Lithogeochemistry as an indicator of uranium and tin mineralization, South Mountain Batholith, Nova Scotia, Canada

Uranium and tin occurrences in the South Mountain Batholith are preferentially found in or near a para-intrusive rock suite which is characterized by strong granophile element enrichments. Furthermore, bodies which show a Th-enrichment trend with increasing differentiation appear to be more favorable exploration targets than spatially associated bodies in which Th is depleted.     

Late quaternary deformation and palaeoseismicity: Insight into geomorphotectonic evolution of Kachchh, western Indian Subcontinent

Kachchh in western Indian Shield, according to the Bureau of Indian Standard (IS:1893:2002), falls in Seismic Zone V. This is intriguing considering that the region is far away from active Plate margin. Apart from the recent incidences of earthquakes, there are several pre-historic/archaeological records of earthquakes in the region. Beyond these, the geological evidence of earth-movements (causing earthquakes) is provided by the occurrence of several’ active’ faults, which are considered geological markers of palaeoseismicity. There are records of innumerable incidences of faulting in the region in not so distant geological past. Study of fault features especially the scarp faces marking abrupt change in physical relief proves that the different levels of topography in the entire terrain are fault-bound features. Studies also confirm that the topographic difference between the high and ’sunken’ features have formed due to uplift and relative down-sagging during the geomorphotectonic evolution of the terrain. Features that make the region unique are: (i) restriction of fault-related deformation zone to a narrow strip between the southern margin of Thar Desert and the south coast line of the Kachchh Peninsula; (ii) overall sub-horizontality of bedding and other topographic and planation surfaces over the entire region; (iii) evidence of fault-controlled geomorphology indicating vertical movement along fault planes; (iv) evidence constraining the time of geomorphological evolution of the terrain only during the Late Quaternary, making it the youngest neotectonically evolved terrain in the Precambrian Indian Shield.     

Variations in shear wave velocity and soil site class in Kolkata city using regression and sensitivity analysis

The detrimental effects of an earthquake are strongly influenced by the response of soils subjected to dynamic loading. The behavior of soils under dynamic loading is governed by the dynamic soil properties such as shear wave velocity, damping characteristics and shear modulus. Worldwide, it is a common practice to obtain shear wave velocity (V _s in m/s) using the correlation with field standard penetration test (SPT) N values in the absence of sophisticated dynamic field test data. In this paper, a similar but modified advanced approach has been proposed for a major metro city of eastern India, i.e., Kolkata city (latitudes 22°20′N–23°00′N and longitudes 88°04′E–88°33′E), to obtain shear wave velocity profile and soil site classification using regression and sensitivity analyses. Extensive geotechnical borehole data from 434 boreholes located across 75 sites in the city area of 185 km² and laboratory test data providing information on the thickness of subsoil strata, SPT N values, consistency indices and percentage of fines are collected and analyzed thoroughly. A correlation between shear wave velocity (V _s) and SPT N value for various soil profiles of Kolkata city has been established by using power model of nonlinear regression analysis and compared with existing correlations for other Indian cities. The present correlations, having regression coefficients (R ²) in excess of 0.96, indicated good prediction capability. Sensitivity analysis predicts that significant influence of soil type exists in determining V _s values, for example, typical silty sand shows 30.4 % increase in magnitude of V _s as compared to silt of Kolkata city. Moreover, the soil site classification shows Class D and Class E category of soil that exists typically in Kolkata city as per NEHRP (Recommended provisions for seismic regulations for new buildings and other structures—Part 1: Provisions. Prepared by the Building Seismic Safety Council for the Federal Emergency Management Agency (Report FEMA 450), Washington, DC, 2003) guidelines and thereby highlighting the seismic vulnerability of the city. The results presented in this study can be utilized for seismic microzonation, ground response analysis and hazard assessment for Kolkata city.

     

The Bayesian approach to an internally consistent thermodynamic database: theory, database, and generation of phase diagrams

