The Pushtashan juvenile suprasubduction zone assemblage of Kurdistan (northeastern Iraq): A Cretaceous (Cenomanian) Neo-Tethys missing link

The Pushtashan suprasubduction zone assemblage of volcanic rocks, gabbros, norites and peridotites occurs in the Zagros suture zone, Kurdistan region, northeastern Iraq. Volcanic rocks are dominant in the assemblage and consist mainly of basalt and basaltic andesite flows with interlayered red shale and limestone horizons. Earlier lavas tend to be MORB-like, whereas later lavas display island arc tholeiite to boninitic geochemical characteristics. Tholeiitic gabbros intrude the norites and display fractionation trends typical of crystallisation under low-pressure conditions, whereas the norites display calc-alkaline traits, suggesting their source included mantle metasomatised by fluids released from subducted oceanic crust. Enrichment of Rb, Ba, Sr, Th and the presence of negative Nb anomalies indicate generation in a suprasubduction zone setting. Trondhjemite and granodiorite intrusions are present in the volcanic rocks, gabbros and norites. SHRIMP U-Pb dating of magmatic zircons from a granodiorite yields a mean~(206)Pb/~(238)U age of 96.0 ±2.0 Ma(Cenomanian). The initial ε_(Hf) value for the zircons show a narrow range from +12.8 to+15.6, with a weighted mean of + 13.90±0.96. This initial value is within error of model depleted mantle at 96 Ma or slightly below that, in the field of arc rocks with minimal contamination by older continental crust. The compositional bimodality of the Pushtashan suprasubduction sequence suggests seafloor spreading during the initiation of subduction, with a lava stratigraphy from earlyerupted MORB transitioning into calc-alkaline lavas and finally by 96 Ma intrusion of granodioritic and trondhjemitic bodies with juvenile crustal isotopic signatures. The results confirm another Cretaceous arc remnant preserved as an allochthon within the Iraqi segment of the Cenozoic Zagros suture zone. Implications for the closure of Neo-Tethys are discussed.     

A New Equation for the Shear Strength of Cable Bolts Incorporating the Energy Balance Theory

The application of cable bolts as a secondary support system is an increasing trend in underground coal mines worldwide. The performances of cable bolts have been evaluated under both axial and shear loading conditions. Two methods of testing cables for shear, single and double shear, have been recognised. This paper examines the shear behaviour of a variety of cable bolts under different pre-tension loads by double shear testing. Plain, spiral and the combination of both cable types were used in this study. The initial axial load and the type of cable bolts are the main factors affecting their shear strength. By increasing the axial pre-tension load, the peak shear load occurs at lower shear displacement. The failure angle due to cable bending across the joint at different pre-tension loads varied between 41° and 49°. This demonstrates that the ratio of axial and perpendicular displacements is almost constant and on average the failure occurs at about 45°. A novel analytical model is proposed to evaluate the shear behaviour of pre-tensioned fully grouted cable bolts subjected to double shearing. Energy and Fourier Series methods were incorporated in the model to simulate the shear behaviour of cable bolts. The comparison of the experimental results with the proposed model shows a good agreement.     

Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

A state boundary surface model for improving the dilatancy simulation of granular material in reinforced anchors

It is acknowledged that for extending the experimental results to real scale design, it is necessary to use an appropriate numerical analysis. The good analysis in geotechnical problems needs to adopt a suitable constitutive model for the materials. This paper presents a modeling approach to investigate the complex behavior of granular trench and reinforcement system. For this purpose, an experimental and numerical investigation has been carried out on the behavior of pullout resistance of an embedded anchor (circular plate) with and without geogrid reinforcement layers in stabilized loose and dense sand using a granular trench. Different parameters have been considered, such as number of geogrid layers, embedment ratios, relative density of soil, and height ratios of granular trench. Finite element analysis with Hardening Soil Model was utilized for sand and CANAsand constitutive model was used for granular trench to investigate failure mechanism and the associated rupture surfaces. Results showed that, when soil was improved with the granular-geogrid trench, the uplift force significantly increased, but in geogrid-reinforced granular trench condition, the ultimate pullout resistance at failure increased as the number of geogrid layers increased up to the third layer, the fifth layer had a negligible effect in comparison with the third layer of reinforcement. The ultimate uplift capacity of anchor plate and the variation of surface deformation for all the tests indicated a close agreement between the experimental and numerical models.     

