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951.
D.Vaman Rao M.K. Narayanan U.B. Nayak K. Ananthapadmanabhan P. Somasundaran 《International Journal of Mineral Processing》1985,14(1):57-66
Separation of Mussorie rock phosphate (P2O5 = 20%) from Uttar Pradesh, India, containing pyrite, calcite and other carbonaceous impurities by flotation has been successfully attempted to upgrade the phosphate values. Based on Hallimond cell flotation results of single and synthetic mineral mixtures of calcite and apatite using oleic acid and potassium phosphate, conditions were obtained for the separation of calcite from apatite which is considered to be the most difficult step in the beneficiation of calcareous phosphates. Further studies using 250 g of the mineral (?60 +150 and ?150 mesh fractions, deslimed) in laboratory size Fagergren subaeration machine employed a stagewise flotation viz. carbonaceous materials using terpineol, pyrite using potassium-ethyl xanthate and calcite using oleic acid respectively. Separation was, however, found to be unsatisfactory in the absence of a depressant.Among starch, hydrofluosilicic acid and dipotassium hydrogen phosphate, which were tried as depressants for apatite in the final flotation stage, dipotassium hydrogen phosphate proved to be superior to others. However, the tests with the above fractions did not yield the required grade. This was possibly due to insufficient liberation of the phosphate mineral from the ore body and different experimental conditions due to scale up operations. Experiments conducted using ?200 mesh deslimed fractions has yielded an acceptable grade of 27.6% P2O5 with a recovery of about 60%. The results have been explained in terms of the specific adsorption characteristics of phosphate ions on apatite and the liberation size of the mineral. 相似文献
952.
Naguleswaran Niroshan Nagaratnam Sivakugan Ryan Llewellyn Veenstra 《Geotechnical and Geological Engineering》2018,36(4):2261-2272
Cemented paste backfill (CPB) is primarily used for backfilling underground voids at George Fisher Mine (Mount Isa, Australia). The objective of this paper is to summarise the geotechnical characterisation of the tailings and the rheological properties of the CPB as determined from a laboratory testing program undertaken at James Cook University. Two binders were examined [a General Purpose cement and a slag blend cement] over a range of dosages from 0 to 6% and CPB mix solids content in the range of 72–78%. The slump tests were carried out using the standard cone (ASTM C 143) used for concrete and a cylinder with 110 mm (diameter) × 110 mm (height), whereas the yield stress was measured using a shear vane (Brookfield vane spindle V-73). The index characteristics of the tailings including the grain size distribution, liquid limit, plastic limit, specific gravity were determined as per ASTM standards. This paper will then discuss the interrelationships among the solid content, slump, saturated density and the yield stress of the CPB. It is shown that there is strong correlation between the two different slump test devices used in this study. The smaller cylindrical device appears to have good potential for slurries like mine tailings or dredged mud that have high water content for slump test. There is also strong inter-relationship among solid content, slump, yield stress, and bulk density. Increasing the solid content increases the bulk density and yield stress, but reduces the slump. While there is hardly any difference between the two binder types used in this study in terms of flow parameters, namely the yield stress and slump, the binder dosage has an effect. At any specific solid content, higher binder dosages lead to a drop in the slump and increase in the yield stress. The difference is more pronounced in dense slurries. It is also strongly believed that the trends and relationships developed in this study may be valuable for the other mining operations using CPB. 相似文献
953.
The PbS-Bi2S3 join was studied up to 25 mole percent Bi2S3 by electron microscopy and diffraction. It was found that Bi2S3 can be incorporated into the PbS matrix by tropochemical twinning, forming isolated {113}PbS microtwins, or after clustering of these defects, lamellar twinned regions. Only two known mineral members of the homologous series (lillianite Pb3Bi2S6 and heyrowskyite Pb6Bi2S9) were found to be stable in this part of the PbS-Bi2S3 join, while irregularly spaced twin bands within these two structures were observed where deviations in the PbS/Bi2S3 ratio from 6/1 and 3/1, respectively, took place. No ordered intergrowth members were found between heyrowskyite and lillianite. The difference between the PbS-Bi2S3 join and the analogous MnS-Y2S3 one was attributed to the lone pair of nonbonded electrons from the Bi3+ ions, which tends to concentrate these ions in the vicinity of the twin planes. 相似文献
954.
Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst 总被引:5,自引:0,他引:5
Kyung Ho Park B. Ramachandra Reddy D. Mohapatra Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265
Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na2CO3 and H2O2 in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na2CO3, 10 vol.% H2O2 and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO3 of 97.30% purity was achieved by ammonium molybdate precipitation method. 相似文献
955.
