Global and regional ocean carbon uptake and climate change: sensitivity to a substantial mitigation scenario

Under future scenarios of business-as-usual emissions, the ocean storage of anthropogenic carbon is anticipated to decrease because of ocean chemistry constraints and positive feedbacks in the carbon-climate dynamics, whereas it is still unknown how the oceanic carbon cycle will respond to more substantial mitigation scenarios. To evaluate the natural system response to prescribed atmospheric ??target?? concentrations and assess the response of the ocean carbon pool to these values, 2 centennial projection simulations have been performed with an Earth System Model that includes a fully coupled carbon cycle, forced in one case with a mitigation scenario and the other with the SRES A1B scenario. End of century ocean uptake with the mitigation scenario is projected to return to the same magnitude of carbon fluxes as simulated in 1960 in the Pacific Ocean and to lower values in the Atlantic. With A1B, the major ocean basins are instead projected to decrease the capacity for carbon uptake globally as found with simpler carbon cycle models, while at the regional level the response is contrasting. The model indicates that the equatorial Pacific may increase the carbon uptake rates in both scenarios, owing to enhancement of the biological carbon pump evidenced by an increase in Net Community Production (NCP) following changes in the subsurface equatorial circulation and enhanced iron availability from extratropical regions. NCP is a proxy of the bulk organic carbon made available to the higher trophic levels and potentially exportable from the surface layers. The model results indicate that, besides the localized increase in the equatorial Pacific, the NCP of lower trophic levels in the northern Pacific and Atlantic oceans is projected to be halved with respect to the current climate under a substantial mitigation scenario at the end of the twenty-first century. It is thus suggested that changes due to cumulative carbon emissions up to present and the projected concentration pathways of aerosol in the next decades control the evolution of surface ocean biogeochemistry in the second half of this century more than the specific pathways of atmospheric CO₂ concentrations.     

Source location of long period seismicity at Volcàn de Colima,México

This paper presents an analysis of seismicity associated with the volcanic activity of Volcàn de Colima (México) and recorded in the period November 2005–April 2006 during a field survey by the Istituto Nazionale di Geofisica e Vulcanologia (INGV)–Osservatorio Vesuviano, the Observatorio Vulcanologico de Colima of Colima University and the Instituto Andaluz de Geofisica, University of Granada. Three different types of volcanic earthquakes have been identified on the basis of their spectral properties: Type A (0.3–1 Hz), Type B (1–5 Hz) and Type C (3–4 Hz). Results of polarization analysis applied to Type A events show a predominance of radial motion, indicating that the wavefield comprises compressional waves (P) and shear waves polarized in the vertical plane (SV), while the signal always begins with a negative polarity. Type A, B and C earthquakes have been located using both a flat layered model and a 3D model including topography. Hypocentre distributions indicate that the source of Type A signals is very shallow and confined to a small volume lying about 1 km below the crater. In contrast, the source of Type B and C events is significantly deeper, with most hypocentres located in a volume of about 1 km³ centred at 2.5–3 km depth. A cluster analysis based on the cross-correlation among the waveforms of different events recorded at the same station was applied to Type A earthquakes. Only two clusters, which include only a small percentage of events were found, indicating that earthquake families were uncommon during the period of our survey.     

Insight into sodium silicate glass structural organization by multinuclear NMR combined with first-principles calculations

Short and medium range order of silica and sodium silicate glasses have been investigated from a quantitative analysis of ²⁹Si MAS NMR and ²³Na, ¹⁷O MQMAS NMR spectra. The method described enables the extraction of the underlying ¹⁷O NMR parameter distributions of bridging oxygens (BOs) and non-bridging oxygens (NBOs), and yields site populations which are confirmed by ²⁹Si NMR data. The extracted NMR parameter distributions and their variations with respect to the glass chemical composition can then be analyzed in terms of local structural features (bond angles and bond lengths, coordination numbers) with the help of molecular dynamics simulations combined with first-principles calculations of NMR parameters. Correlations of relevant structural parameters with ²³Na, ²⁹Si and ¹⁷O NMR interactions (isotropic chemical shift δ_iso, quadrupolar coupling constant C_Q and quadrupolar asymmetry parameter η_Q) are re-examined and their applicability is discussed. These data offer better insights into the structural organization of the glass network, including both chemical and topological disorder. Adding sodium to pure silica significantly diminishes the Si-O-Si bond angles and leads to a longer mean Si-O bond length with a slight decrease of the mean Na-O bond length. Moreover, the present data are in favor of a homogeneous distribution of Na around both oxygen species in the silicate network. Finally, our approach was found to be sensitive enough to investigate the effect of addition of a small quantity of molybdenum oxide (about 1 mol%) on the ¹⁷O MAS spectrum, opening new possibilities for investigating the Mo environment in silicate glasses.     

