The effect of peat structure on the spatial distribution of biogenic gases within bogs

Northern peatlands are a large source of atmospheric methane (CH₄) and both a source and a sink of atmospheric carbon dioxide (CO₂). The rate and temporal variability in gas exchanges with peat soils is directly related to the spatial distribution of these free‐phase gases within the peat column. In this paper, we present results from surface and borehole ground‐penetrating radar surveys – constrained with direct soil and gas sampling – that compare the spatial distribution of gas accumulations in two raised bogs: one in Wales (UK), the other in Maine (USA). Although the two peatlands have similar average thickness, physical properties of the peat matrix differ, particularly in terms of peat type and degree of humification. We hypothesize that these variations in physical properties are responsible for the differences in gas distribution between the two peatlands characterized by (1) gas content up to 10.8% associated with woody peat and presence of wood layers in Caribou Bog (Maine) and (2) a more homogenous distribution with gas content up to 5.7% at the surface (i.e. <0.5 m deep) in Cors Fochno (Wales). Our results highlight the variability in biogenic gas accumulation and distribution across peatlands and suggest that the nature of the peat matrix has a key role in defining how biogenic gas accumulates within and is released to the atmosphere from peat soils. © 2015 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Tasman Sea guyots

Tasman Sea guyots are former volcanic islands that have subsided an average of 166 fathoms since the Middle or Late Tertiary. These guyots have heights up to 2333 fathoms above the surrounding sea floor; their flat-topped platforms are at depths ranging from 50 to 500 fathoms below present sea level. Reef formations are found along the edges and on the tops of the guyots. Volcanic rocks dredged from these truncated undersea mountains are alkaline olivine basalts with large augite, olivine and plagioclase phenocrysts in a glassy matrix. Limestones dredged from the guyots are either hard, light brown, massive foraminiferal limestones or grey, porous limestones composed mainly of skeletal material. Using foraminiferal evidence we assign an age for the limestone accumulation of Late Pliocene or Early Pleistocene. Phosphorite is also present and is thought to be formed from the replacement of carbonate ions in calcareous material by phosphate ions. There is some evidence of direct precipitation of phosphatic material as coatings on many of the basalt samples.     

Hydrological data assimilation with the ensemble Kalman filter: Use of streamflow observations to update states in a distributed hydrological model

This paper describes an application of the ensemble Kalman filter (EnKF) in which streamflow observations are used to update states in a distributed hydrological model. We demonstrate that the standard implementation of the EnKF is inappropriate because of non-linear relationships between model states and observations. Transforming streamflow into log space before computing error covariances improves filter performance. We also demonstrate that model simulations improve when we use a variant of the EnKF that does not require perturbed observations. Our attempt to propagate information to neighbouring basins was unsuccessful, largely due to inadequacies in modelling the spatial variability of hydrological processes. New methods are needed to produce ensemble simulations that both reflect total model error and adequately simulate the spatial variability of hydrological states and fluxes.     

Expansion rate and geometry of floating vegetation mats on the margins of thermokarst lakes,northern Seward Peninsula,Alaska, USA

Investigations on the northern Seward Peninsula in Alaska identified zones of recent (<50 years) permafrost collapse that led to the formation of floating vegetation mats along thermokarst lake margins. The occurrence of floating vegetation mat features indicates rapid degradation of near‐surface permafrost and lake expansion. This paper reports on the recent expansion of these collapse features and their geometry is determined using geophysical and remote sensing measurements. The vegetation mats were observed to have an average thickness of 0.57 m and petrophysical modeling indicated that gas content of 1.5–5% enabled floatation above the lake surface. Furthermore, geophysical investigation provides evidence that the mats form by thaw and subsidence of the underlying permafrost rather than terrestrialization. The temperature of the water below a vegetation mat was observed to remain above freezing late in the winter. Analysis of satellite and aerial imagery indicates that these features have expanded at maximum rates of 1–2 m yr^‐1 over a 56 year period. Including the spatial coverage of floating ‘thermokarst mats’ increases estimates of lake area by as much as 4% in some lakes. Copyright © 2011 John Wiley & Sons, Ltd.     

