Short-term changes in C and N distribution in soil particle size fractions induced by agricultural practices in a cultivated volcanic soil from Mexico

The purpose of this study was to assess the effect of agricultural practices on the characteristics of soil organic carbon (SOC). The study area is located in the Central Volcanic Belt (Michoacán) in Mexico. The soil is an Acrisol, acidic and rich in clays and sesquioxides. Experimental plots were treated with four different agronomic management systems between 2002 and 2003: traditional, improved traditional, organic and fallow. Each treatment was replicated twice. Samples were taken at depths of 0–10 and 10–20 cm and were subjected to a physical fractionation process by way of particle size. SOC was fractionated into fulvic acids, humic acids and humin. After two years of cultivation, the SOC content increased significantly with the organic management (2.2 mg g⁻¹ at 0–10 cm and 5.8 mg g⁻¹ at 10–20 cm). The C content of the soil fine particle fraction increased with the traditional and organic managements. The organic C and N contents of the silt + clay particle-size fraction were mainly concentrated as humin, indicating that this SOM should be stable and have a low risk of mineralization. The humin C content only decreased significantly under the traditional and fallow treatments. The N content of the humin fraction decreased significantly under the traditional management system (from 69% to 54%), indicating the low sustainability of this soil management. The C/N ratio of the soil increased significantly under all treatments, but mainly under the traditional and organic treatments (from 12.1 and 12.8 to 13.7 and 14.0, respectively). This indicates a decrease in humus quality. In addition, the C/N of the humin increased significantly (from 13.3 and 12.7 to 19.2 and 16.0, respectively).     

New Activity of Chiron: Results from 5 Years of Photometric Monitoring

The results of photometric observations of Centaur object Chiron carried out at the Observatório do Pico dos Dias (OPD, Brazil), the Estación Astrof?́sica de Bosque Alegre (EABA, Argentina), and Complejo Astronómico El Leoncito (CASLEO, Argentina) from 1997 to 2001 are presented here. The analysis of the photometric data shows that the brightness of Chiron reached a minimum value in 1999 and began increasing again in 2000. The absolute magnitude, H_V, varied from 7.26 in June 1999 to 5.78 in April 2001. The data tend to indicate that Chiron is starting a new outburst of activity which is compatible with a sporadic cometary behavior not related to heliocentric distance.     

Evaluation of ecotoxicological effects of endocrine disrupters during a four-year survey of the Mediterranean population of swordfish (Xiphias gladius)

In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1–22, Cd 1–28 and Pb 0–1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.     

Unveiling the thermal and magnetic map of neutron star surfaces though their X-ray emission: method and light-curve analysis

Recent Chandra and XMM–Newton observations of a number of X-ray 'dim' pulsating neutron stars have revealed quite unexpected features in the emission from these sources. Their soft thermal spectrum, believed to originate directly from the star surface, shows evidence for a phase-varying absorption line at some hundred eVs. The pulse modulation is relatively large (pulsed fractions in the range ∼12–35 per cent), the pulse shape is often non-sinusoidal, and the hard X-ray colour appears to be anticorrelated in phase with the total emission. Moreover, the prototype of this class, RX J0720.4−3125, has been found to undergo rather sensible changes in both its spectral and timing properties over a time-scale of a few years. All these new findings seem difficult to reconcile with the standard picture of a cooling neutron star endowed with a purely dipolar magnetic field, at least if surface emission is produced in an atmosphere on top of the crust. In this paper we explore how a dipolar+quadrupolar star-centred field influences the properties of the observed light curves. The phase-resolved spectrum has been evaluated accounting for both radiative transfer in a magnetized atmosphere and general relativistic ray-bending. We computed over 78 000 light curves, varying the quadrupolar components and the viewing geometry. A comparison of the data with our model indicates that higher-order multipoles are required to reproduce the observations.     

