Experimental study of the dehydration of 10-Å phase,with implications for its H<Subscript>2</Subscript>O content and stability in subducted lithosphere

The 10-Å phase (TAP) is a hydrous magnesium silicate that forms from the reaction of talc with H₂O at high pressures. Its high-pressure, low-temperature stability means that it could be a storage site for H₂O in subduction zones. We have determined the position of the TAP dehydration reaction, TAP = enstatite + coesite + H₂O, in phase-equilibrium experiments from 5.0 to 7.1 GPa. Because previous studies had suggested that the composition of TAP is a function of synthesis duration, we used a TAP sample that was synthesised for 392 h. Over the pressure interval of our experiments, the dehydration reaction is isothermal, occurring at a temperature of ~690°C. It is coincident, within experimental uncertainty, with the position of the dehydration reaction of TAP synthesised in short experiments (up to 46 h). Above 7.5 GPa, TAP breaks down to enstatite + stishovite + H₂O. This reaction has a negative dP/dT and terminates at an invariant point involving the 3.65-Å phase at ~9.5 GPa, 500°C. The zero volume change implied by the isothermal reaction TAP = enstatite + coesite + H₂O was used to calculate the interlayer H₂O content of TAP along the reaction. A best-fit H₂O content of 1 H₂O pfu was obtained. This H₂O content is independent of TAP synthesis conditions, suggesting that variations in previously measured H₂O contents of TAP occur during quenching and decompression of the samples. The stability of TAP in the Earth is probably limited to cold subduction zones, but in these, it could persist to 300 km depth.     

The response of phytoplankton to iron enrichment in Sub-Antarctic HNLCLSi waters: Results from the SAGE experiment

Areas of high nutrients and low chlorophyll a comprise nearly a third of the world’s oceans, including the equatorial Pacific, the Southern Ocean and the Sub-Arctic Pacific. The SOLAS Sea-Air Gas Exchange (SAGE) experiment was conducted in late summer, 2004, off the east coast of the South Island of New Zealand. The objective was to assess the response of phytoplankton in waters with low iron and silicic acid concentrations to iron enrichment. We monitored the quantum yield of photochemistry (F_v/F_m) with pulse amplitude modulated fluorometry, chlorophyll a, primary productivity, and taxonomic composition. Measurements of F_v/F_m indicated that the phytoplankton within the amended patch were relieved from iron stress (F_v/F_m approached 0.65). Although there was no significant difference between IN and OUT stations at points during the experiment, the eventual enhancement in chlorophyll a and primary productivity was twofold by the end of the 15-day patch occupation. However, no change in particulate carbon or nitrogen pools was detected. Enhancement in primary productivity and chlorophyll a were approximately equal for all phytoplankton size classes, resulting in a stable phytoplankton size distribution. Initial seed stocks of diatoms were extremely low, <1% of the assemblage based on HPLC pigment analysis, and did not respond to iron enrichment. The most dominant groups before and after iron enrichment were type 8 haptophytes and prasinophytes that were associated with ∼75% of chlorophyll a. Twofold enhancement of biomass estimated by flow cytometry was detected only in eukaryotic picoplankton, likely prasinophytes, type 8 haptophytes and/or pelagophytes. These results suggest that factors other than iron, such as silicic acid, light or physical disturbance limited the phytoplankton assemblage during the SAGE experiment. Furthermore, these results suggest that additional iron supply to the Sub-Antarctic under similar seasonal conditions and seed stock will most likely favor phytoplankton <2 ??m. This implies that any iron-mediated gain of fixed carbon will most likely be remineralized in shallow water rather than sink and be sequestered in the deep ocean.     

Fishing dynamics associated with periodically harvested marine closures

Periodically-harvested fisheries closures are emerging as a socially acceptable and locally implementable way to balance concerns about conserving ecosystem function and sustaining livelihoods. Across the Indo-Pacific periodically-harvested closures are commonly employed, yet their contribution towards more sustainable fisheries remains largely untested in the social and ecological context of tropical small-scale fisheries. To address this, we use an interdisciplinary approach to examine harvesting dynamics that would affect sustainability, namely, fishing effort, yield, gear and method use, periodicity of harvesting, controls placed on harvesting and resource owners’ decisions to open and close four fishing grounds in Solomon Islands. We compare these fishing patterns with those on surrounding, continuously open fishing grounds. Our study shows that total effort and total catch from periodically-harvested reef closures are low to moderate compared to reefs open to continuous fishing. When periodically-harvested closures were opened, effort in the closures was relatively intense, however, in most cases yield did not exceed annual benchmarks of sustainability described by previous studies. In some cases, harvesting during openings was restricted to a single taxon and single fishing gear and method, while in others there was unrestricted multi-species and multi-method harvesting. The duration and frequency of openings were highly variable, with open periods ranging from a single night to one month in duration, and occurring between one and 15 times per year. Fishing during openings was permitted for entire fishing communities in some cases, and only for specific rights-holding families in others. Decisions to open periodically-harvested closures tended to be based on immediate social or economic needs, and the openings provided a small boost to fish catch landed in communities. While periodically-harvested closures may alleviate fishing pressure in a small area of fishing grounds by reducing the opportunity to fish, openings of long duration or high frequency, combined with heavy or destructive exploitation, may lead to unsustainable harvesting within the area.     