Uncertainty assessment of the multilayer perceptron (MLP) neural network model with implementation of the novel hybrid MLP-FFA method for prediction of biochemical oxygen demand and dissolved oxygen: a case study of Langat River

Accurate prediction of the chemical constituents in major river systems is a necessary task for water quality management, aquatic life well-being and the overall healthcare planning of river systems. In this study, the capability of a newly proposed hybrid forecasting model based on the firefly algorithm (FFA) as a metaheuristic optimizer, integrated with the multilayer perceptron (MLP-FFA), is investigated for the prediction of monthly water quality in Langat River basin, Malaysia. The predictive ability of the MLP-FFA model is assessed against the MLP-based model. To validate the proposed MLP-FFA model, monthly water quality data over a 10-year duration (2001–2010) for two different hydrological stations (1L04 and 1L05) provided by the Irrigation and Drainage Ministry of Malaysia are used to predict the biochemical oxygen demand (BOD) and dissolved oxygen (DO). The input variables are the chemical oxygen demand (COD), total phosphate (PO₄), total solids, potassium (K), sodium (Na), chloride (Cl), electrical conductivity (EC), pH and ammonia nitrogen (NH₄-N). The proposed hybrid model is then evaluated in accordance with statistical metrics such as the correlation coefficient (r), root-mean-square error, % root-mean-square error and Willmott’s index of agreement. Analysis of the results shows that MLP-FFA outperforms the equivalent MLP model. Also, in this research, the uncertainty of a MLP neural network model is analyzed in relation to the predictive ability of the MLP model. To assess the uncertainties within the MLP model, the percentage of observed data bracketed by 95 percent predicted uncertainties (95PPU) and the band width of 95 percent confidence intervals (d-factors) are selected. The effect of input variables on BOD and DO prediction is also investigated through sensitivity analysis. The obtained values bracketed by 95PPU show about 77.7%, 72.2% of data for BOD and 72.2%, 91.6% of data for DO related to the 1L04 and 1L05 stations, respectively. The d-factors have a value of 1.648, 2.269 for BOD and 1.892, 3.480 for DO related to the 1L04 and 1L05 stations, respectively. Based on the values in both stations for the 95PPU and d-factor, it is concluded that the neural network model has an acceptably low degree of uncertainty applied for BOD and DO simulations. The findings of this study can have important implications for error assessment in artificial intelligence-based predictive models applied for water resources management and the assessment of the overall health in major river systems.     

A hybrid computational approach to formulate soil deformation moduli obtained from PLT

In this study, new empirical equations were developed to predict the soil deformation moduli utilizing a hybrid method coupling genetic programming and simulated annealing, called GP/SA. The proposed models relate secant (E_s), unloading (E_u) and reloading (E_r) moduli obtained from plate load–settlement curves to the basic soil physical properties. Several models with different combinations of the influencing parameters were developed and checked to select the best GP/SA models. The database used for developing the models was established upon a series of plate load tests (PLT) conducted on different soil types at various depths. The validity of the models was tested using parts of the test results that were not included in the analysis. The validation of the models was further verified using several statistical criteria. A traditional GP analysis was performed to benchmark the GP/SA models. The contributions of the parameters affecting E_s, E_u and E_r were analyzed through a sensitivity analysis. The proposed models are able to estimate the soil deformation moduli with an acceptable degree of accuracy. The E_s prediction model has a remarkably better performance than the models developed for predicting E_u and E_r. The simplified formulations for E_s, E_u and E_r provide significantly better results than the GP-based models and empirical models found in the literature.     

Time series analysis of daily rainfall and streamflow in a volcanic dike-intruded aquifer system, O��ahu, Hawai��i, USA

A conceptual model of groundwater occurrence was developed for a dike-intruded aquifer system in M??kaha valley, O??ahu, Hawai??i, USA, and used to explain the impacts of water resource development on groundwater levels and streamflow. Time-series analyses were applied to two subsets of daily rainfall, total flow, and baseflow??from the third (1946?C1968) and fourth (1968?C1991) periods of development??to evaluate changes in streamflow response. Autocorrelation, cross-correlation, squared coherency and phase functions were used to estimate the decorrelation lag time, and the correlation length, linearity with frequency, and frequency response delay between rainfall and streamflow. The decorrelation lag time for total flow and baseflow declined by 16?C20?days (d). The correlation length between rainfall and streamflow declined 4?C7?d for total flow and 10?C13?d for baseflow. The squared coherency function indicates an overall decline in linearity between rainfall and total flow across most frequencies. The changes in hydrologic response following increased water-resource development is consistent with a model of groundwater depletion resulting in less groundwater discharge and more induced groundwater recharge. Changes in streamflow response are inconsistent with observed changes in rainfall and imply that streamflow decline is more likely to be the result of groundwater pumping.     

New ophiolite occurrences in Sudan and constraint on the western boundary of the Nubian Shield: Petrographical and geochemical evidence

