安徽马鞍山市当涂地区地下水水化学特征及演化机制

【研究目的】 了解长江中下游平原地区地下水流系统并深入分析其地下水水化学特征及其演化机制。【研究方法】 综合马鞍山市当涂地区的水文地质条件、水动力场等,基于研究区水化学基本特征,运用多元统计分析、水化学图件、离子比值和反向水文地球化学模拟等方法对该地区浅层地下水水化学演化进行分析。【研究结果】 结果表明：（1）研究区地下水主要为低矿化度偏碱性水,地下水组分中阳离子以Ca²⁺和Mg²⁺为主,阴离子以HCO₃^-和SO₄^2-为主。（2）研究区地下水水化学类型主要可分为7类,其中松散岩类孔隙含水岩组和碎屑岩类孔隙裂隙含水岩组的水化学类型主要为HCO₃^-Ca型、HCO₃^-Ca·Na型、HCO₃·Cl-Ca·Na型以及HCO₃^-Ca·Mg型;基岩类裂隙含水岩组的化学类型主要为HCO₃·SO₄-Ca·Mg型和SO₄·HCO₃^-Ca·Mg型。（3）研究区浅层地下水水样超标率为46%,总体水质较差,超标率较高的组分依次为Mn、高锰酸盐指数（COD_Mn）、硝酸盐（以N计）、Fe、As、氨氮（以N计）等。（4）研究区地下水的化学组分主要受到岩石风化作用的控制;此外,还存在Na-Ca的正向阳离子交替吸附作用。反向水文地球化学模拟结果进一步定量论证了水岩相互作用对本区浅层地下水组分的形成和演化起着主导作用。【结论】 研究区地下水主要为低矿化度偏碱性,主要可分为松散岩类孔隙水、碎屑岩类孔隙裂隙水和基岩类裂隙水。主要离子比例和反向水文地球化学模拟揭示了本区浅层地下水化学组分主要是地下水溶滤方解石、白云石等碳酸盐矿物、石英、长石等硅酸盐矿物,高岭土等黏土矿物以及岩盐、石膏等达到过饱和之后形成的。     

U–Pb and Re–Os geochronology and geodynamic setting of the Dabaoshan polymetallic deposit, northern Guangdong Province, South China

The Dabaoshan polymetallic deposit in northern Guangdong Province contains iron, copper, lead, zinc, molybdenum, tungsten and sulfur mineral resources. Porphyry-type Mo(W) and skarn-type Mo-W mineralization occurs along the internal and external contact zones of the granodioritic porphyry, respectively. LA-ICP-MS U–Pb dating of zircons from two granodioritic porphyry samples yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 175.8 ± 1.5 Ma (MSWD = 0.037) and 175.0 ± 1.7 Ma (MSWD = 0.41). They can be pooled together to yield a combined weighted age of 175.4 ± 1.6 Ma (MSWD = 0.26), which is interpreted as the emplacement age of the granodioritic porphyry. Re–Os dating of three molybdenite samples from porphyry and skarn ores yielded consistent model ages of 163.2 ± 2.3 Ma to 165.2 ± 2.4 Ma, with a weighted mean of 163.9 ± 1.3 Ma (MSWD = 0.81), which is the age of Mo–W mineralization. These ages are consistent with the molybdenite Re–Os model age (164.7 ± 3 Ma) measured by Mao et al. (2004a) for the stratiform Cu–Pb–Zn orebody, and they can yield a weighted mean of 164.0 ± 2.5 Ma (MSWD = 0.16). This implies that Mo–W and Cu–Pb–Zn mineralization in the Dabaoshan polymetallic deposit are the products of one mineralization event. The mineralization in the deposit coincides closely with that of Mo-polymetallic mineralization (164–149 Ma) elsewhere in the Nanling region, comprising an important polymetallic metallogenic belt of south China, and corresponds to the second episode of Mesozoic metallogenesis in South China. Combined with previous studies, we suggest that the Dabaoshan polymetallic deposit is related to post-collisional lithosphere extension in the Nanling region of South China. Geological data and Pb isotopic evolution diagrams, together with stable isotopic data of fluid inclusions (δ¹⁸O = − 3.75–7.0‰, δD = − 50.7 to − 56.1‰) and ore sulfides (δ³⁴S = − 2–3‰), suggest a genetic relationship between the Dabaoshan polymetallic deposit, the granodioritic porphyry and the dacitic porphyry. These data, combined with the Re content (64.7 to 102.4 ppm) of molybdenite, indicate that the ore-forming components were derived from mixed crustal and mantle sources.     