An internally consistent thermodynamic dataset has been derived for 148 endmember phases (145 solids and 3 fluids) comprising the elements Li, Na, K, Be, Mg, Ca, Ti, Cr, Mn, Fe, Zn, Al, Si, C, H, and O. This has been achieved by simultaneous treatment of phase property (like standard enthalpy of formation, standard entropy, molar heat capacity, molar volume, thermal expansivity, bulk modulus etc.) and reaction reversal data by the Bayesian method. The theory underlying the approach, and the computational methods involved, are briefly outlined. (For the benefit of readers unfamiliar with inference statistics, the basic concepts of the Bayes method are also presented in such a way that they can be grasped intuitively.) Although not yet addressed, this method can be extended to refine the thermodynamic mixing properties of crystalline solutions. The sources of the input data, culled from the literature, are summarized in the Appendix. The resulting database is succinctly documented in this paper. It includes the enthalpies of formation and entropies, their uncertainties, and the correlation among them. The database allows calculation of P-T, T-X _CO2, P-X _CO2, and T-f _O2 sections, with error propagation into the computed phase diagrams on a routine basis. A user-friendly computer program has been written to generate such phase diagrams. It is public domain software. The software and the thermodynamic database (which includes a complete documentation of the thermodynamic data above and beyond those listed (Table 2, here) may be downloaded from the web site http://homepage.ruhr-uni-bochum.de/niranjan.chatterjee/Index.htm. Examples of computed phase diagrams are given to illustrate the quality of the data and the capabilities of the software. Received: 11 March 1998 / Accepted: 11 June 1998     

Experimental and thermodynamic study of heterogeneous and homogeneous equilibria in the system NaAlSiO4-SiO2

Internally consistent thermodynamic datasets available at present call for a further improvement of the data for nepheline (Holland and Powell 1988; Berman 1991). Because nepheline is a common rock-forming mineral, an attempt has been made to improve on the present state of knowledge of its thermodynamic properties. To achieve that goal, two heterogeneous reactions involving nepheline, albite, jadeite and a-quartz in the system NaAlSiO₄-SiO₂ have been reversed bylong duration runs in the range 460 ≤ T(°C) ≤ 960 and 10 ≤ P(kbar) ≤ 22. Given sufficiently long run times, thealbite run products approach internal equilibrium with respect to their Al,Si order-disorder states. Using appropriate thermochemical, thermophysical, and volumetric data, Landau expansion for albite, and the relevant reaction reversals, a refined thermodynamic dataset (Δ_fH_i⁰ and S_i⁰) has been derived for nepheline, jadeite, a-quartz, albite, and monalbite. Our refined data agree very well with theircalorimetric counterparts, but have smaller uncertainties. The refined dataset for Δ_fH_i⁰ and S_i⁰, including their uncertainties and correlation, help generate the NaAlSiO₄-SiO₂ phase diagram including 2a confidence interval for eachP-T curve (Fig. 5). Editorial responsibility: W. Schreyer     

Heat capacity of wadeite-type K2Si4O9 and the pressure-induced stable decomposition of K-feldspar

The heat capacity of synthetic, stoichiometric wadeite-type K₂Si₄O₉ has been measured by DSC in the 195≤T(K)≤598 range. Near the upper temperature limit of our data, the heat capacity observed by DSC agrees with that reported by Geisinger et al. (1987) based on a vibrational model of their infrared and Raman spectroscopic data. However, with decreasing temperature, the Cp observed by DSC is progressively higher than that predicted from the vibrational model, suggesting that the standard entropy of K₂Si₄O₉ is likely to be larger than 198.9 ± 4.0 J/K · mol computed from the spectroscopic data. A fit to the DSC data gave: Cp(T) = 499.13 (±1.87) − 4.35014 · 10³(±3.489 · 10¹) · T ^−0.5, with T in K and average absolute percent deviation of 0.37%. The room-temperature compressibilities of kalsilite and leucite, hitherto unknown, have been measured as well. The data, fitted to the Murnaghan equation of state, gave K _o = 58.6 GPa, K _o ^′ = 0.1 for kalsilite and K _o = 45 GPa, K _o ^′ = 5.7 for α-leucite. Apart from the above mentioned data on the properties of the individual phases, we have also obtained reaction-reversals on four equilibria in the system K₂O-Al₂O₃-SiO₂. The Bayesian method has been used simultaneously to process the properties of 13 phases and 15 reactions between them to derive an internally consistent thermodynamic dataset for the K₂O-Al₂O₃-SiO₂ ternary. The enthalpy of formation of K₂Si₄O₉ wadeite is in perfect agreement with its revised calorimetric value, the standard entropy is 232.1 ± 10.4 J/K · mol, ∼15% higher than that implied by vibrational modeling. The phase diagram, generated from our internally consistent thermodynamic dataset, shows that for all probable P-T trajectories in the subduction regime, the stable pressure-induced decomposition of K-feldspar will produce coesite + kalsilite rather than coesite + kyanite + K₂Si₄O₉ (cf. Urakawa et al. 1994). Received: 11 June 1997 / Accepted: 2 December 1997     

