Biosensors for marine pollution research,monitoring and control

Measurement of ecological, climatic and anthropogenic changes underpins the formulation of effective management strategies for sustainable use and protection of the marine environment. Sensors are traditionally used in marine studies to determine physical parameters, but there is increasing demand for real-time information about chemical and biological parameters. These parameters are currently measured in samples collected at sea and subsequently analysed in the laboratory. Biosensors fuse the exquisite sensitivity and specificity of living systems with the processing power of microelectronics to deliver simple, inexpensive measurement systems for use in the field or deployment in situ. While their potential for use in the marine environment is enormous, much published work to date has focussed on applications in freshwater and wastewater. Marine applications pose a substantial challenge in the robustness required for remote application, but recent developments in portable medical devices and receptor design suggest that these demands can now be realistically tackled.     

Presolar nanodiamonds: faster, cleaner, and limits on platinum-HL

We have developed a procedure that allows extraction of clean nanodiamond samples from primitive meteorites for isotopic analyses of trace elements on a timescale of just a week. This procedure includes microwave digestion and optimization of existing isolation techniques for further purification. Abundances of trace elements that are difficult to dissolve using standard procedures (e.g., Ir) are lower in the diamond residues prepared using the new technique. Accelerator mass spectrometry (AMS) was explored as a means for isotopic measurements. Results obtained on diamond fractions from Allende and Murchison show the need for suitable matrix-adjusted standards to correct for fractionation effects; nevertheless they allow putting an upper limit on the abundance of ¹⁹⁸Pt-H in nanodiamonds of ∼1 × 10¹⁴ atoms/g. This limit is on the order of what can be expected from predictions of competing nucleosynthesis models and extrapolation of the apparently mass dependent abundance trend of the associated noble gases.Unfortunately, and unexpectedly, presolar silicon carbide is almost quantitatively dissolved during microwave digestion with HCl/HF/HNO₃. Re-evaluation of the standard extraction technique, however, shows that it also may lead to severe loss of fine-grained SiC, a fact not commonly appreciated. A lower limit to SiC abundance in Murchison is 20 ppm, and previous conclusions that Murchison SiC is unusually coarse-grained compared to SiC in other primitive meteorites seem not to be warranted. Graphite and silicon nitride may survive and possibly can be separated after this step as suggested by a simulation experiment using terrestrial analog material, but the detailed behavior of meteoritic graphite requires further study.     

High spatio-temporal resolution measurements of cohesive sediment erosion

In this study, we present a novel approach to measure fundamental processes of cohesive sediment erosion. The experimental setup consists of a laboratory erosion flume (SETEG) and a photogrammetric method to detect sediment erosion (PHOTOSED). Detailed data are presented for three erosion experiments, which were conducted with a natural non-cohesive/cohesive sediment mixture at increasing sediment depths (4, 8, 16 cm). In each experiment, the sediment was exposed to a set of incrementally increasing shear stresses and the erosion was measured dynamically, pixel-based, and approximate to the process scale given the resolution of PHOTOSED. This enables us to distinguish between (i) individual emerging erosion spots caused by surface erosion and (ii) large holes torn open by detached aggregate chunks. Moreover, interrelated processes were observed, such as (iii) propagation of the erosion in the longitudinal and lateral direction leading to merging of disconnected erosion areas and (iv) progressive vertical erosion of already affected areas. By complementing the (bulk) erosion volume profiles with additional quantitative variables, which contain spatial information (erosion area, specific deepening, number of disconnected erosion areas), conclusions on the erosion behaviour (and the dominant processes) can be drawn without requiring qualitative information (such as visual observations). In addition, we provide figures indicating the spatio-temporal erosion variability and the (bulk) erosion rates for selected time periods. We evaluate the variability by statistical quantities and show that significant erosion is mainly confined to only a few events during temporal progression, but then considerably exceeds the time-averaged median of the erosion (factors between 7.0 and 16.0). Further, we point to uncertainties in using (bulk) erosion rates to assess cohesive sediment erosion and particularly the underlying processes. As a whole, the results emphasise the need to measure cohesive sediment erosion with high spatio-temporal resolution to obtain reliable and robust information. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Sea-level change, carbon cycling and palaeoclimate during the Late Cenomanian of northwest Europe; an integrated palaeoenvironmental analysis