A Comparison Between Contour Elevation Data Sources for DEM Creation and Soil Carbon Prediction, Coshocton, Ohio

A raster and vector GIS was created for the North Appalachian Experimental Watershed (NAEW) from legacy (1960) 1:2,400‐scale contour maps. The intent of the study was to use terrain data for the spatial modeling of soil organic carbon. It was hypothesized that DEMs derived from these data would be more accurate and therefore more useful for terrain‐based soil modeling than those from USGS 1:24,000‐scale contour data. Central tasks for this study were to digitally capture the 1:2,400‐scale maps, convert digital contour data sources to raster DEMs at multiple resolutions, and derive terrain attributes. A flexible approach was adopted, using software outside of mainstream GIS sources where scientifically or practically advantageous. Elevation contours and streamlines were converted to raster DEMs using ANUDEM. DEMs ranging in resolution from 0.5–30 m were tested for accuracy against precision carrier‐phase GPS data. The residual standard deviation was 1.68 meters for the USGS DEM and 0.36 meters for the NAEW DEM. The optimal horizontal resolution for the NAEW DEM was 5 m and for the USGS 10 m. Five and 10 m resolution DEMs from both data sources were tested for carbon prediction. Multiple terrain parameters were derived as proxies for surficial processes. Soil samples (n = 184) were collected on four zero‐order watersheds (conventional tillage, no‐till, hay and pasture). Multiple least squares regressions (m.l.s.) were used to predict mass C (kg m^?2, 30 cm depth) from topographic information. Model residuals were not spatially autocorrelated. Statistically significant topographic parameters were attained most consistently from the 5 m NAEW DEM. However, topography was not a strong predictor of carbon for these watersheds, with r² ranging from 0.23 to 0.58.     

Highly localised distribution patterns of juvenile sea cucumber Australostichopus mollis

Information on the environmental characteristics of the juvenile habitat of many deposit-feeding sea cucumber species is limited, despite most fished species exhibiting rapid localised depletion. The current study combined large and small scale surveying techniques within a New Zealand harbour to identify areas with high densities of juvenile Australostichopus mollis, a commercially valuable aspidochirote holothurian. Data from detailed surveys were used to relate densities of juveniles and adults with measures of physical habitat characteristics including depth, sediment facies type, grain size range, as well as measures of chlorophyll-a, phaeopigment, carbon and nitrogen content of surface sediment. Results revealed a highly localised distribution of juvenile A. mollis focused on one site associated with an area of high adult density. Sites of high juvenile A. mollis density were characterised by sediment qualities favouring epibenthic detritivorous deposit feeding, including high nitrogen content, high phaeopigment:chlorophyll-a ratio and small grain size. The high-density juvenile site had facies that were further characterised by the presence of large shell fragments (>10 cm length) of the horse mussel (Atrina zelandica), which may provide a unique settlement microhabitat for early juveniles. Unlike some other sea cucumber species, juvenile A. mollis shows no distinct spatial separation from adult sea cucumbers, no association with dense macroalgae and no clear preference for shallower depths than adults. Overall, the results illustrate the highly localised pattern of recruitment of this species to a widely distributed adult population, which may help to explain the lack of previous observations of juveniles in this species. These results indicate the importance of identifying and protecting what appear to be very specific juvenile habitats in deposit-feeding sea cucumbers to ensure continuing recruitment to exploited populations.     

Microbial carbon cycling in oligotrophic regional aquifers near the Tono Uranium Mine, Japan as inferred from δC and ΔC values of in situ phospholipid fatty acids and carbon sources