Performance of the L’Aquila (central Italy) gas distribution network in the 2009 (\mathrm{{M}}_\mathrm{{w}} 6.3) earthquake

Despite the seismic vulnerability of gas systems and the significance of the direct and indirect consequences that loss functionality might have on large communities, the analysis of the earthquake performance and of post-earthquake management for this kind of distribution networks appears under-represented in the international literature, with respect to other lifeline systems. To contribute on this matter, the study presented comprises an investigation of the impact of L’Aquila 2009 earthquake ( $\text{ M }_\mathrm{w}$ 6.3) on the performance of the local medium- and low-pressure gas distribution networks. The assessment of the physical impact of the earthquake to the buried components of network, namely pipes, valves, and demand nodes, was carried out when processing post-earthquake repair activity reports. Repair data, along with geometrical and constructive features, were collected in a geographic information system linked to the digitized maps of the network, and compared with the interpolated map of recorded transient ground motion, measured in terms of peak ground velocity (i.e., a $Shakemap^\mathrm{TM}$ ). The impact of permanent ground deformation was also investigated and found to be limited in the study area. The resulting observed repair rates (number of repairs per km), presented for different pipeline materials, were compared with repair ratio fragility functions available in literature, showing relatively agreement especially to those for steel pipes, likely also because of the uncertainties in the estimations. Finally, the management of the L’Aquila gas system in the emergency phase and the resilience (functionality recover versus time) of the system was discussed.     

Effects of nutrient availability and temperature on phytoplankton development: a case study from large lakes south of the Alps

This work investigated the combined effects of nutrient availability and temperature on phytoplankton in large and deep lakes south of the Alps (lakes Garda, Iseo, Como, Lugano and Maggiore). The more eutrophic basins (Lugano and Iseo) showed a higher presence of cyanobacteria, green algae (Chlorophyta and Charophyta) and dinoflagellates (Dinophyta). Besides these two water bodies, high biomasses of cyanobacteria were recorded also in the oligo-mesotrophic Lake Garda. The development of these algal groups during the growing season showed a strong dependence on the surface spring availability of SRP, which, in turn, was related to winter climatic oscillations, deep mixing dynamics, and trophic status. A specific analysis carried out by applying additive mixed modelling, generalized least squares and mixed modelling, allowed investigation of the direct, seasonal effects of water temperature variations and trophic status on different algal groups. The dominant cyanobacteria (Oscillatoriales) showed only a partial relationship with temperature, while Nostocales and Chroococcales, which did not appear to have a close relationship with the trophic status of the lakes, were characterised by abrupt increases during the warmer months. High positive relationships with temperature were found for a few other algal groups (e.g., Chlorophyta, Charophyta and Dinophyta). Overall, the results indicated a positive relationship between the seasonal development of the more abundant and eutrophic-sensitive algal groups and the concurrent effect of trophic status and water temperature. Nevertheless, it was stressed that specific differences could be interpreted taking into account the different autoecological characteristics and susceptibilities of different species and functional groups to other stressing factors favouring losses, including, e.g., vertical sinking and grazing.     

Heating-induced phase transformation in zeolite brewsterite: new 4- and 5-coordinated (Si,Al) sites

The dehydration-rehydration processes and phase transformations of brewsterite (space group P2₁/m, ideal formula (Sr,Ba)Al₂Si₆O₁₆·5H₂O) were studied by single crystal X-ray diffraction on two samples heated in an evacuated capillary for 24 h at 280°C and 330°C, respectively, and then cooled to room temperature. After the data collection, the capillary of the crystal heated at 280°C was broken, the sample was kept at room conditions for one month, and diffraction data were recollected. Brewsterite heated in vacuum at 280°C shows a strong decrease of the unit cell volume (about 10%) and the statistical breaking of the T1-O7-T2 bridge of the 4-ring of the 4²5⁴ PBU. T1 cation, in 31% of cases, migrates to a new tetrahedral site, which shares three vertices with the previously occupied one; the fourth vertex is on the mirror plane, and joins two adjacent layers. T2 cation, in 20% of cases, migrates to a new site, which is characterized by a 5-fold coordination. This coordination polyhedron shares three vertices with the previously occupied tetrahedron; the fourth vertex is on the mirror plane, and joins two adjacent layers; the fifth one is unshared. The formation of these new T-O-T bridges prevents the re-expansion and rehydration of the heated brewsterite; as a consequence, the crystal brought back to room conditions does not show any noticeable structural difference with respect to that heated at 280°C. The exchangeable cations, which occupy only one extraframework site in the untreated brewsterite, spread over several sites. The sample heated at 330°C shows a further decrease in the unit cell volume of about 2% with respect to the sample heated at 280°C, and an increase in the migration percentage of T1 and T2 cations to the new sites. Received: 11 November 1997 / Revised, accepted: 26 June 1998     

XAFS characterization of the structural site of Yb in synthetic pyrope and grossular garnets