A palygorskite unit was discovered in a road cut of undifferentiated Tertiary limestone between the villages of El Pariso
and San Roman (18°49.309N, 88°37.861W) in the southeastern Yucatán Peninsula, Mexico. This is the southern most locality of
a clay-rich sedimentary unit reported in the literature for the Tertiary carbonates of the Yucatán Peninsula. This occurrence
indicates a much wider range of palygorskite-rich clay deposition than previously recognized. The lithology is 99% clay and
1% sand to silt size diagenetic quartz grains. The clay consists of approximately 85% palygorskite, 15% montmorillonite and
trace amounts of titanium oxides. EDS analyses on palygorskite are largely consistent with sedimentary palygorskites from
other coastal marine settings, however palygorskite has a low total Fe content (average = 0.40 wt% expressed as Fe2O3) compared to many other sedimentary palygorskites. Montmorillonite chemical compositions are typical and compared to the
palygorskite have substantially higher Fe2O3 concentrations (average = 3.90 wt%). The low percentage of coarse grains in the lithology combined with a high proportion
of palygorskite and lack of detrimental trace minerals suggest the deposit is of industrial grade; however, it has limited
reserves (6,000 m3). The unit could be potentially used in a wide array of environmental applications which are needed in the region including
liners for landfills and constructed wetlands. The unit is in a geographic location which would serve the expanding economy
of the region. This resource has the potential to have great impact on the quality of the local environment and the economy
of a region under great environmental threat. 相似文献
956.
Bedard Jean H. J.; Marsh Bruce D.; Hersum Taber G.; Naslund H. Richard; Mukasa Samuel B. 《Journal of Petrology》2007,48(12):2289-2326
The Jurassic Ferrar dolerite sills of the McMurdo Dry Valleys,Antarctica represent the plumbing system for flood basalt eruptionsassociated with the breakup of Gondwana. Among the Ferrar sills,the 350–450 m thick cumulate-textured Basement Sill isdifferentiated into a Lower Marginal Zone (LMZ) gabbronorite,a thick Lower Zone (LZ) orthopyroxene–plagioclase orthocumulatepyroxenite, a strongly layered mela- to leuco-gabbronorite MiddleZone (MZ), a thick Upper Zone (UZ) gabbronorite with ferrogabbroicpods, and an Upper Marginal Zone (UMZ) gabbronorite. Texturesand mineral compositions in the LZ pyroxenite and MZ–UZgabbronorites are nearly identical, the main distinction beingthe greater relative proportion of plagioclase in the MZ–UZgabbronorites, and of pigeonite in the UZ. Most orthopyroxenein the LZ, MZ and UZ occurs as sub-euhedral, normally zonedprimocrysts, commonly with rounded plagioclase inclusions. Plagioclaseis usually sub-euhedral and normally zoned, but can containsodic cores interpreted to be xenocrystic. Orthopyroxene andfeldspar compositions thoughout the sill are generally fairlyuniform, and resemble the compositions of micro-phenocrystsin the chilled margins. We infer that the sill was filled bya c. 1250°C slurry of orthopyroxene + plagioclase phenocrystsor primocrysts that subsequently unmixed in response to buoyancyforces. The LZ websterite contains numerous anorthosite to gabbronoriteschlieren, veins and pipes (< 2 m diameter), which we interpretas fossil segregation channels. Textures and mineral compositionsin these felsic channels are very similar both to UZ and MZgabbronorites, and to the groundmass separating accumulatedorthopyroxene primocrysts in the LZ and MZ. We infer that plagioclase-charged,hydrous pore melt from the pyroxenite may have segregated, pooledand ascended through these conduits to feed growth of the UZgabbronorite. Detailed mapping shows that the pipes are separatedby about 15 m on average. Calculations suggest that this numberdensity of conduits could have drained the LZ cumulates of theirinterstitial melt + plagioclase in about 8 days. Sequences (eachc. 5–10 m thick) of layered leuco-gabbronorite in theMZ could represent intra-cumulate sills that formed from plagioclase-richslurries ascending in segregation channels. Fe–Ti-richpyroxenitic veins and pods (some pegmatitic) and an unusualcoarse-grained plagioclase facies occur at the contacts betweenmassive leuco-gabbronorite layers in the MZ. Discordant ferro-pegmatitepods and dykes occur throughout the UZ. We interpret these Fe-richpegmatoidal rocks as evolved residual melts expelled from thecompacting gabbronoritic cumulates of the MZ and UZ. KEY WORDS: Ferrar; cumulates; differentiation; Antarctica; layering 相似文献
957.
G. T. Skublov Yu. B. Marin S. G. Skublov Yu. N. Tarasenko 《Geology of Ore Deposits》2008,50(7):535-550
Volkhovites—tektite-like glasses—have been detected in the Holocene glacial drift along the right bank of the Volkhov River. A cryptomagmatic model of their formation and pre-Holocene age of volkhovite melts, cinder, and frothed glasses has been suggested (Skublov et al., 2007). Four geochemical types of volkhovites are distinguished: (1) manganous (Mn, Fe, Cr, V, Si, Nb, Pb, H), (2) magnesian (Mg, Al, Ti, F, B), (3) potassic (K, Rb, Cs), and (4) calcic (Ca, REEs, Ba, U, Th, Ta, Hf, Y, Sc, Cl). In light of the geochemical data, volkhovites are regarded as natural silicate glasses of kimberlite-carbonatite composition. Their types are called kimberlitic (Mn type), kimberlitic-carbonatitic (Mg type), lamproitic-carbonatitic (K type), and carbonatitic (Ca type). Volkhovites are suggested to be indicators of undiscovered diamond mineralization of kimberlite or carbonatite (Chagatai) types. 相似文献
958.
