Removal of textile dyes from aqueous solution by conducting polymer modified clinoptilolite

In this work, clinoptilolite was modified with conducting polyaniline polymer and then the nanocomposite was used as an adsorbent for methyl orange (MO) as a model dye. Cations located in clinoptilolite structure like Na⁺, K⁺, Mg²⁺, Ca²⁺ were exchanged with anilinium cations and then the polymerization of anilinium cations in and outside of the clinoptilolite channels resulted in the formation of polyaniline/clinoptilolite nanocomposite. The resulted nanocomposite was used for the removal of MO from aqueous solution. The effect of various factors like contact time, concentration of dye as well as the amount of adsorbent on the removal efficiency of dye was investigated. The adsorption isotherms were investigated. It was found that the equilibrium adsorption data were well described by the Langmuir isotherm model. The kinetic studies indicated that the adsorption process was controlled by pseudo-second-order equation. High adsorption capacity and low contact time as well as the low cost of modified clinoptilolite proved that it is an efficient adsorbent for the removal of MO from aqueous solutions.     

Earthquake response analysis considering non-proportional damping

Non-proportional damping may be defined as a form of linear viscous damping which introduces coupling between the undamped modal co-ordinate equations of motion. The standard mode superposition method of earthquake response analysis therefore cannot be employed with non-proportionally damped structures. In this paper, several methods for analysing the dynamic response of non-proportional damped structures are outlined. It is concluded that the most efficient procedure is to express the response in terms of a truncated set of undamped modal coordinates and to integrate directly the resulting coupled equations. The effectiveness of the method is demonstrated by a numerical example.     

Ground improvement using SPVD and RPE

Excessive total and differential settlement at the intersection of a surcharged prefabricated vertical drain (SPVD) and a rigid piled embankment on soft ground during the post-construction period leads to considerable time and costs being spent on repetitive remedial works in the future. This paper presents a sustainable design approach for high and long embankment filling on soft clay at the approach to the structure by introducing the intersection of an SPVD at the transition to a rigid piled embankment in order to regulate the differential settlement between the two conventional ground treatment approaches. This paper also presents a full-scale field study to validate the performance of the intersection of the SPVD at the transition to the rigid piled embankment. By introducing the intersection ground treatment, post-construction settlement and differential settlement are minimised significantly, while the post-construction total settlement at the rigid transition piled embankment (TPE) zone is reduced significantly by about 80 to 95% of the total settlement, as compared to a conventional TPE.