Important mafic–ultramafic masses have been located for the first time in the intersection area between the Keraf Shear Zone and the Nakasib Suture Zone of the Nubian Shield. The masses, comprising most of the members of the ophiolite suite, are Sotrebab and Qurun complexes east of the Nile, and Fadllab complex west of the Nile. The new mafic–ultramafic masses are located on the same trend of the ophiolitic masses decorating the Nakasib Suture. A typical complete ophiolite sequence has not been observed in these complexes, nevertheless, the mafic–ultramafic rocks comprise basal unit of serpentinite and talc chlorite schists overlain by a thick cumulate facies of peridotites, pyroxenites and layered gabbros overlain by basaltic pillow lavas with dolerite dykes and screens of massive gabbros. Associated with pillow lavas are thin layers of carbonates and chert. The best section of cumulate mafic–ultramafic units has been observed in Jebel Qurun and El Fadlab complexes, comprising peridotites, pyroxenites and layered gabbros. Dolerite dykes and screens of massive gabbros have been observed with basaltic pillow lava sections in Wadi Dar Tawaiy. The basal ultramafic units of the complexes have been fully or partly retrograded to chlorite magnetite schist and talc to talc-carbonate rocks (listowenites), especially in the Jebel Qurun and Sotrebab complexes. Petrographically, the gabbros (layered and massive) and the basaltic pillow lavas show mineral assemblages of epidote amphibolite facies. The mafic members from the three complexes show a clear tholeiitic trend and oceanic floor affinity. The pillow lavas plot in the field of oceanic floor basalt, namely in the back arc field. Primitive mantle normalized spider diagram of the pillow lavas reveals a closer correspondence to Enrich-Mid-Oceanic Ridge Basalt (E-MORB) type, which is confirmed by the flat chondrite normalized Rare Earth Elements (REE) pattern. Field, petrographical and geochemical evidence supports ophiolitic origin of the three complexes. The newly discovered ophiolitic complexes mark the western continuation of the Nakasib Suture Zone.     

Neoproterozoic contaminated MORB of Wadi Ghadir ophiolite,NE Africa: Geochemical and Nd and Sr isotopic constraints

The ophiolitic metabasalts (pillowed and sheeted dikes) of Wadi Ghadir area, Eastern Desert, Egypt, were analyzed for their major, trace and rare earth elements, Nd and Sr isotopes and the chemistry of their plagioclase, amphibole and chlorite was also reported. Geochemically these rocks range from tholeiitic basalt to basaltic andesite. The generally low MgO, Cr and Ni and high Zr contents are consistent with derivation of these rocks from an evolved magma. The high TiO₂ contents (mostly between 1.76% and 2.23%) classify Wadi Ghadir ophiolitic metabasalts as MORB ophiolite. The chondrite-normalized REE patterns of most samples display small LREE-enrichment with (La/Yb)_n ranging from 1.44 to 2.56. The MORB-normalized spider diagram shows variable LILE abundances, which are either similar to or enriched relative to MORB, and most samples display small Nb depletion. The abundances of some LILE (Ba, Rb and K) as well as Na and Si were modified by post-magmatic seafloor hydrothermal alteration. Enrichment of the least mobile LILE (Th & U) indicates that Wadi Ghadir ophiolitic metabasalts are akin to C (contaminated)-MORB. These geochemical characteristics are similar to BABB modified by contamination.Wadi Ghadir metabasalts have low initial Sr ratios (0.7010–0.7034) which are similar to those of MORB, while their ε_Nd(t) values (+7.7–+4.5) are either more or less positive than the value of depleted mantle (DM). The more positive ε_Nd(t) values indicate DM source for these basalts, while the less positive ε_Nd(t) values reflect the involvement of slightly older component in Wadi Ghadir ophiolite. We suggest that the parent magma of metabasalts was contaminated by slightly older material, most probably oceanic-arc crustal rocks, which caused enrichment in LREE, and by analogy LILE, but did not significantly affect Nd isotopic systematics or modify Sr isotopes.Such contaminated MORB character also revealed by other ophiolitic metavolcanics in the Central Eastern Desert, contrasting the N-MORB character of the Gerf ophiolite in the South Eastern Desert. Moreover, the present work suggests the increase of the degree of contamination of the ophiolitic metabasalts from south to north in the Central Eastern Desert.     

Arsenic contamination in groundwater and its proposed remedial measures

Arsenic contamination occurs in groundwater of Bangladesh mainly from the alluvial and deltaic sediments. Arsenic contamination of groundwater in Bangladesh was first detected more than a decade ago and the ’shallow tubewells’ were reported as the main source of arsenic contaminated water. From the nutritional and metabolic points of view, arsenic is likely to adversely affect human health and nutrition. Up to now, several studies have been carried out on this context; however, inadequate knowledge on arsenic sources, mobilization and transport still remains as a constraint due to lack of data, information and technological advances. Thus, a review study has been undertaken on the sources of arsenic, its causes, mobilization, transport, effects on human health, arsenic test procedures and removal methods, in the context of groundwater contamination in Bangladesh, and finally sustainable remedial measures of arsenic have been proposed. This study suggests that laboratory facilities for testing of arsenic and effects of enhanced groundwater pumping, phosphate fertilizer etc., need to be updated, expanded and studied. This review work is significant to further knowledge improvement, as the topic is general and worldwide. It can be concluded that the integration of the proposed remedial measures with the national geographic information system interface database relating to arsenic for analysis, production of hazard maps, and dissemination on television show for the planners, engineers, managers, field supervisors and affected people, can reach at the sustainable solution for mitigating arsenic and associated problems successfully in Bangladesh.