High‐resolution synchrotron X‐ray fluorescence investigation of calcite coralloid speleothems: Elemental incorporation and their potential as environmental archives

Synchrotron high‐resolution and micro‐X‐ray fluorescence elemental mapping of two coeval coralloid speleothems from Lamalunga Cave (Italy) are complemented with petrographic, morphological and microstratigraphic studies. The importance of these speleothems relies on their direct and indirect association with a complete Neanderthal skeleton (‘Altamura Man’) found inside the cave. The coralloids grew discontinuously between 64·6 ka and the Holocene and reveal exceptionally high concentrations of Mg, Sr and Si, particularly on convex surfaces, where evaporation is more intense. The incorporation of trace elements depends on several factors including location, shape and geometrical evolution during their growth, as well as climate and environmental parameters. This resulted in calcite precipitation with Sr compositions from 100 to 1200 ppm and an average concentration of 7000 ppm Mg. An unusually high Si content (up to 16%) is possibly derived from volcanic ash transported as particulate and in solution inside the cave. The most common fabrics observed consist of non‐fluorescent elongated columnar calcite forming clean isopachous bands and fluorescent fibre‐like crystals associated with laminated, lenticular bands high in Sr, Mg and Si. Variability in Sr, Mg and Si concentrations appears to induce fabric changes in the coralloids. Elongation and lattice distortion of the crystals was found to coincide with high Mg concentrations. The transition from compact elongated to open to fibre‐like, is here interpreted as due to high concentrations of Si and Sr, which are preferentially incorporated in the speleothem at crystal boundaries and intra‐laminae. It is here inferred that coralloid fabric changes and their elemental content potentially record local rainfall variations through time, with the clean compact calcite marking high infiltration and open fibre‐like and micrite fabrics recording dry periods.     

Evaluation of ecotoxicological effects of endocrine disrupters during a four-year survey of the Mediterranean population of swordfish (Xiphias gladius)

In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1-22, Cd 1-28 and Pb 0-1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.     

Distribution and geological control of mud volcanoes and other fluid/free gas seepage features in the Mediterranean Sea and nearby Gulf of Cadiz

Existing knowledge on the distribution of mud volcanoes (MVs) and other significant fluid/free gas-venting features (mud cones, mud pies, mud-brine pools, mud carbonate cones, gas chimneys and, in some cases, pockmark fields) discovered on the seafloor of the Mediterranean Sea and in the nearby Gulf of Cadiz has been compiled using regional geophysical information (including multibeam coverage of most deepwater areas). The resulting dataset comprises both features proven from geological sampling, or in situ observations, and many previously unrecognized MVs inferred from geophysical evidence. The synthesis reveals that MVs clearly have non-random distributions that correspond to two main geodynamic settings: (1) the vast majority occur along the various tectono-sedimentary accretionary wedges of the Africa-Eurasia subduction zone, particularly in the central and eastern Mediterranean basins (external Calabrian Arc, Mediterranean Ridge, Florence Rise) but also along its westernmost boundary in the Gulf of Cadiz; (2) other MVs characterize thick depocentres along parts of the Mesozoic passive continental margins that border Africa from eastern Tunisia to the Levantine coasts, particularly off Egypt and, locally, within some areas of the western Mediterranean back-arc basins. Meaningfully accounting for MV distribution necessitates evidence of overpressured fluids and mud-rich layers. In addition, cross-correlations between MVs and other GIS-based data, such as maps of the Messinian evaporite basins and/or active (or recently active) tectonic trends, stress the importance of assessing geological control in terms of the presence, or not, of thick seals and potential conduits. It is contended that new MV discoveries may be expected in the study region, particularly along the southern Ionian Sea continental margins.     

The influence of ENSO and PDO on tropical Andean glaciers and their impact on the hydrology of the Amazon Basin

Recent decades, particularly since the late 1970s, have witnessed a rapid retreat of glaciers in the tropical Andes. We compiled the changes in glacier surfaces along the eastern cordilleras of the tropical Andes of Peru and Bolivia since the early 1980s from the literature. Water levels from two Brazilian river basins in the Amazon basin (one (Madeira River) glacially fed by meltwater from the Andes and the other (Envira River) non‐glacially fed), were analysed for a 30‐year period between 1985?2014. Furthermore, precipitation data near these two basins were also analysed in order to understand the differential contributions of glacier melting and rainfall. Variations in the water levels from the glacially fed Madeira River showed that some years were associated with higher water levels even when the precipitation remained low during the corresponding season (May‐October). This observation was common when El Niño events occurred during the positive phase of Pacific Decadal Oscillation (PDO). Water levels in glacier‐fed Madeira River were slightly higher during the periods where El Niño and warm PDO co‐occurred. On the other hand, water levels in the Envira River were precipitation dependent; water levels were higher when the rainfall was high.