Microorganisms are ubiquitous in deep subsurface environments, but their role in the global carbon cycle is not well-understood. The natural abundance δ¹³C and Δ¹⁴C values of microbial membrane phospholipid fatty acids (PLFAs) were measured and used to assess the carbon sources of bacteria in sedimentary and granitic groundwaters sampled from three boreholes in the vicinity of the Tono Uranium Mine, Gifu, Japan. Sample storage experiments were performed and drill waters analyzed to characterize potential sources of microbial contamination. The most abundant PLFA structures in all waters sampled were 16:0, 16:1ω7c, cy17:0, and 18:1ω7c. A PLFA biomarker for type II methanotrophs, 18:1ω8c, comprised 3% and 18% of total PLFAs in anoxic sedimentary and granitic waters, respectively, sampled from the KNA-6 borehole. The presence of this biomarker was unexpected given that type II methanotrophs are considered obligate aerobes. However, a bacterium that grows aerobically with CH₄ as the sole energy source and which also produces 56% of its total PLFAs as 18:1ω8c was isolated from both waters, providing additional evidence for the presence of type II methanotrophs. The Δ¹⁴C values determined for type II methanotroph PLFAs in the sedimentary (−861‰) and granite (−867‰) waters were very similar to the Δ¹⁴C values of dissolved inorganic carbon (DIC) in each water (∼−850‰). This suggests that type II methanotrophs ultimately derive all their carbon from inorganic sources, whether directly from DIC and/or from CH₄ produced by the reduction of DIC. In contrast, δ¹³C values of type II PLFAs in the sedimentary (−93‰) and granite (−60‰) waters indicate that these organisms use different carbon assimilation schemes in each environment despite very similar δ¹³C_CH4 values (∼−95‰) for each water. The δ¹³C_PLFA values (−28‰ to −45‰) of non-methanotrophic bacteria in the KNA-6 LTL water do not clearly distinguish between heterotrophic and autotrophic metabolisms, but Δ¹⁴C_PLFA values indicate that >65% of total bacteria filtered from the KNA-6 LTL water are heterotrophs. Ancient Δ¹⁴C values (∼−1000‰) of some PLFAs suggest that many heterotrophs utilize ancient organic matter, perhaps from lignite seams within the sedimentary rocks. The more negative range of δ¹³C_PLFA values determined for the KNA-6 granitic water (−42‰ to −66‰) are likely the result of a microbial ecosystem dominated by chemolithoautotrophy, perhaps fuelled by abiogenic H₂. Results of sample storage experiments showed substantial shifts in microbial community composition and δ¹³C_PLFA values (as much as 5‰) during 2-4 days of dark, refrigerated, aseptic storage. However, water samples collected and immediately filtered back in the lab from freshly drilled MSB-2 borehole appeared to maintain the same relative relationships between δ¹³C_PLFA values for sedimentary and granitic host rocks as observed for samples directly filtered under artesian flow from the KNA-6 borehole of the Tono Uranium Mine.     

Census and typology of braided rivers in the French Alps

Following the implementation of the European Water Framework Directive (WFD) and the need to reach a “good ecological status” for rivers, key-questions are being raised about braided rivers. Before any environmental policy can be drawn up, these rivers need to be located, long term changes must be evaluated, and the regional diversity of such systems must be understood, as their inner complexity has not yet been well studied. Therefore, the aim of this work is to carry out a census of the braided channels of the French Alps and to establish a typology based on basic geomorphic indicators. A minimum estimate of the cumulative length of braided rivers prior to major infrastructure construction amounted to 1214 km. Around 53% of these rivers have disappeared during the last two centuries in relation to embankment or channelization, but a loss of 17% is still unexplained. The range in catchment size, mean slope and active channel width has been determined for the Western Alpine braided channels as well as the range in changes due to narrowing, widening and shifting. Seven types of braided rivers have been distinguished based on geographical settings (climate conditions and geology) and differences in terms of adjustment to human pressure on peak flow and sediment delivery. The percentage area of islands in the active channel and the relative length of banks also show a regional difference. Maximum and minimum thresholds of braided activity have been established taking into account the active channel width and the catchment area. The position of the studied reaches between these two thresholds are discussed in relation to position of rivers known in the literature, considering both long-term trends and short-term fluctuations in channel width.     

Rosetta-Alice observations of exospheric hydrogen and oxygen on Mars

The European Space Agency’s Rosetta spacecraft, en route to a 2014 encounter with comet 67P/Churyumov-Gerasimenko, made a gravity assist swing-by of Mars on 25 February 2007, closest approach being at 01:54 UT. The Alice instrument on board Rosetta, a lightweight far-ultraviolet imaging spectrograph optimized for in situ cometary spectroscopy in the 750-2000 Å spectral band, was used to study the daytime Mars upper atmosphere including emissions from exospheric hydrogen and oxygen. Offset pointing, obtained five hours before closest approach, enabled us to detect and map the H i Lyman-α and Lyman-β emissions from exospheric hydrogen out beyond 30,000 km from the planet’s center. These data are fit with a Chamberlain exospheric model from which we derive the hydrogen density at the 200 km exobase and the H escape flux. The results are comparable to those found from the Ultraviolet Spectrometer experiment on the Mariner 6 and 7 fly-bys of Mars in 1969. Atomic oxygen emission at 1304 Å is detected at altitudes of 400-1000 km above the limb during limb scans shortly after closest approach. However, the derived oxygen scale height is not consistent with recent models of oxygen escape based on the production of suprathermal oxygen atoms by the dissociative recombination of .