Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

From sequential to parallel growth of cities: Theory and evidence from Canada

This paper examines city growth patterns and the corresponding city size distribution evolution over long periods of time using a simple New Economic Geography(NEG) model and urban population data from Canada. The main findings are twofold. First, there is a transition from sequential to parallel growth of cities over long periods of time: city growth shows a sequential mode in the stage of rapid urbanization, i.e., the cities with the best development conditions will take the lead in growth, after which the cities with higher ranks will become the fastest-growing cities; in the late stage of urbanization, city growth converges according to Gibrat′s law, and exhibits a parallel growth pattern. Second, city size distribution is found to have persistent structural characteristics: the city system is self-organized into multiple discrete size groups; city growth shows club convergence characteristics, and the cities with similar development conditions eventually converge to a similar size. The results will not only enhance our understanding of urbanization process, but will also provide a timely and clear policy reference for promoting the healthy urbanization of developing countries.     

Large vesicles record pathways of degassing at basaltic volcanoes

Volcanic degassing is directly linked to magma dynamics and controls the style of eruptive activity. To better understand how gas is transported within basaltic magma we perform a 3D investigation of vesicles preserved in scoria from the 2005 activity at Stromboli volcano (Italy). We find that clasts are characterized by the ubiquitous occurrence of one to a few large vesicles, exhibiting mostly irregular, tortuous, channel-like textures, orders of magnitude greater in volume than all the other vesicles in the sample. We compare observations on natural samples with results from numerical simulations and experimental investigations of vesicle size distributions and demonstrate that this type of vesicle invariably forms in magmas with vesicularities > 0.30 (and possibly > 0.10). We suggest that large vesicles represent pathways used by gas to flow non-explosively to the surface and that they indicate the development of an efficient system that sustains persistent degassing in basaltic systems.     

The interaction between surface water and groundwater and its effect on water quality in the Second Songhua River basin,northeast China

The relationship between surface water and groundwater not only influences the water quantity, but also affects the water quality. The stable isotopes (δD, δ ¹⁸O) and hydrochemical compositions in water samples were analysed in the Second Songhua River basin. The deep groundwater is mainly recharged from shallow groundwater in the middle and upper reaches. The shallow groundwater is discharged to rivers in the downstream. The runoff from upper reaches mainly contributed the river flow in the downstream. The CCME WQI indicated that the quality of surface water and groundwater was ‘Fair’. The mixing process between surface water and groundwater was simulated by the PHREEQC code with the results from the stable isotopes. The interaction between surface water and groundwater influences the composition of ions in the mixing water, and further affects the water quality with other factors.     

Climate change outlook for water resources management in a semiarid river basin: the effect of the environmental water demand

Iran is a developing country with arid and semiarid regions. Poor management of water resources combined with the effects of climate change is leading to the drying of several rivers and wetlands. Several planned water development projects, primarily for agricultural expansion, will be implemented in the coming years which could worsen impacts on vulnerable aquatic ecosystems. Proper water resources management is essential to meet present and future residential, environmental, industrial, and agricultural demands in semiarid regions. This paper presents projections of how the availability of water resources will change in the Karkheh river basin of Iran for the period 2010–2059 employing sustainability criteria in the form of time-based reliability, volumetric reliability, resiliency, and vulnerability. This paper’s results show that consideration of environmental receptors as a stakeholder of water use places limitations on agricultural development within the Karkheh river basin.     

Photosynthetic characteristics of dominant tree species and canopy in the broadleaved Korean pine forest of Changbai Mountains

Based on the light-photosynthesis response measurement at leaf level, combined with over-and under-canopy eddy covariance measurements, research on photosynthetic characteristics of single trees and forest canopy was conducted. The relationship between light intensity and photosynthetic rates for leaves and canopy can be well fitted by a non-rectangular hyperbola model. Mongolian oak presented a high light compensation point, L _cp (28 μmol·m^?2·s^?1), a light saturation point L _sp (>1800 μmol·m^?2·s^?1), and a maximal net photosynthetic rate P _max (9.96 μmol·m^?2·s^?1), which suggest that it is a typical heliophilous plant. Mono maple presented the highest apparent quantum efficiency α (0.066) but the lowest, L _cp (16 μmol·m^?2·s^?1), L _sp (≈800 μmol·m^?2·s^?1), and P _max (4.51 μmol·m^?2·s^?1), which suggest that it is heliophilous plant. Korean pine showed the lowest α value but a higher P _max, which suggest that it is a semi-heliophilous plant. At the canopy level, the values of both α and P _max approached the upper limit of reported values in temperate forests, while L _cp was within the lower limit. Canopy photosynthetic characteristics were well consistent with those of leaves. Both showed a high ability to photosynthesize. However, environmental stresses, especially high vapor pressure deficits, could significantly reduce the photosynthetic ability of leaves and canopy.     

