Trend analysis of nutrient loadings in a large prairie catchment

Nutrient loadings in many river catchments continue to increase due to rapid expansion of agriculture, urban and industrial development, and population growth. Nutrient enrichment of water bodies has intensified eutrophication which degrades water quality and ecosystem health. In this study, we carried out a trend analysis of total phosphorus and total nitrogen loads in the South Saskatchewan River (SSR) catchment using a novel approach to analyse nutrient time series. Seasonal analysis of trends at each of the water quality stations was performed to determine the relationships between annual flow regimes and nutrient loads in the catchment, in particular, the influence of the high spring runoff on nutrient export. Decadal analysis was also performed to determine the long-term relationships of nutrients with anthropogenic changes in the catchment. Although it was found that seasonal and historical variability of nutrient load trends is mainly determined by streamflow regime changes, there is evidence that increases in nitrogen concentration can also be attributed to anthropogenic changes.     

粤港澳大湾区发展的理论框架与发展战略探究

粤港澳大湾区是在“一带一路”倡议下,由珠三角经济圈的强化合作而产生的新地理概念。作为新兴的全球化港湾,粤港澳大湾区如何突破新自由主义框架理论,探索出符合社会主义市场经济体制的发展路径,是当前决策者和规划者需要思考的重要问题。本文简要梳理了现有的城市群、区域增长极理论,新经济地理集群理论,全球产业链网络理论并结合大湾区现状优势,对湾区发展战略定位与发展路径进行探究,认为可通过粤港澳三方通力合作,创造一个内生型的经济与产业本土增长模式为主要方向。具体表现为：首先,要以先进制造业为立足点、实现自我创新的产业升级,形成完善的制造业产业链,并成为全球生产网络的重要节点与区域性枢纽;其次,大湾区还应利用自身的科研与教育、金融与创新资源优势,推进“一国两制三关税区”、尤其是与香港在大湾区建设中的全方位参与联动,完善产权制度,加强合规和规则经济的市场经济体系建设,将大湾区打造为中国的科创中心及全球性金融中心。     

The influence of coupled physical swelling and chemical reactions on deformable geomaterials

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.     

Le rayonnement x du soleil lors de l'éclipsé du 20 Mai 1966

Résumé L'éclipsé solaire du 20 mai 1966 a été observée par le satellite de l'U.S. Naval Research Laboratory 1965–93 A muni de photomètres sensibles aux rayonnements X et ultra-violet. Trois sources d'émission X ont été occultées sur le disque. On a ainsi pu mesurer leur flux et leurs dimensions et comparer les résultats aux observations effectuées en radioastronomie.     

Biostratigraphic and aminostratigraphic constraints on the age of the Middle Pleistocene glacial succession in north Norfolk,UK

Considerable debate surrounds the age of the Middle Pleistocene glacial succession in East Anglia following some recent stratigraphical reinterpretations. Resolution of the stratigraphy here is important since it not only concerns the glacial history of the region but also has a bearing on our understanding of the earliest human occupation of north‐western Europe. The orthodox consensus that all the tills were emplaced during the Anglian (Marine Isotope Stage (MIS) 12) has recently been challenged by a view assigning each major till to a different glacial stage, before, during and after MIS 12. Between Trimingham and Sidestrand on the north Norfolk coast, datable organic sediments occur immediately below and above the glacial succession. The oldest glacial deposit (Happisburgh Till) directly overlies the ‘Sidestrand Unio‐bed’, here defined as the Sidestrand Hall Member of the Cromer Forest‐bed Formation. Dating of these sediments therefore has a bearing on the maximum age of the glacial sequence. This paper reviews the palaeobotany and describes the faunal assemblages recovered from the Sidestrand Unio‐bed, which accumulated in a fluvial environment in a fully temperate climate with regional deciduous woodland. There are indications from the ostracods for weakly brackish conditions. Significant differences are apparent between the Sidestrand assemblages and those from West Runton, the type site of the Cromerian Stage. These differences do not result from contrasting facies or taphonomy but reflect warmer palaeotemperatures at Sidestrand and a much younger age. This conclusion is suggested by the higher proportion of thermophiles at Sidestrand and the occurrence of a water vole with unrooted molars (Arvicola) rather than its ancestor Mimomys savini with rooted molars. Amino acid racemisation data also indicate that Sidestrand is significantly younger than West Runton. These data further highlight the stratigraphical complexity of the ‘Cromerian Complex’ and support the conventional view that the Happisburgh Till was emplaced during the Anglian rather than the recently advanced view that it dates from MIS 16. Moreover, new evidence from the Trimingham lake bed (Sidestrand Cliff Formation) above the youngest glacial outwash sediments (Briton's Lane Formation) indicates that they also accumulated during a Middle Pleistocene interglacial – probably MIS 11. All of this evidence is consistent with a short chronology placing the glacial deposits within MIS 12, rather than invoking multiple episodes of glaciation envisaged in the ‘new glacial stratigraphy’ during MIS 16, 12, 10 and 6. Copyright © 2009 John Wiley & Sons, Ltd.     