Influence of seismic motions on behavior of piles in liquefied soils

In the present study an analytical procedure based on finite element technique is proposed to investigate the influence of vertical load on deflection and bending moment of a laterally loaded pile embedded in liquefiable soil, subjected to permanent ground displacement. The degradation of subgrade modulus due to soil liquefaction and effect of nonlinearity are also considered. A free headed vertical concrete elastic nonyielding pile with a floating tip subjected to vertical compressive loading, lateral load, and permanent ground displacement due to earthquake motions, in liquefiable soil underlain by nonliquefiable stratum, is considered. The input seismic motions, having varying range of ground motion parameters, considered here include 1989 Loma Gilroy, 1995 Kobe, 2001 Bhuj, and 2011 Sikkim motions. It is calculated that maximum bending moment occurred at the interface of liquefiable and nonliquefiable soil layers and when thickness of liquefiable soil layer is around 60% of total pile length. Maximum bending moment of 1210 kNm and pile head deflection of 110 cm is observed because of 1995 Kobe motion, while 2001 Bhuj and 2011 Sikkim motions amplify the pile head deflection by 14.2 and 14.4 times and bending moment approximately by 4 times, when compared to nonliquefiable soil. Further, the presence of inertial load at the pile head increases bending moment and deflection by approximately 52% when subjected to 1995 Kobe motion. Thus, it is necessary to have a proper assessment of both kinematic and inertial interactions due to free field seismic motions and vertical loads for evaluating pile response in liquefiable soil.     

Bayes estimation: A novel approach to derivation of internally consistent thermodynamic data for minerals,their uncertainties,and correlations. Part II: Application

Internally consistent thermodynamic data, including their uncertainties and correlations, are reported for 22 phases of the quaternary system CaO-Al₂O₃-SiO₂-H₂O. These data have been derived by simultaneous evaluation of the appropriate phase properties (PP) and reaction properties (RP) by the novel technique of Bayes estimation (BE). The thermodynamic model used and the theory of BE was expounded in Part I of this paper. Part II is the follow-up study illustrating an application of BE. The input for BE comprised, among others, the a priori values for standard enthalpy of formation of the i-th phase, Δ_f H _i ⁰ , and its standard entropy, S _i ⁰ , in addition to the reaction reversal constraints for 33 equilibria involving the relevant phases. A total of 269 RP restrictions have been processed, of which 107 turned out to be non-redundant. The refined values for Δ_f H _i ⁰ and S _i ⁰ obtained by BE, including their 2σ-uncertainties, appear in Table 4; the Appendix reproduces the corresponding correlation matrix. These data permit generation of computed phase diagrams with 2σ-uncertainty envelopes based on conventional error propagation; Fig. 3 depicts such a phase diagram for the system CaO-Al₂O₃-SiO₂. It shows that the refined dataset is capable of yielding phase diagrams with uncertainty envelopes narrow enough to be geologically useful. The results in Table 4 demonstrate that the uncertainties of the prior values for Δ_f H _i ^Emphasis>0 , given in Table 1, have decreased by up to an order of magnitude, while those for S _i ⁰ improved by a factor of up to two. For comparison, Table 4 also lists the refined Δ_f H _i ⁰ and S _i ⁰ data obtained by mathematical programming (MAP), minimizing a quadratic objective function used earlier by Berman (1988). Examples of calculated phase diagrams are given to demonstrate the advantages of BE for deriving internally consistent thermodynamic data. Although P-T curves generated from both MAP and BE databases will pass through the reversal restrictions, BE datasets appear to be better suited for extrapolations beyond the P-T range explored experimentally and for predicting equilibria not constrained by reversals.     

Mercury enrichments in core sediments in Hugli–Matla–Bidyadhari estuarine complex,north-eastern part of the Bay of Bengal and their ecotoxicological significance

Mercury concentrations (Hg_T) in fine-grained fraction (<63 μm) of core sediments of the Hugli–Matla–Bidyadhari estuarine complex, India were analyzed. Results revealed a wide range of spatial variations (<4–93 ng g⁻¹ dry weight) with a definite enhancement level at the lower stretch of the estuarine complex infested with mangrove plants, which might act as a sink to Hg_T. An elevated concentration of Hg was encountered in surface/subsurface layer of the core in majority of the cases resulting from physical, biogenic and postdepositional diagenetic processes that remobilized and resuspended the metal from deeper sediments. A strong positive correlation was observed between the Hg and clay fraction content of the sediments, while the correlations of Hg with Al, Fe and Mn were poor. Based on the index of geoaccumulation (I _geo) and effects range-low (ER-L) value, it is considered that the sediments are less polluted and thus there is less chance of ecotoxicological risk to organisms living in sediments.