Prediction of water inflow to mechanized tunnels during tunnel-boring-machine advance using numerical simulation

An accurate estimate of the groundwater inflow to a tunnel is one of the most challenging but essential tasks in tunnel design and construction. Most of the numerical or analytical solutions that have been developed ignore tunnel seepage conditions, material properties and hydraulic-head changes along the tunnel route during the excavation process, leading to inaccurate prediction of inflow rates. A method is introduced that uses MODFLOW code of GMS software to predict inflow rate as the tunnel boring machine (TBM) gradually advances. In this method, the tunnel boundary condition is conceptualized and defined using Drain package, which is simulated by dividing the drilling process into a series of successive intervals based on the tunnel excavation rates. In addition, the drain elevations are specified as the respective tunnel elevations, and the conductance parameters are assigned to intervals, depending on the TBM type and the tunnel seepage condition. The Qomroud water conveyance tunnel, located in Lorestan province of Iran, is 36 km in length. Since the Qomroud tunnel involved groundwater inrush during excavating, it is considered as a good case study to evaluate the presented method. The groundwater inflow to this tunnel during the TBM advance is simulated using the proposed method and the predicted rates are compared with observed rates. The results show that the presented method can satisfactorily predict the inflow rates as the TBM advances.     

Determining the hard rock groundwater pathway in Golgohar complex formation using hydrochemical data in AHP

Thirty percent of present industrial water consumption of the Golgohar Iron Ore Mine (GIOM) is supplied from a hard rock well (PW-A15) and the rest from 25 wells located in 4 disconnected alluvial aquifers. This well is drilled in the metamorphic complex of Golgohar formation. Attempts have been made to develop extraction of water from other hard rocks existing in the area with no success. Therefore, extensive researches have been carried out to find the pathway, or a provision pathway of water discharged from this well. To study the hydrochemical similarity of this water with other water resources, 122 water samples from an area of 7132 km² were collected from the existing pumping wells, piezometers, mine exploration bore holes, and three salt pans in the vicinity of the area for hydrochemical analysis. The analyses were performed for concentration of major ions and some minor elements. Furthermore, the spatial distribution of ion concentration was plotted in the GIS to delineate the similarity of the PW-A15 water with other water sources and their hydrochemical neighborhood by analytical hierarchy process (AHP). The AHP was performed in two steps: first, iso-concentration maps of seven major ions, eight minor elements, and TDS were used to produce an AHP map (Map1) using weights for different hydrochemical parameters; and second, a similarity index (SI) map was prepared by performing a suggested clustering approach in SPSS using K-means clustering, which was overlaid on Map1 producing Map2. The result of AHP Map2 was then overlaid on the iso-potential map of the sampled locations in GIS software using a mask operator. Therefore, the zones having the most similarity and higher hydraulic potential than PW-A15 were nominated as the zones which possibly could recharge this well, and the groundwater (GW) pathway was proposed. The result of the study method showed to be successful and will be used as a guide for future exploration drillings.     

Provenance of buried esker groundwater: the case of Vars-Winchester esker aquifer,Eastern Ontario,Canada

An innovative mode of groundwater recharge to a buried esker aquifer is considered. The current conceptual model affords a natural safeguard to underlying aquifers from the overlying muds. A hypothesis of groundwater recharge to a buried esker aquifer via preferential pathways across its overlying muds is tested here by heuristic numerical one-dimensional and two-dimensional modeling simulations. The hypothesis has been tested against two other conventionally accepted scenarios involving: (1) distal esker outcrop areas and (2) remote shallow-bedrock recharge areas. The main evidence comes from documented recharge pressure pulses in the overlying mud aquitard and in the underlying esker hydraulic-head time series for the Vars-Winchester esker aquifer in Eastern Ontario, Canada. These perturbations to the potentiometric surface are believed to be the aquifer response to recharge events. The migration rate of these pressure pulses is directly related to the hydraulic diffusivity of the formation. The measured response time and response amplitude between singular radar precipitation events and well hydrographs constituted the heuristic model calibration targets. The main evidence also includes mud-layering deformation (water escape features) which was observed in seismic surveys of the over-esker muds. These disturbed stratigraphic elements provide a realistic mechanism for migrating water to transit through the muds. The effective hydraulic conductivities of these preferential pathways in the muds were estimated to be between 2?×?10^?6 and 7?×?10^?6 m/s. The implications of these findings relate to the alleged natural safeguard of these overlying muds.     

Rupture process of the 2015 Pishan earthquake from joint inversion of InSAR,teleseismic data and GPS

An earthquake of Mw6.4 occurred in Pishan County in Xinjiang Province, northwestern Tibetan Plateau, on July 3,2015. The epicenter was located on an active blind thrust system located at the northern margin of the Western Kunlun Mountain Orogenic Belt southwest of the Tarim Basin. We constructed a shovel-shaped fault model based on the layered-crust model with reference to the seismic reflection profile, and obtained the rupture process of the earthquake from the joint inversion of Interferometric Synthetic Aperture Radar(InSAR) measurements, far-field waveform data, and Global Positioning System(GPS) data. The results show that the seismic fault dips southward with a strike of 109°, and the rupture direction was essentially northward. The fault plane rupture distribution is concentrated, with a maximum recorded slip of 73 cm. The main features of the fault are as follows: low inclination angle(25°–10°), thrust slip at a depth of 9–13 km, rupture propagation time of about 12 s, no significant slip in soft or hard sedimentary layers at 0–4 km depth and propagation from the initial rupture point to the surrounding area with no obvious directionality. The InSAR time-series analysis method is used to determine the deformation rate in the source region within 2 years after the earthquake, and the maximum value is ~17 mm yr-1 in the radar line-of-sight direction. Obvious post-earthquake deformation is evident in the hanging wall, with a similar trend to the coseismic displacement field. These results suggest that the Pishan earthquake has not completely released the accumulated energy of the region, given that the multilayer fold structure above the blind fault is still in a process of slow uplift since the earthquake. Post-earthquake adjustment models and aftershock risk analysis require further study using more independent data.