attenuation of hybrid modes, whereas prominence radiation is responsible for the damping of internal modes and coronal conduction essentially dominates the attenuation of external modes. In addition, the energy transfer between the prominence and the corona caused by thermal conduction has a noticeable effect on the wave stability, radiative losses from the prominence plasma being of paramount importance for the thermal stability of fast modes. We conclude that slow modes are efficiently damped, with damping times compatible with observations. On the contrary, fast modes are less attenuated by non-adiabatic effects and their damping times are several orders of magnitude larger than those observed. The presence of the corona causes a decrease of the damping times with respect to those of an isolated prominence slab, but its effect is still insufficient to obtain damping times of the order of the period in the case of fast modes.     

Interactive effects of elevated [CO2] and temperature on growth and development of a short- and long-season peanut cultivar

Temperature and CO₂ are two of the main environmental factors associated with climate change. It is generally expected that elevated [CO₂] will increase crop production. However, other environmental factors such as temperature along with management practices could further modify a crop’s response to CO₂. The goal of this study was to determine the interactive effects of elevated [CO₂] and above-optimum temperature on growth, development and yield of two peanut (Arachis hypogaea L.) cultivars, e.g., Pronto and Georgia Green. One of the objectives was to determine if there was any variation in response between these two cultivars with respect to possible adaptation to climate change. Peanut plants were grown in controlled environment chambers in the University of Georgia Envirotron under conditions of non-limiting water and nutrient supply. Plants were exposed to day/night air temperatures of 33/21°C (T _A), 35.5/23.5°C (T _A + 2.5°C), and 38/26°C (T _A + 5°C) along with CO₂ treatments of 400 and 700 μmol CO₂ mol^???1 air. The selected range of temperatures was based on the temperatures that are common for southwest Georgia during the summer months. The results showed that LAI of both cultivars responded positively, e.g., 28.3% for Pronto and 49.3% for Georgia Green to elevated [CO₂]. Overall, elevated [CO₂] alone resulted in a significant increase in total biomass at final harvest across all temperatures (P?< 0.0001), but decreased final seed yield (P?< 0.0005), except for Georgia Green at (T _A + 5°C). The higher temperatures compared to T _A reduced the relative response of total biomass to CO₂ for both cultivars. It can be concluded that final seed yield response to CO₂ depends on the sensitivity of individual cultivars to temperature, especially during the reproductive development stage.     

Dissolution kinetics of synthetic Na-smectite. An integrated experimental approach

The effect of pH and Gibbs energy on the dissolution rate of a synthetic Na-montmorillonite was investigated by means of flow-through experiments at 25 and 80 °C at pH of 7 and 9. The dissolution reaction took place stoichiometrically at 80 °C, whereas at 25 °C preferential release of Mg over Si and Al was observed. The TEM-EDX analyses (transmission electronic microscopy with quantitative chemical analysis) of the dissolved synthetic phase at 25 °C showed the presence of newly formed Si-rich phases, which accounts for the Si deficit. At low temperature, depletion of Si concentration was attributed to incongruent clay dissolution with the formation of detached Si tetrahedral sheets (i.e., alteration product) whereas the Al behaviour remains uncertain (e.g., possible incorporation into Al-rich phases). Hence, steady-state rates were based on the release of Mg. Ex situ AFM measurements were used to investigate the variations in reactive surface area. Accordingly, steady-state rates were normalized to the initial edge surface area (11.2 m² g⁻¹) and used to propose the dissolution rate law for the dissolution reactions as a function of ΔG_r at 25 °C and pH∼9:

     

Post-depositional tectonic modification of VMS deposits in Iberia and its economic significance

The original stratigraphic relationships and structure of VMS deposits are commonly obscured by deformation. This can also affect their economic significance, as shown by several Iberian Pyrite Belt (IPB, SW Iberia) examples. The contrasting rheologic properties of the different lithologies present in an orebody (massive sulphide, feeder stockwork, alteration envelope, volcanic and sedimentary rocks) play a major role in determining its overall behaviour. Variscan thin-skinned tectonics led to stacking of the massive pyrite and stockwork bodies in duplex structures, resulting in local thickening and increased tonnage of minable mineralization. Furthermore, differential mechanical behaviour of the different sulphide minerals localised the detachments along relatively ductile sulphide-rich bands. The result was a geochemical and mineralogical reorganisation of most deposits, which now consist of barren, massive pyrite horses, bounded by base metal-rich ductile shear zones. Metal redistribution was enhanced by mobilisation of the base metal sulphides from the initially impoverished massive pyrite, through pressure-solution processes, to tensional fissures within the already ductile shear zones. In NW Iberia, VMS deposits were also strongly overprinted by the Variscan deformation during emplacement of the Cabo Ortegal and órdenes allochthonous nappe complexes, but no stacking of the orebodies was produced. Original contacts were transposed, and the orebodies, their feeder zones and the country rock acquired pronounced laminar geometry. In lower-grade rocks (greenschist facies, Cabo Ortegal Complex), solution transfer mechanisms are common in pyrite, which remains in the brittle domain, while chalcopyrite shows ductile behaviour. In higher-grade rocks (amphibolite facies, órdenes Complex), metamorphic recrystallisation overprints earlier deformation textures. The contrasting behaviour of the IPB and NW Iberian deposits is explained by key factors that affect their final geometry, composition and economics, such as pre-deformation structure, size and mineralogical composition of the orebody and associated lithologies, temperature, crustal level, deviatoric stress and availability of a fluid phase during deformation and the style and rate of deformation.     

Reactive transport modeling of the interaction between water and a cementitious grout in a fractured rock. Application to ONKALO (Finland)

Grouting of water-conducting fractures with low-alkali cement is foreseen for the potential future repository for spent nuclear fuel in Finland (ONKALO). A possible consequence of the interaction between groundwater and grout is the formation of high-pH solutions which will be able to react with the host rock (gneisses) and alter its mineralogy and porosity. A reactive transport modeling study of this possible alteration has been conducted. First, the hydration of the low-alkali cementitious grout has been modeled, using results from the literature as a guide. The hydrated cement is characterized by the absence of portlandite and the presence of a C-S-H gel with a Ca/Si ratio about 0.8 after tens of years (Ca/Si is about 1.7 in Ordinary Portland Cement). Second, calculations have simulated the interaction between flowing water and grout and the formation of an alkalinity plume, which flows beyond the grouted section of the fracture. The calculations include the hydration and simultaneous leaching of the grout through diffusive exchange between the porewater in the grout and the flowing water in the fracture. The formation of an alkaline plume is extremely limited when the low-pH grout is used. Even when using a grout with a lower silica fume content, the extent and magnitude of the alkaline plume is quite minor. These results are in qualitative agreement with monitoring at ONKALO.