Planetary X-ray fluorescence analogue laboratory experiments and an elemental abundance algorithm for C1XS

We have conducted laboratory experiments as an analogue to planetary XRF (X-ray fluorescence) missions in order to investigate the role of changing incidence (and phase) angle geometry and sample grain-size on the intensity of XRF from regolith-like samples. Our data provide evidence of a grain-size effect, where XRF line intensity decreases with increasing sample grain-size, as well as an almost ubiquitous increase in XRF line intensity above incidence angles of ∼60°. Data from a lunar regolith simulant are also used to test the accuracy of an XRF abundance algorithm developed at the Rutherford Appleton Laboratory (RAL), which is used to estimate the major element abundance of the lunar surface from Chandrayaan-1 X-ray Spectrometer (C1XS) XRF data. In ideal situations (i.e., when the input spectrum is well defined and the XRF spectrum has a sufficient signal to noise ratio) the algorithm can recover a known rock composition to within 1.0 elemental wt% (1σ).     

Longitudinal size distributions of bluegill bullies (Gobiomorphus hubbsi) and torrentfish (Cheimarrichthys fosteri) in two large New Zealand rivers

This study compared the longitudinal size distribution of bluegill bullies (Gobiomorphus hubbsi) from Hutt River with existing data on the size distributions of bluegill bullies and torrentfish (Cheimarrichthys fosteri) from Rakaia River, New Zealand. All populations had longitudinal trajectories that showed some increase in size with distance upstream. This increase in size appeared to primarily reflect the influence of amphidromous life styles, where juveniles diffuse upstream from the sea. However, a quantile regression analysis revealed differences in growth and migration rate between the two bluegill bully populations; bluegill bullies from Rakaia River grew at a slower rate and showed variation in migration rate within their population that was not evident in the Hutt River population. Null models were also generated for each population to test for the presence of all size classes of fish in the lower reaches of each river. Both bluegill bully populations showed a significant absence of the largest size classes in the lower reaches and the size trajectories differed significantly from the null models. This difference suggests that all individual bluegill bullies continuously move upstream throughout their lives. In comparison, the size distribution of torrentfish closely resembled the null model, indicating that some individuals did not migrate upstream to the same extent as others.     

Resilience Theory and Thomas Vale's Plants and People: A Partial Consilience of Ecological and Geographic Concepts of Succession

Geography has discovered resilience theory, a body of thought about ecological change that initiated with C.S. Holling in the 1970s. We describe the similarities and differences between resilience theory and a geographical treatise, Thomas Vale's (1982) book Plants and People. Vale's work draws more from the tradition of field botany and plant succession than from the theoretical and mathematical ecology that prompted Holling's ideas. Yet like resilience theory, Vale's model of ecological change emphasized multiple states, the threshold transitions between them, and their irreversibility. Each described how forests and rangelands can flip between stability domains in response to altered fire regimes, modified grazing pressures, and climate change. Plants and People also recognized the dual nature of stability encapsulated in Holling's formalization of engineering and ecological resilience. Although resilience theory predates Vale's work and retains primacy through its citation record, we show how their partial consilience promotes a more critical understanding of resilience theory and the ways in which models, scale, and human values influence our comprehension of ecological change.     

Investigating the crystallization history of Apollo 15 mare basalts using quantitative textural analysis

Mare basalts collected at the Apollo 15 landing site are classified as belonging to either the quartz-normative suite or the olivine-normative suite, based on differences in whole-rock major element chemistry. A wide range of textures are displayed within samples from both suites, which provide insight into eruption processes on the Moon. Here we use crystal size distribution (CSD) analysis and spatial distribution pattern (SDP) analysis of pyroxene, olivine, and plagioclase crystals in eight Apollo 15 mare basalt samples to investigate the crystallization and emplacement of the quartz-normative and olivine-normative suites. In general, our results show similarities between the CSDs and SDPs for both mare basalt suites. However, we also report two distinct groups of pyroxene CSD trends that likely represent samples with common cooling histories, originating from comparable depths within respective olivine-normative and quartz-normative lava flows. We use our results to determine the relative depths of samples within the lava flows at the Apollo 15 landing site.     

Searching for nonlocal lithologies in the Apollo 12 regolith: A geochemical and petrological study of basaltic coarse fines from the Apollo lunar soil sample 12023,155