Two chemical processes can remove Mg2+ from suspensions containing amorphous silica (am-SiO2) at low temperatures: adsorption and precipitation of a Mg-hydroxysilicate resembling sepiolite. Mg2+ removal from am-SiO2 suspensions was investigated, and the relative role of the two removal processes evaluated, as a function of: pH, ionic strength, Mg2+ concentration, and temperature.The extent of Mg2+ adsorption onto am-SiO2 decreases with increasing NaCl concentration due to displacement of Mg2+ by Na+. At NaCl concentrations of 0.05 M and above, adsorption occurs only at pH values above 8.5, where rapid dissolution of am-SiO2 gives rise to high concentrations of dissolved silica, resulting in supersaturation with respect to sepiolite. Removal of Mg2+, at concentrations of 40 to 650 μM, from am-SiO2 suspensions in 0.70 M NaCl at 25 °C occurs at pH 9.0 and above. Experiments show that under these conditions adsorption and Mg-hydroxysilicate precipitation remove Mg2+ at similar rates. For 0.05 M Mg2+, at 0.70 M ionic strength and 25 °C, measurable Mg2+ removal occurs down to ca. pH 7.5 but is primarily due to Mg-hydroxysilicate precipitation. For the same solution conditions at 5°C, Mg2+ removal occurs above pH 8.0 and is primarily due to adsorption.Assuming that increasing pressure does not greatly enhance adsorption, Mg2+ adsorption onto am-SiO2 is an insignificant process in sea water. The surface charge of pristine am-SiO2 in sea water is primarily controlled by interactions with Na+. The principal reaction between Mg2+ and am-SiO2 in marine sediments is sepiolite precipitation.The age distribution of sepiolite in siliceous pelagic sediments is influenced by temperatures of bottom waters and by geothermal gradients. 相似文献
959.
The infrared reflectivity spectra of two natural cassiterite single crystals from Portugal and Vietnam have been studied and analysed in the frequency range of 15–4000 cm–1 at room temperature. The optical mode parameters are deduced by simulation of the experimental spectra using the factorised form of the dielectric function. The difference with synthetic SnO2 spectra is a dip near 500 cm–1 understood as the activation of an infrared forbidden E
g
mode due to the amount of Fe3+ and Ti4+ impurities. Another result of this work is the derivation of the correct values of the static dielectric constant of cassiterite. 相似文献
960.
V. V. Yarmolyuk V. P. Kovach V. I. Kovalenko E. B. Salnikova A. M. Kozlovskii A. B. Kotov S. Z. Yakovleva A. M. Fedoseenko 《Petrology》2011,19(1):55-78
Data on the composition, inner structure, and age of volcanic and siliceous-terrigenous complexes and granitoids occurring
in association with them in the Caledonian Lake zone in Central Asia are discussed in the context of major relations and trends
in the growth of the Caledonian continental crust in the Central Asian Foldbelt (CAFB). The folded structures of the Lake
zone host basalt, basalt-andesite, and andesite complexes of volcanic rocks that were formed in distinct geodynamic environments.
The volcanic rocks of the basalt complex are noted for high concentrations of TiO2 and alkalis, occur in association with fine-grained siliceous siltstone and siliceous-carbonate rocks, are thus close to
oceanic-island complexes, and were likely formed in relation to a mantle hotspot activity far away from erosion regions supplying
terrigenous material. The rocks of the basalt-andesite and andesite complexes have lower TiO2 concentrations and moderate concentrations of alkalis and contain rock-forming amphibole. These rocks are accompanied by
rudaceous terrigenous sediments, which suggests their origin in island-arc environments, including arcs with a significantly
dissected topography. These complexes are accompanied by siliceous-terrigenous sedimentary sequences whose inner structure
is close to those of sediments in accretionary wedges. The folded Caledonides of the Lake zone passed through the following
evolutionary phases. The island arcs started to develop at 570 Ma, their evolution was associated with the emplacement of
layered gabbroids and tonalitetrondhjemite massifs, and continued until the onset of accretion at 515–480 Ma. The accretion
was accompanied by the emplacement of large massifs of the tonalite-granodiorite-plagiogranite series. The postaccretionary
evolutionary phase at 470–440 Ma of the Caledonides was marked by intrusive subalkaline and alkaline magmatism. The Caledonides
are characterized by within-plate magmatic activity throughout their whole evolutionary history, a fact explained by the accretion
of Vendian-Cambrian oceanic structures (island arcs, oceanic islands, and back-arc basins) above a mantle hotspot. Indicators
of within-plate magmatic activity are subalkaline high-Ti basalts, alkaline-ultrabasic complexes with carbonatites and massifs
of subalkaline and alkaline gabbroids, nepheline syenites, alkaline granites, subalkaline granites, and granosyenites. The
mantle hotspot likely continued to affect the character of the lithospheric magmatism even after the Caledonian folded terrane
was formed. 相似文献