Carbon Isotope Fractionation of PCE and TCE During Dechlorination by Vitamin B12

Reductive dechlorination of perchloroethylene (PCE) and trichloroethylene (TCE) by vitamin B12 is an analogue of the microbial reductive dechlorination reaction and is presently being applied as a remediation technique. Stable carbon isotopic analysis, an effective and powerful tool for the investigation and monitoring of contaminant remediation, was used to characterize the isotopic effects of reductive dechlorination of PCE and TCE by vitamin B12 in laboratory microcosms. In laboratory experiments, 10 mg/L vitamin B12 degraded >90% of the initial 20 mg/L PCE with TCE, the primary product of PCE degradation, accounting for between 64% and 72% of the PCE degraded. In experiments with TCE, 147 mg/L vitamin B12 degraded >90% of the initial 20 mg/L TCE with cis -dichloroethene ( c DCE), the primary product of degradation accounting for between 30% and 35% of the TCE degraded. Degradation of both PCE and TCE exhibited first-order kinetics. Strong isotopic fractionation of the reactant PCE and of the reactant TCE was observed over the course of degradation. This fractionation could be described with a Rayleigh model using enrichment factors of −16.5%o and −15.8%o for PCE, and −17.2%o and −16.6%o for TCE. Fractionation was similar in all experiments, with a mean enrichment factor of −16.5%o ± 0.6%o. The occurrence of such large enrichment factors indicates that isotopic analysis can be used to monitor the dechlorination of PCE and TCE by vitamin B12 and remediation of ground water plumes. Evidence indicates that isotopic fractionation is taking place during complexation of the chlorinated ethenes to vitamin B12, as has been suggested for reductive dechlorination by zero valent iron. The differences between e values for this reaction and those observed for anaerobic biodegradation of the chlorinated ethenes suggest that there may be differences in the rate-determining step for these two processes.     

The contribution of snow condition trends to future ground climate

Global climate models predict that terrestrial northern high-latitude snow conditions will change substantially over the twenty-first century. Results from a Community Climate System Model simulation of twentieth and twenty-first (SRES A1B scenario) century climate show increased winter snowfall (+10–40%), altered maximum snow depth (?5 ± 6 cm), and a shortened snow-season (?14 ± 7 days in spring, +20 ± 9 days in autumn). By conducting a series of prescribed snow experiments with the Community Land Model, we isolate how trends in snowfall, snow depth, and snow-season length affect soil temperature trends. Increasing snowfall, by countering the snowpack-shallowing influence of warmer winters and shorter snow seasons, is effectively a soil warming agent, accounting for 10–30% of total soil warming at 1 m depth and ~16% of the simulated twenty-first century decline in near-surface permafrost extent. A shortening snow season enhances soil warming due to increased solar absorption whereas a shallowing snowpack mitigates soil warming due to weaker winter insulation from cold atmospheric air. Snowpack deepening has comparatively less impact due to saturation of snow insulative capacity at deeper snow depths. Snow depth and snow-season length trends tend to be positively related, but their effects on soil temperature are opposing. Consequently, on the century timescale the net change in snow state can either amplify or mitigate soil warming. Snow state changes explain less than 25% of total soil temperature change by 2100. However, for the latter half of twentieth century, snow state variations account for as much as 50–100% of total soil temperature variations.     

Assimilation of snow covered area information into hydrologic and land-surface models

This paper describes a data assimilation method that uses observations of snow covered area (SCA) to update hydrologic model states in a mountainous catchment in Colorado. The assimilation method uses SCA information as part of an ensemble Kalman filter to alter the sub-basin distribution of snow as well as the basin water balance. This method permits an optimal combination of model simulations and observations, as well as propagation of information across model states. Sensitivity experiments are conducted with a fairly simple snowpack/water-balance model to evaluate effects of the data assimilation scheme on simulations of streamflow. The assimilation of SCA information results in minor improvements in the accuracy of streamflow simulations near the end of the snowmelt season. The small effect from SCA assimilation is initially surprising. It can be explained both because a substantial portion of snowmelts before any bare ground is exposed, and because the transition from 100% to 0% snow coverage occurs fairly quickly. Both of these factors are basin-dependent. Satellite SCA information is expected to be most useful in basins where snow cover is ephemeral. The data assimilation strategy presented in this study improved the accuracy of the streamflow simulation, indicating that SCA is a useful source of independent information that can be used as part of an integrated data assimilation strategy.     

The Bragg Crystal Spectrometer for SOLAR-A

The Bragg Crystal Spectrometer (BCS) is one of the instruments which makes up the scientific payload of the SOLAR-A mission. The spectrometer employs four bent germanium crystals, views the whole Sun and observes the resonance line complexes of H-like Fexxvi and He-like Fexxv, Caxix, and Sxv in four narrow wavelength ranges with a resolving power (/) of between 3000 and 6000. The spectrometer has approaching ten times better sensitivity than that of previous instruments thus permitting a time resolution of better than 1 s to be achieved. The principal aim is the measurement of the properties of the 10 to 50 million K plasma created in solar flares with special emphasis on the heating and dynamics of the plasma during the impulsive phase. This paper summarizes the scientific objectives of the BCS and describes the design, characteristics, and performance of the spectrometers.After the launch the name of SOLAR-A has been changed to YOHKOH.Tragically Professor K. Tanaka died on January 2, 1990.