The incorporation and site preference of minor amounts (about 1 wt%) of Yb³⁺ in synthetic pyrope (Mg₃Al₂Si₃O₁₂) and grossular (Ca₃Al₂Si₃O₁₂) garnet were studied by X-ray Absorption Fine-Structure (XAFS) Spectroscopy. The measurements, performed in the temperature range 77–343 K at both Yb L_I- and L_III-edges, demonstrate that Yb³⁺ enters the garnet structure and is located in the dodecahedral site in both samples. The coordination environment of Yb³⁺ in the two samples was compared to that of the X-site cation in end-member synthetic pyrope and grossular and in Yb₃Al₅O₁₂ as determined by single-crystal X-ray diffraction. The local geometry around Yb³⁺ is different from that of Mg and Ca in the bulk of the garnet, and also from that of Yb³⁺ in Yb₃Al₅O₁₂. Τhe XAFS results indicate that, (1) structural relaxation occurs around Yb³⁺ in the garnet structure; (2) the host garnet matrix exerts a major structural control on the incorporation of Yb³⁺, and (3) minor amounts of Yb³⁺ in garnet are located in structural sites and not in ill-defined defects. Received: 15 January 1998/ Revised, accepted: 21 July 1998     

The 'silent world' of Comet 15P/Finlay

Comet 15P/Finlay is unusual in that, contrary to ab initio expectations, it demonstrates no apparent linkage to any known meteor shower. Using data contained within the Electronic Atlas of Dynamical Evolutions of Short-Period Comets, we evaluate theoretical shower radiants for Comet 15P/Finlay, but find no evidence to link it to any meteoric anomalies in recorded antiquity. This result, however, must be tempered by the fact that any Comet 15P/Finlay-derived meteoroids will have a low, 16 km s⁻¹, encounter velocity with Earth's atmosphere. Typically, therefore, one would expect mostly faint meteors to be produced during an encounter with a Comet 15P/Finlay-derived meteoroid stream. We have conducted a D -criterion survey of meteoroid orbits derived from three southern hemisphere meteor radar surveys conducted during the 1960s, and again we find no evidence for any Comet 15P/Finlay-related activity. Numerical calculations following the orbital evolution of hypothetical meteoroids ejected from the comet, at each perihelion epoch since 1886, indicate that Jovian perturbations effectively 'drive' the meteoroids to orbits with nodal points beyond the Earth's orbit. The numerical calculations indicate that, even if Comet 15P/Finlay had been a copious emitter of meteoroids during the past 100 years, virtually none of them would have evolved into orbits capable of being sampled by the Earth. There are good observational data, however, to suggest that Comet 15P/Finlay is becoming a transitional comet–asteroid object, and that it has probably not been an efficient producer of meteoroids during the past several hundreds of years.     

Evaluating asbestos fibre concentration in metaophiolites: a case study from the Voltri Massif and Sestri–Voltaggio Zone (Liguria, NW Italy)

This work is part of the project study for a road tunnel bypassing the town of Genova and was aimed at evaluating the amount of asbestos fibres in the metaophiolites belonging to the Voltri Group and the Sestri–Voltaggio Zone (Liguria, Northern Italy). The 85 studied rock samples (mainly mafic and ultramafic rocks) derive from exposed outcrops and prospecting boreholes. The study of field relations and petrographic/microtextural investigations under the optical microscope allowed for the identification and characterisation of asbestos-bearing settings and lithotypes. Mineralogy and concentration of asbestos fibres in powdered specimens were determined by means of a scanning electron microscope equipped with an energy-dispersive X-ray spectroscopy device. These investigations were combined with petrography on thin-section, X-ray diffraction analysis and phase contrast optical microscopy on rock powders. Mafic and ultramafic rocks commonly contain asbestos in concentrations below 1,000 mg/kg (considered as the contamination threshold under Italian law). However, the fibre concentration rises abruptly within localised zones, where the metaophiolite sequences were involved into late ductile to brittle tectono-metamorphic events. Two groups of asbestos-bearing settings have been so far identified in the area: (a) fracture networks within serpentinites (dominated by fibrous chrysotile), and (b) boudins of chlorite-tremolite schists, likely deriving from dynamic recrystallisation of mafic rocks under greenschist facies conditions (dominated by fibrous amphibole). Even considering the low volumetric incidence of these settings (metres to few tens of metres), their high asbestos content locally controls the total fibre amount in the excavation products, thus requiring special prevention measures during excavation, management and final storage of the contaminated debris.     

A systematic analysis of the <Emphasis Type="Italic">XMM-Newton</Emphasis> background: II. Properties of the in-Field-Of-View excess component

We present an accurate characterization of the particle background behaviour on XMM-Newton based on the entire EPIC archive. This corresponds to the largest EPIC data set ever examined. Our results have been obtained thanks to the collaboration between the FP7 European program EXTraS and the ESA R&D ATHENA activity AREMBES. We used as a diagnostic an improved version of the diagnostic which compares the data collected in unexposed region of the detector with the region of the field of view in the EPIC-MOS. We will show that the in Field-of-View excess background is made up of two different components, one associated to flares produced by soft protons and the other one to a low-intensity background. Its origin needs to be further investigated.