A new high resolution sea-level curve for the Late Cenomanian M. geslinianum Zone has been generated using sequence stratigraphic analysis on transects through the margins of the Anglo-Paris Basin in the UK and Saxony Basin in Germany. Transgressive sediments that bury a rocky shoreline in the Dresden area have proved particularly useful in determining both the absolute amount of sea-level change and the rate of rise. After a brief fall at the base of the M. geslinianum Zone, sea level rose rapidly through the higher part of the zone, resulting in an overall short term eustatic rise of 22–28 m. Biostratigraphy and carbon isotope stratigraphy have enabled detailed correlations to be made between marginal locations and thick, relatively complete, basinal successions. The basinal successions at Eastbourne, UK, and Gröbern, Germany, provide both geochemical proxies for palaeoenvironmental change, including oxygen and carbon isotope records, and an orbital timescale graduated in precession and eccentricity cycles. Integration of the sea-level history with palaeoclimate evolution, palaeoceanography and changes in carbon cycling allows a detailed reconstruction of events during the Late Cenomanian. Orbital forcing on long eccentricity maxima provides the underlying drive for these changes, but amplification by tectonic events and feedback mechanisms augmented the orbital effects and made the Cenomanian/Turonian Boundary Event distinctive. In particular, variations in atmospheric CO₂ caused by oceanic drawdown and a brief period of intense volcanic outgassing resulted respectively in short term cooling and warming events. The magnitude and high rates (up to 1 m/1 kyr) of sea-level rise are diagnostic of glacioeustasy, however improbable this may appear at the height of the Cretaceous greenhouse.     

A mathematical magnetospheric field model with independent physical parameters

A quantitative magnetospheric magnetic field model has been calculated in three dimensions. The model is based on an analytical solution of the Chapman-Ferraro problem. For this solution, the magnetopause was assumed to be an infinitesimally thin discontinuity with given geometry. The shape of the dayside magnetopause is in agreement with measurements derived from spacecraft boundary crossings.The magnetic field of the magnetopause currents can be derived from scalar potentials. The scalar potentials result from solutions of Laplace's equation with Neumann's boundary conditions. The boundary values and the magnetic flux through the magnetopause are determined by all magnetic sources which are located inside and outside the magnetospheric cavity. They include the Earth's dipole field, the fields of the equatorial ring current and tail current systems, and the homogeneous interplanetary magnetic field. In addition, the flux through the magnetopause depends on two constants of interconnection which provide the possibility of calculating static interconnection between magnetospheric and interplanetary field lines. Realistic numerical values for both constants have been derived empirically from observed displacements of the polar cusps which are due to changes in the orientation of the interplanetary field. The transition from a closed to an open magnetosphere and vice versa can be computed in terms of a change of the magnetic boundary conditions on the magnetopause. The magnetic field configuration of the closed magnetosphere is independent of the amount and orientation of the interplanetary field. In contrast, the configuration of the open magnetosphere confirms the observational finding that field line interconnection occurs primarily in the polar cusp and high latitude tail regions.The tail current system reflects explicitly the effect of dayside magnetospheric compression which is caused by the solar wind. In addition, the position of the plasma sheet relative to the ecliptic plane depends explicitly on the tilt angle of the Earth's dipole. Near the tail axis, the tail field is approximately in a self-consistent equilibrium with the tail currents and the isotropic thermal plasma.The models for the equatorial ring current depend on the D_st-parameter. They are self-consistent with respect to measured energy distributions of ring current protons and the axially symmetric part of the magnetospheric field.     

Influence of subsolidus processes on the chromium number in spinel in ultramafic rocks

The chromium number of spinel Cr#^sp (atomic ratio of Cr/(Cr+Al)) is an important geochemical parameter for the estimation of the degree of partial melting, temperatures, and provenance in peridotites. In this study, a model has been developed in order to determine the effect of subsolidus reactions on the Cr#^sp in ultramafic rocks. The final model includes temperature-dependent distribution coefficients of relevant reactions as well as solubility data and has been applied to lithologies common in mid-ocean ridge settings. Significant changes in the Cr#^sp are predicted from the application of this model during cooling from 1300 to 800°C at mantle pressures. For spinel lherzolites and harzburgites, the Cr#^sp is predicted to decrease proportional to the absolute values of the Cr#^sp at (constantly) increasing spinel mass. Cpx-dunites show the same trend, although to a lower extent. Websterites show a different behavior with a slight increase in the Cr#^sp due to their lack of olivine. Modal abundance of spinel correlates with the magnitude in Cr#^sp change, too. Finally, these results were tested for possible effects on the calculated degree of partial melting as function of the Cr#^sp. Application of the Cr#^sp from a peridotite equilibrated down to 800°C would result in an underestimation of only 1.5 % in the degree of melting, justifying the use of Cr#^sp for estimations of this parameter.     