New data from a petrological and geochemical examination of 12 coarse basaltic fines from the Apollo 12 soil sample 12023,155 provide evidence of additional geochemical diversity at the landing site. In addition to the bulk chemical composition, major, minor, and trace element analyses of mineral phases are employed to ascertain how these samples relate to the Apollo 12 lithological basalt groups, thereby overcoming the problems of representativeness of small samples. All of the samples studied are low‐Ti basalts (0.9–5.7 wt% TiO₂), and many fall into the established olivine, pigeonite, and ilmenite classification of Apollo 12 basaltic suites. There are five exceptions: sample 12023,155_1A is mineralogically and compositionally distinct from other Apollo 12 basalt types, with low pigeonite REE concentrations and low Ni (41–55 ppm) and Mn (2400–2556 ppm) concentrations in olivine. Sample 12023,155_11A is also unique, with Fe‐rich mineral compositions and low bulk Mg# (=100 × atomic Mg/[Mg+Fe]) of 21.6. Sample 12023,155_7A has different plagioclase chemistry and crystallization trends as well as a wider range of olivine Mg# (34–55) compared with other Apollo 12 basalts, and shows greater similarities to Apollo 14 high‐Al basalts. Two other samples (12023,155_4A, and _5A) are similar to the Apollo 12 feldspathic basalt 12038, providing additional evidence that feldspathic basalts represent a lava flow proximal to the Apollo 12 site rather than material introduced by impacts. We suggest that at least one parent magma, and possibly as many as four separate parent magmas, are required in addition to the previously identified olivine, pigeonite, and ilmenite basaltic suites to account for the observed chemical diversity of basalts found in this study.     

Vertical electrical sounding to delineate the potential aquifer zones for drinking water in Niamey city,Niger, Africa

Niger is a landlocked African country and the only source of surface water is the Niger River which flows in the western part of Niger and only few villages near to the river gets benefited from it, leaving most of the areas dependent on groundwater solely. The groundwater resources in Niger are mainly used for drinking, livestock and domestic needs. It can be observed that the water exploitation is minimal there due to several factors like undeveloped areas, less population, limited wells, rain-fed irrigation, etc. The delineation of potential aquifer zones is an important aspect for groundwater prospecting. Hence, the direct current (DC) resistivity soundings method also known as vertical electrical sounding (VES) is one of the most applied geophysical techniques for groundwater prospecting that was used in the capital city, Niamey of Niger. Twelve VES surveys, each of AB spacing 400 m were carried out in lateritic and granitic rock formations with a view to study the layer response and to delineate the potential zones. Potential aquifer zones were at shallow depth ranging from 10 to 25 m for the drilled borehole depth of 80–85 m in every village. Analysis of the result showed a good correlation between the acquired data and the lithologs.     

Impact of Higher Frequency Content of Input Motion Upon Equivalent Linear Site Response Analysis for the Study Area of Delhi

While travelling through the subsoil layers, earthquake generated bedrock motions get modified significantly due to local soil and should be quantified using ground response analysis. Present study concentrates on equivalent linear method of site response analysis in SHAKE2000 software. It is a frequency based analysis tool having default frequency set to 15 Hz. While due consideration is given to amplitude, no to very limited information about the frequency content of the input motion to be considered in ground response analysis is available. In the present work, the effect of the maximum frequency of ground motion in site response analysis using SHAKE2000 is examined. Two sets of analyses are carried out in this work based on 30 globally recorded input motions. In the first analyses, input motion up to 15 Hz maximum frequency, which is a default value in SHAKE2000 is considered while second analyses are based on considering each of the 30 input motions up to the Nyquist frequency. Comparing the results from the two sets of analyses highlight that selection of maximum frequency in SHAKE2000 has considerable effect in ground motion amplification at different depths. As a result, even the peak ground acceleration which controls the building behavior and damage scenario, is going to change considerably even in case same input motion is used in the analysis.     

CHARACTERIZATION OF MAJOR,MINOR AND TRACE ELEMENTS IN SIX CCRMP (TDB-1, WGB-1, UMT-1, WPR-1, WMG-1 AND WMS-1) AND ONE IWG (ZW-C) GEOCHEMICAL CANDIDATE REFERENCE MATERIALS*

Elemental compostions of six CCRMP (TDB-1, WGB-1, UMT-1, WPR-1, WMG-1 and WMS-1) and one IWG (ZW-C) geochemical candidate reference materials were determined by XRF, ICP-AES, ICP-MS, GFAAS and other modern instrumental techniques. Inter-method results compared favourably in the case of elements for which multiple data were available.     

The relative mobility of natural (Th,Pb and Po) and fallout (Pu,Am, Cs) radionuclides in the coastal marine environment: results from model ecosystems (MERL) and Narragansett Bay

The relative mobility of nuclides of Pb, Th, Pu, and Cs, which are widely used as geochemical tracers for sedimentation and bioturbation. was investigated in artificial microcosm tanks (MERL) and in Narragansett Bay. Their mobility was characterized by their removal rates from the water column, their affinity toward particles and their degree of penetration into the surface sediments. Pb, Th, and Pu transport was controlled predominantly by the affinity of these elements to particles, and the transport parameters of the particles themselves (i.e. sediment resuspension and mixing rates). Because of its low distribution coefficient, transport of Cs was controlled by molecular diffusion through pore water in the winter, while in summer, Cs transport was enhanced due to bioturbation. The increase with depth of the $\text{Cs}\text{Pu}$ ratio in core profiles of MERL and Narragansett Bay sediments is thus caused primarily by the higher mobility of Cs.