西藏南羌塘增生杂岩中俯冲反向驱动高压变质岩折返:来自猫耳山大型拆离断层的启示

大洋岩石圈俯冲增生过程中可能伴随着复杂的深部板片运动过程。高压变质岩无疑是记录这些深部过程的良好载体。最近的研究提出,在特定情况下,双向俯冲中占主导的俯冲板块拖曳另一侧板块发生反向运动,从而短板片可能被另一侧长板片拖出。该研究提示我们关注俯冲增生过程中这种可能的“不正常”的板片运动方式,从而客观而全面地剖析碰撞造山带。现有高压变质岩折返模式中,除了俯冲隧道流模式,其余模式均强调单次快速折返。然而,俯冲反向运动导致的折返过程有所不同:对单个高压变质岩来说仍是快速折返,但是对整体高压变质岩带来说,整个俯冲反向期间必然都存在高压变质岩折返,从而形成较长的折返过程持续时间。对上地壳层次的折返相关构造变形的研究有助于揭示上述过程。     

Spatial and temporal trends of dust storms across desert regions of Iran

Dust storms are among natural and anthropogenic hazards for socioeconomic resources, especially in desert regions. In recent years, dust storms have become a serious problem, especially in desert regions of Iran. This study investigates temporal and spatial variation of dust storm frequency in desert regions of Iran. The number of dusty days (NDD) are collected from 22 stations across the region. The statistical analysis of NDD time series is carried out to show both spatial and seasonal pattern of dust storm occurrence in the region. The regional map of statistical characteristics indicates a north to south increasing dust storm frequency. The spatial map also reveals higher year-to-year variation in south eastern Iran. The seasonality of NDD shows the highest frequency for summer followed by the spring and autumn seasons. The popular Mann–Kendall and the bootstrap MK test to consider serial correlation are then applied for Trend assessment. Results showed both negative (across the north and northwestern regions) and positive trend (across south and south eastern regions) in the annual and seasonal NDD time series. This north-to-south gradient in the spatial and temporal frequency NDD may arise from harsh dry and gusty winds as well as intense land use change in the south eastern territories of Iran. However, more careful and detailed studies are required to connect environmental conditions to change in NDD frequency.     

Denoising and improving the quality of seismic data using combination of DBM filter and FX deconvolution

Seismic data denoising, random noise attenuation (RNA) and spike-like noise suppression, is a main consideration for improving the quality of records. RNA could increase signal to noise ratio (S/N) to avoid misinterpretation of seismic data. In this research, a novel method is created by using the combination of frequency-offset deconvolution (FXD) and decision-based median (DBM) filter for RNA from seismic data. The method is applied in two main phases; FXD is focused to remove the Gaussian noise and DBM filter is focused to attenuate the impulsive noise and spikes. To implement and verify the method, three types of data are used: two synthetic models (a model with linear events and a model with hyperbolic events) and an observed seismic section. The ability of the proposed method (FXD-DBM) in comparison of applying each in seismic RNA application is proven. The noise level is reduced obviously, and hence, the S/N of all examined seismic records is increased considerably after denoising by the combination of FX deconvolution and DBM filter. About the real seismic section, suppressing random noise and spikes show up improving the seismic reflector continuity and hence enhancing the interpretability of data. Moreover, some masked events by random noise are clarified in different parts of data after denoising using the planned method.     

Impacts of land use change and groundwater management on long-term nitrate-nitrogen and chloride trends in groundwater of Jeju Island,Korea

Impacts of land use changes and groundwater management actions on groundwater quality were evaluated at the island scale with spatiotemporal trends of NO₃-N and Cl concentrations in groundwater of Jeju Island, Korea. The temporal trends from 1993 to 2012 in the concentrations of NO₃-N and Cl from more than 3900 wells were estimated using the Mann–Kendall trend test and Sen’s slope analysis and compared with the land use change trend for the period 1995–2009. The results indicate that the upward trends in NO₃-N were associated with the expansion of agricultural lands, whereas Cl trends were considered to be affected by other factors in addition to the land use changes. In the mid-mountainous region, the deterioration in the groundwater quality by the both NO₃-N and Cl was expected due to the continuous expansion of agricultural lands. In the lowland area, the NO₃-N and Cl components showed different trends depending on the regions. In the eastern area, increasing trends in NO₃-N were observed due to the development of new agricultural areas, while the Cl concentration was observed to decrease as a result of the regulation on groundwater extraction to reduce seawater intrusion. Our study highlights that a comprehensive interpretation of trends in NO₃-N and Cl and land use changes for long-term periods can provide useful insights to prepare for suitable groundwater management plans in the whole island perspective.     