Spatial variation of erosion in a small,glaciated basin in the Teton Range,Wyoming, based on detrital apatite (U‐Th)/He thermochronology

Evolution of mountain landscapes is controlled by dynamic interactions between erosional processes that vary in efficiency over altitudinal domains. Evaluation of spatial and temporal variations of individual erosion processes can augment our understanding of factors controlling relief and geomorphic development of alpine settings. This study tests the application of detrital apatite (U‐Th)/He thermochronology (AHe) to evaluate variable erosion in small, geologically complex catchments. Detrital grains from glacial and fluvial sediment in a single basin were dated and compared with a bedrock derived age‐elevation relationship to estimate spatial variation in erosion over different climate conditions in the Teton Range, Wyoming. Controls and pitfalls related to apatite quality and yield were fully evaluated to assess this technique. Probability density functions comparing detrital age distributions identify variations in erosional patterns between glacial and fluvial systems and provide insight into how glacial, fluvial, and hillslope processes interact. Similar age distributions representing erosion patterns during glacial and interglacial times suggest the basin may be approaching steady‐state. This also implies that glaciers are limited and no longer act as buzzsaws or produce relief. However, subtle differences in erosional efficiency do exist. The high frequency of apatite cooling ages from high altitudes represents either rapid denudation of peaks and ridges by mass wasting or an artifact of sample quality. A gap in detrital ages near the mean age, or mid‐altitude, indicates the fluvial system is presently transport limited by overwhelming talus deposits. This study confirms that sediment sources can be traced in small basins with detrital AHe dating. It also demonstrates that careful consideration of mineral yield and quality is required, and uniform erosion assumptions needed to extract basin thermal history from detrital ages are not always valid.     

Improving multimodel weather forecast of monsoon rain over China using FSU superensemble

In this paper we present the current capabilities for numerical weather prediction of precipitation over China using a suite of ten multimodels and our superensemble based forecasts. Our suite of models includes the operational suite selected by NCARs TIGGE archives for the THORPEX Program. These are: ECMWF, UKMO, JMA, NCEP, CMA, CMC, BOM, MF, KMA and the CPTEC models. The superensemble strategy includes a training and a forecasts phase, for these the periods chosen for this study include the months February through September for the years 2007 and 2008. This paper addresses precipitation forecasts for the medium range i.e. Days 1 to 3 and extending out to Day 10 of forecasts using this suite of global models. For training and forecasts validations we have made use of an advanced TRMM satellite based rainfall product. We make use of standard metrics for forecast validations that include the RMS errors, spatial correlations and the equitable threat scores. The results of skill forecasts of precipitation clearly demonstrate that it is possible to obtain higher skills for precipitation forecasts for Days 1 through 3 of forecasts from the use of the multimodel superensemble as compared to the best model of this suite. Between Days 4 to 10 it is possible to have very high skills from the multimodel superensemble for the RMS error of precipitation. Those skills are shown for a global belt and especially over China. Phenomenologically this product was also found very useful for precipitation forecasts for the Onset of the South China Sea monsoon, the life cycle of the mei-yu rains and post typhoon landfall heavy rains and flood events. The higher skills of the multimodel superensemble make it a very useful product for such real time events.     

Assessment and management of the trochus fishery at West Nggela, Solomon Islands: An interdisciplinary approach

A proper understanding of the management status of small-scale subsistence and artisanal fisheries requires not only detailed sociocultural study, but comprehensive analysis of the state of the fished population(s), using rigorous stock assessment and other fisheries biology tools. In this article I describe several approaches taken to assess the artisanal trochus fishery at West Nggela. This includes stock density and other data, that demonstrate many reefs are overfished. I discuss the social and economic factors influencing the performance of the fishery. The importance of an understanding of property tenure is dealt with in some detail. An analysis of the various categories of fishers’ ecological knowledge about trochus is also presented, and discussed with respect to the categories of biological and ecological information considered by most fisheries biologists as essential to the assessment and management of a fishery.