Geochemical studies in the drainage basin of the Rio Vouga,Portugal. IV. Impact of land use on the hydrogeochemistry of natural waters in the Vouzela region

A hydrogeochemical study of the impact of land use on the composition of natural waters in the Vouzela region in northern Portugal was carried out during the summer of 1983. Water samples were collected from spring and major streams in the area and analyzed for major constituents and some trace elements. Analysis of variance and subsequent pairwise contrast tests demonstrated that waters from agricultural areas are significantly enriched in constiluents such as Na, K, Ca, Mg, Sr, Cl, SO₄, and NO₃. High concentrations of these ions in agricultural areas are the result of both the application of fertilizers and enhanced evaporation by the intensive irrigation of agricultural lands. Constitutents such as H₄SiO₄, HCO₃, F, and probably Li, which are typically related to mineral weathering, were not affected by land use. In waters from forested areas the concentration of most constituents was about 20% higher than in waters from uncultivated areas with mainly a grass cover. This reflects the difference in the evapotranspiration of these two vegetation types. The chemistry of the Rio Zela clearly reflects differences in land use in the Rio Zela valley.     

Thermodynamics of plagioclase II: Temperature evolution of the spontaneous strain at the I\bar 1 \leftrightarrow P\bar 1 phase transition in anorthite

The temperature dependence of the lattice parameters of pure anorthite with high Al/Si order reveals the predicted tricritical behaviour of the \(I\bar 1 \leftrightarrow P\bar 1\) phase transition at T _c ^* =510 K. The spontaneous strain couples to the order parameter Q° as x _i∝S _xQ ⁱ Q°² with S _xQ ¹ =4.166×10^?3, S _xQ ² =0.771×10^?3, S _xQ ³ =?7.223×10^?3 for the diagonal elements. The temperature dependence of Q° is $$Q^{\text{o}} = \left( {1 - \frac{T}{{510}}} \right)^\beta ,{\text{ }}\beta = \tfrac{{\text{1}}}{{\text{4}}}$$ A strong dependence of T _c ^* , S _xQ ⁱ and β is predicted for Al/Si disordered anorthite.     

Field observations of stratified atmospheric flow above an obstacle

In a study using the plume from the Four Corners power plant, near Farmington, N.M., lee waves were observed during times when the plume flowed across the Hogback. Wavelengths were typically about 1.2 km; wave amplitudes were more variable, ranging from 20 to 100 m. The observed amplitudes imply an obstacle that is broader and shallower than is actually the case. This is in agreement with laboratory studies that show the existence of regions of complex flow both upstream and downstream from an obstacle, which have the effect of broadening the region over which laminar flow occurs. Visual observation, measurement of the plume cross-sectional area both upstream and downstream from the Hogback, and measurement of plume aerosol concentrations show that turbulent and eddy flow over and downwind from the Hogback increase the rate of mixing of the plume with the surrounding atmosphere. This in turn increases the rate at which plume components come into contact with the ground.     

Strontium-calcium ratios in Cenozoic planktonic foraminifera

The $\text{Sr}\text{Ca}$ ratio and other parameters have been measured in fossil planktonic foraminifera from the Atlantic and Pacific Ocean basins in order to evaluate the $\text{Sr}\text{Ca}$ ratio of seawater during the last 75 million years. Results on well-preserved samples indicate that the ratio has increased to its present value by 10–15% during the Cenozoic, and that minima occurred between 55-45 Ma and 10-5 Ma, when the ratio was 15–25% less than at present. The long-term increase may reflect either decreasing deposition of aragonite with a high $\text{Sr}\text{Ca}$ ratio in shallow seas, or decreasing seafloor spreading rates and consequently decreasing hydrothermal supply of Ca during the Cenozoic. Other geologic evidence suggests that the Eocene minimum (near 50 Ma) may have resulted from increased aragonite sedimentation, while the Late Miocene minimum (between 10-5 Ma) may have been caused by an increased rate of seawater-basalt exchange when seafloor spreading rates increased on the East Pacific Rise near 10 Ma.     

Vertical sedimentation units in a barrier island washover fan

Overwash is a major component of a barrier island's response to high energy conditions. Examination of the 19-20 March, 1975, storm deposits at Assateague Island, showed that an overwash sequence could be divided into sedimentation units. Interpretation depends upon defining textural and mineralogical combinations that can be logically ordered as a vertical sequence. If the sequence is depositional and formed from a single material, normal grading usually results; if polymineralogical and erosionally truncated, inverse grading with a top layer of heavy minerals can be formed via an in situ sorting process dependent on disturbance depth and overwash influence.     

A generalised one-dimensional kinematic catchment model

A numerical model has been developed for the solution of the kinematic wave equation for a one-dimensional catchment, using the Lax-Wendroff technique. The model has been verified by comparing its solutions with some analytical solutions already available. Certain catchment parameters have been identified and the model applied with promising results to two actual catchments to ascertain their values.     

Dynamic model of flotation cell banks — circuit analysis

While all mineral industry flotation circuits are stable, they are sensitive to low-frequency perturbations in the feedrate. In both countercurrent and cocurrent circuits, the lead cell is more sensitive to feed variations. The frequency response predicts the amount of extra cell capacity needed to handle the maximum feed due to a sinusoidal forcing function. Feedback loops are more significant than sump delays. The countercurrent $\text{4 × 4}$ circuit floating quartz, with a 200-sec retention time, requires 75 minutes for the concentration of quartz in the input to the first cell to reach 95% of its steady-state value. Countercurrent circuits were found superior to cocurrent circuits in all respects.     

内蒙古苏尼特左旗南两类花岗岩同位素年代学及其构造意义

内蒙古北部索伦缝合带（索伦-苏尼特左旗-锡林浩特）被多数中外学者认为是西伯利亚板块南缘和华北板块北缘的最终缝合带,本文选择该缝合带上苏尼特左旗南两类花岗岩-与俯冲有关和与碰撞有关的岩浆岩（分别叫弧岩浆岩和碰撞岗岩）进行同位素年代学研究,结果表明：（1）弧岩浆活动有两期,分别约为490Ma和310Ma(锆石U-Pb,SHRIMP);碰撞花岗岩的侵位年代在230-250Ma(Rb-Sr全岩和锆石U-Pb);（2）根据本文新的年代学数据,索伦缝合带的最终缝合时间可能是在230-310Ma,这显然不同于国内多数学者坚持的“晚泥盆世碰撞”模式;而Sengor等推测的“晚二又开展碰撞”模式与本文数据一致。