Forecasting Wave Amplitudes after the Arrival of a Tsunami

The destructive Pacific Ocean tsunami generated off the east coast of Honshu, Japan, on 11 March 2011 prompted the West Coast and Alaska Tsunami Warning Center (WCATWC) to issue a tsunami warning and advisory for the coastal regions of Alaska, British Columbia, Washington, Oregon, and California. Estimating the length of time the warning or advisory would remain in effect proved difficult. To address this problem, the WCATWC developed a technique to estimate the amplitude decay of a tsunami recorded at tide stations within the Warning Center’s Area of Responsibly (AOR). At many sites along the West Coast of North America, the tsunami wave amplitudes will decay exponentially following the arrival of the maximum wave (Mofjeld et al., Nat Hazards 22:71–89, 2000). To estimate the time it will take before wave amplitudes drop to safe levels, the real-time tide gauge data are filtered to remove the effects of tidal variations. The analytic envelope is computed and a 2 h sequence of amplitude values following the tsunami peak is used to obtain a least squares fit to an exponential function. This yields a decay curve which is then combined with an average West Coast decay function to provide an initial tsunami amplitude-duration forecast. This information may then be provided to emergency managers to assist with response planning.     

Paleomagnetic result of the Lower-Cretaceous from Luanping basin,Hebei Province and its tectonic implications*

A paleomagnetic study of about 95 samples from 16 sites sampled in the Early Cretaceous in Luanping basin in Hebei Province was reported. Stepwise thermal demagnetization was used to isolate magnetic components. Most samples have a characteristic direction with a high temperature component above 500°C. The tectonic-corrected data areD = 347.8°,I = 50.4°, α₉₅ = 7.l°, and the corresponding pole position is at 76.1°N, 346.3°E,with dp =6.4°,dm = 3.8°, paleolatitude λ = 31.1°N. This result indicates a counterclockwise post-Cretaceous rotation of 30.7° ±9.8° with respect to the stable Ordos basin in the west of North China Block, and a non-significant northward motion. This rotation could be related to local fault action or structural detachment, or regional NNW-NWWward motion and collision of Kula-Pacific plate with eastern China since the Early Cretaceous.

     

Petrogenesis of the Ulsan carbonate rocks from the south-eastern Kyongsang Basin, South Korea

Abstract The petrogenesis of the Ulsan carbonate rocks in the Mesozoic Kyongsang Basin of South Korea, which have previously been interpreted as limestone of Paleozoic age, is reconsidered in the present study. Within the Kyongsang Basin, a small volume of carbonate rocks, containing a magnetite deposit and spatially associated ultramafic rocks, is surrounded by sedimentary, volcanic and granitic rocks of the Mesozoic age. The simple cross‐cutting relationships and other outcrop features of the area indicate that the carbonate rocks are an intrusive phase and younger than the other surrounding Mesozoic rocks. The Ulsan carbonates have low concentrations of rare earth elements (REE) and trace elements with the carbon and oxygen isotope values in the range of δ¹³C_PDB = 2.4 to 4.0‰ and δ¹⁸O_SMOW = 17.0 to 19.5‰. Outcrop evidence and geochemical signatures indicate that the Ulsan carbonates were formed from crustal carbonate melts, which were generated by the melting/fluxing of crustal carbonate materials, caused by the emplacement‐related processes of alkaline A‐type granitic rocks. Compared to typical mantle‐derived carbonatites associated with silica‐undersaturated, strongly peralkaline systems, the relatively small size and geochemical characteristics of the Ulsan carbonates reflect carbonatite genesis in a silica‐saturated, weakly alkali intrusive system. Major deep‐seated tectonic fractures formed by the collapse of the cauldron or the rift system associated with the opening of the East Sea (Japan Sea) might have facilitated the ascent of the crustal carbonate melts.     

Reconstruction of Horizontal Plasma Motions at the Photosphere from Intensitygrams: A Comparison Between DeepVel,LCT, FLCT,and CST

Direct measurements of plasma motions in the photosphere are limited to the line-of-sight component of the velocity. Several algorithms have therefore been developed to reconstruct the transverse components from observed continuum images or magnetograms. We compare the space and time averages of horizontal velocity fields in the photosphere inferred from pairs of consecutive intensitygrams by the LCT, FLCT, and CST methods and the DeepVel neural network in order to identify the method that is best suited for generating synthetic observations to be used for data assimilation. The Stein and Nordlund (Astrophys. J. Lett.753, L13, 2012) magnetoconvection simulation is used to generate synthetic SDO/HMI intensitygrams and reference flows to train DeepVel. Inferred velocity fields show that DeepVel performs best at subgranular and granular scales and is second only to FLCT at mesogranular and supergranular scales.