Calcium isotope record of Phanerozoic oceans: Implications for chemical evolution of seawater and its causative mechanisms

A total of 280 brachiopods of Ordovician to Cretaceous age, complemented by published data from belemnites and planktonic foraminifera, are used to reconstruct the evolution of calcium isotope composition of seawater (δ^44/40Ca_SW) over the Phanerozoic. The compiled δ^44/40Ca_SW record shows a general increase from ∼1.3‰ (NIST SRM 915a) at the beginning of the Ordovician to ∼2‰ at present. Superimposed on this trend is a major long-term positive excursion from the Early Carboniferous to Early Permian as well as several short-term, mostly negative, oscillations.A numerical model of the global cycles of calcium, carbon, magnesium and strontium was used to estimate whether the recorded δ^44/40Ca_SW variations can be explained by varying magnitudes of input and output fluxes of calcium to the oceans. The model uses the record of marine ⁸⁷Sr/⁸⁶Sr ratios as proxy for seafloor spreading rates, a record of oceanic Mg/Ca ratios to estimate rates of dolomite formation, and reconstructed atmospheric CO₂, discharge and erosion rates to estimate continental weathering fluxes.The model results indicate that varying magnitudes of the calcium input and output fluxes cannot explain the observed δ^44/40Ca_SW trends, suggesting that the isotope signatures of these fluxes must also have changed. As a possible mechanism we suggest variable isotope fractionation in the sedimentary output flux controlled by the dominant mineralogy in marine carbonate deposits, i.e. the oscillating ‘calcite-aragonite seas’. The ultimate control of the calcium isotope budget of the Phanerozoic oceans appears to have been tectonic processes, specifically variable rates of oceanic crust production that modulated the hydrothermal calcium flux and the oceanic Mg/Ca ratio, which in turn controlled the dominant mineralogy of marine carbonates, hence the δ^44/40Ca_SW. As to the causes of the short-term oscillations recorded in the secular δ^44/40Ca_SW trend, we tentatively propose that these are related to variable rates of dolomite formation and/or to changing chemical composition of the riverine flux, in particular and ratios, induced by variable proportions of silicate vs. carbonate weathering rates on the continents.     

<Superscript>10</Superscript>Be surface exposure dating of the last deglaciation in the Aare Valley,Switzerland

The combined Rhone and Aare Glaciers presumably reached their last glacial maximum (LGM) extent on the Swiss Plateau prior to 24 ka. Two well-preserved, less extensive moraine stades, the Gurten and Bern Stade, document the last deglaciation of the Aare Valley, yet age constraints are very scarce. In order to establish a more robust chronology for the glacial/deglacial history of the Aare Valley, we applied ¹⁰Be surface exposure dating on eleven boulders from the Gurten and Bern Stade. Several exposure ages are of Holocene age and likely document post-depositional processes, including boulder toppling and quarrying. The remaining exposure ages, however yield oldest ages of 20.7 ± 2.2 ka for the Gurten Stade and 19.0 ± 2.0 ka for the Bern Stade. Our results are in good agreement with published chronologies from other sites in the Alps.     

Vulnerability of water resources in northern Cameroon in the context of climate change

Water resources in northern Cameroon have continuously been reducing over the past years. Many studies have suggested two principal causes: (1) human activities such as poor farming practices, unsustainable use of water resources, increased demand of water, deforestation, land-use change, etc., (2) human-induced climate change. Northern Cameroon in this study includes: the Adamawa, North and Far North regions located closer to the Sahel regions of Africa. These regions are already water stressed because of their location and any further change in climate with rising temperature would impact water resource either positively or negatively. Time series analysis and a 12-month standardized precipitation index (SPI12) with digital data between 1957 and 2006 were used to investigate the variation of water resources in northern Cameroon. Results obtained varies between the different regions with an increased annual trend in temperature and precipitation for Ngaoundere (Adamawa region) and Garoua (north region), whereas Maroua (far north region) had a decreased annual trend in both precipitation and temperature. Further variability results obtained from a SPI12 show that wetter period out number drought period in all three regions. The study concluded that water resources vary with the changing climatic condition and the severity of the impact varies from region to region. Furthermore, water deficiency in northern Cameroon might not be due to climate change. The reasons might be a combination of poor water management and other factors such population growth, the environmental condition, etc.