Environmental correlates of large-scale spatial variation in the δ13C of marine animals

Carbon stable isotopes can be used to trace the sources of energy supporting food chains and to estimate the contribution of different sources to a consumer's diet. However, the δ¹³C signature of a consumer is not sufficient to infer source without an appropriate isotopic baseline, because there is no way to determine if differences in consumer δ¹³C reflect source changes or baseline variation. Describing isotopic baselines is a considerable challenge when applying stable isotope techniques at large spatial scales and/or to interconnected food chains in open marine environments. One approach is to use filter-feeding consumers to integrate the high frequency and small-scale variation in the isotopic signature of phytoplankton and provide a surrogate baseline, but it can be difficult to sample a single consumer species at large spatial scales owing to rarity and/or discontinuous distribution. Here, we use the isotopic signature of a widely distributed filter-feeder (the queen scallop Aequipecten opercularis) in the north-eastern Atlantic to develop a model linking base δ¹³C to environmental variables. Remarkably, a single variable model based on bottom temperature has good predictive power and predicts scallop δ¹³C with mean error of only 0.6‰ (3%). When the model was used to predict an isotopic baseline in parts of the overall study region where scallop were not consistently sampled, the model accounted for 76% and 79% of the large-scale spatial variability (10¹–10⁴ km) of the δ¹³C of two fish species (dab Limanda limanda and whiting Merlangus merlangius) and 44% of the δ¹³C variability in a mixed fish community. The results show that source studies would be significantly biased if a single baseline were applied to food webs at larger scales. Further, when baseline δ¹³C cannot be directly measured, a calculated baseline value can eliminate a large proportion of the unexplained variation in δ¹³C at higher trophic levels.     

Annual cycles in the interstellar scintillation time-scales of PKS B1519–273 and PKS B1622–253

We have used the University of Tasmania's 30-m radio telescope at Ceduna in South Australia to regularly monitor the flux density of a number of southern blazars. We report the detection of an annual cycle in the variability time-scale of the centimetre radio emission of PKS B1622−253. Observations of PKS B1519−273 over a period of nearly 2 yr confirm the presence of an annual cycle in the variability time-scale in that source. These observations prove that interstellar scintillation is the principal cause of inter-day variability at radio wavelengths in these sources. The best-fitting annual cycle model for both sources implies a high degree of anisotropy in the scattering screen and that it has a large velocity offset with respect to the local standard of rest. This is consistent with a greater screen distance for these 'slow' intra-day variability (IDV) sources than for rapid scintillators such as PKS B0405−385 or J1819+3845.     

In situ measurement of Re-Os isotopes in mantle sulfides by laser ablation multicollector-inductively coupled plasma mass spectrometry: analytical methods and preliminary results

A method has been developed for the in situ determination of Re-Os isotopes in single grains of sulfides in mantle-derived peridotites using a laser ablation microprobe attached to a multicollector-induced coupled plasma mass spectrometer (MC-ICPMS). High-precision Os isotope analysis by MC-ICPMS is demonstrated by the measurement of interlaboratory Os standards. Evaluation of mass bias correction procedures shows that the exponential law provides the best fit to the Os isotope data and that the ratio of the mass fractionation coefficients for Re and Os remains constant for the range of typical instrument operating conditions. This relationship enables the accurate and precise correction of the isobaric interference of ¹⁸⁷Re on ¹⁸⁷Os for ¹⁸⁷Re/¹⁸⁸Os values up to 1.6.Results are presented for single sulfide inclusions in olivine macrocryts from kimberlites in the Siberian and Slave Cratons, and sulfides enclosed in silicates and interstitial to silicates in peridotite xenoliths from the Slave Craton and Massif Central, France. Enclosed sulfides larger than 50 μm in diameter and with Os contents ≥40 ppm give ¹⁸⁷Os/¹⁸⁸Os ratios with a precision of 0.1% (2 SE), which is equivalent to N-TIMS whole-rock data. Interstitial sulfides typically have lower Os (10 to 30 ppm) and give analyses with lower precision (∼1 to 2%) but still provide valuable information on the movement of Os within the lithosphere. The sulfide inclusions in silicates preserve significantly less radiogenic Os isotopic compositions than interstitial sulfides and accordingly produce significantly older and more realistic Re-Os age information. Whole-rock Os isotope compositions reflect the proportions of different generations of enclosed and interstitial sulfides; this calls into question the significance of many published “depletion ages.”