Microcracking in calcite and dolomite marble: microstructural influences and effects on properties

Microstructure‐based finite-element analysis with a microcracking algorithm was used to simulate an actual degradation phenomenon of marble structures, i.e., microcracking. Both microcrack initiation and crack propagation were characterized, as were their dependence on lattice preferred orientation (LPO), grain shape preferred orientation (SPO), grain size, marble composition (calcite and dolomite) and grain‐boundary fracture toughness. Two LPOs were analyzed: a random orientation distribution function and an orientation distribution function with strong directional crystalline texture generated from a March–Dollase distribution. Three SPOs were considered: equiaxed grains; elongated grains and a mixture of equiaxed and elongated grains. Three different grain sizes were considered: fine grains of order 200 μm (only calcitic marble); medium size grains of order 1 mm (calcitic and dolomitic marbles); and large grains of order 2 mm (only dolomitic marble). The fracture surface energy for the grain boundaries, γ_ig, was chosen to be 20 and 40 % of the fracture surface energy of a grain, γ_xtal, so that both intergranular and transgranular fracture were possible. Studies were performed on these idealized marble microstructures to elucidate the range of microcracking responses. Simulations were performed for both heating and cooling by 50 °C in steps of 1 °C. Microcracking results were correlated with the thermoelastic responses, which are indicators related to degradation. The results indicate that certain combinations of LPO, SPO, grain size, grain‐boundary fracture toughness and marble composition have a significant influence on the thermal-elastic response of marble. Microstructure with the smallest grain size and the highest degree of SPO and LPO had less of a tendency to microcrack. Additionally, with increasing SPO and LPO microcracking becomes more spatially anisotropic. A significant observation for all microstructures was an asymmetry in microcracking upon heating and cooling: more microcracking was observed upon cooling than upon heating. Given an identical microstructure and crystallographic texture, calcite showed larger thermal stresses than dolomite, had an earlier onset of microcracking upon heating and cooling, and a greater microcracked area at a given temperature differential. Thermal expansion coefficients with and without microcracking were also determined.     

Role of tropical atlantic SST variability as a modulator of El Niño teleconnections

The present study suggests that the off-equatorial North Atlantic (NATL) SST warming plays a significant role in modulating El Niño teleconnection and its impact on the North Atlantic and European regions. The El Niño events accompanied by NATL SST warming exhibit south-north dipole pattern over the Western Europe to Atlantic, while the ENSO teleconnection pattern without NATL warming exhibits a Rossby wave-like pattern confined over the North Pacific and western Atlantic. Especially, the El Niño events with NATL warming show positive (negative) geopotential-height anomalies over the North Atlantic (Western Europe) which resemble the negative phase of the NAO. Consistently, it is shown using a simple statistical model that NATL SSTA in addition to the tropical Pacific SSTA leads to better prediction on regional climate variation over the North Atlantic and European regions. This role of NATL SST on ENSO teleconnection is also validated and discussed in a long term simulation of coupled global circulation model (CGCM).     

Granitic dimensional stones in Uruguay: evaluation and assessment of potential resources

In Uruguay commercial granite varieties comprise mafic rocks, granitoids, and syenitoids. There is a long tradition in Uruguay, as well as worldwide, of using dimensional stones in architecture and art, specially granitic ones. Some of the present applications of these dimensional stones are as façade cladding, countertops, and outdoor and indoor floor slabs. The color spectrum of the Uruguayan granitic dimensional stones varies from black to light gray, covering a wide variety of red and pink and minor greenish-gray. The décor of these granitic dimensional stones is mainly determined by their fabric, fundamentally the grain size and the color distribution between the different minerals that compose the rocks. In the present research the most important commercial granites were sampled to analyze their petrography and petrophysical properties. A detailed structural analysis has been performed in several deposits, as well as the application of the software 3D Block Expert for modeling the possible raw block size distribution. Other factors controlling the mining viability of the deposits were also studied (e.g., homogeneity/heterogeneity of color and décor) and the possible reserves were calculated.     

The plutonism in the North Chilean Coast-Range and its geodynamic significance

Extended deep plutons of the Chilean Coast-Range can, according to their composition, age and spatial distribution, be assigned to the following three Superunits, each of which represents a closed magmatic cycle. Albayay-Superunit approximately 300-200 m. a. Cifuncho-Superunit approximately 190-130 m. a. Esmeralda-Superunit less than 130 m. a.Structurally we distinguished five large batholithic complexes, which are tectonically displaced along vertical fault-planes. The petrographie composition ranges from gabbronoritic through dioritic up to granitic rocks with predominance of granitoids.Methodical investigation led beyond the explanation of the origin of the magma, and opened the way for new geogynamic interpretations. We postulate a model of repeated crustal thickening caused by continental collision, which is opposed to the schematic plate-tectonics model.

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Zusammenfassung In der Küstenkordillere Nordchiles lassen sich ausgedehnte Tiefengesteinskörper nach Stoffbestand, Alter und rÄumlicher Verteilung folgenden drei Superunits zuordnen, die jeweils einem abgeschlossenen magmatischen Zyklus entsprechen. Albayay-Superunit ca. 300-200 m. a. Cifuncho-Superunit ca. 190-130 m. a. Esmeralda-Superunit jünger als 130 m. a.Strukturell haben wir fünf grö\ere, durch Tektonik entlang vertikaler Brüche zerlegte Baholith-Komplexe ausgeschieden. Die petrologische Zusammensetzung reicht von gabbro-noritischen über dioritische bis zu granitischen Gesteinen, wobei der Schwerpunkt bei den Granitoiden liegt.Die methodische Untersuchung führte über die KlÄrung der Magmengenese hinaus und eröffnete den Zugang zu neuen geodynamischen Vorstellungen. Wir postulieren ein Modell einer mehrphasigen Krustenverdickung durch kontinentale Kollision, das im Gegensatz zu dem schematischen Modell der Plattentektonik steht.

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Resumen En la Cordillera de la Costa del Norte de Chile existen extensos cuerpos intrusivos que se queden asignar, sobre la base de su composición, edad y distribución espacial, a las tres Superunidades siguientes, las que a su vez corresponden a ciclos magmáticos completos. Superunidad-Albayay approximadamente 300-200 m.a. Superunidad-Cifuncho approximadamente 190-130 m.a. Superunidad-Esmeralda más jóvenque 130 m.a.Estructuralmente hemos distinguido cinco complejos batoliticos mayores recortados por una tectónica de fallas verticales. La compositión petrográfica va desde rocas gabronoríticas hasta graníticas pasando por las dioríticas, con predominio de granitoides.El análisis metódico de los datos obtenidos orientado a la petrogénesis de estos cuerpos dió lugar a nuevas interpretaciones geodinámicas. Postulamos un modelo de fases sucesivas de acumulación cortical mediante colisión continental, el cual se opone al esquemático modelo de la Tectónica de Placas.

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, , : Albayay-Superunit ... 300-200 Cifuncho-Superunit ... 190-130 Esmeralda-Superunit ... 130 . 5 . - , , . y ; .

     

A Computationally Efficient,Time-Dependent Model of the Solar Wind for Use as a Surrogate to Three-Dimensional Numerical Magnetohydrodynamic Simulations

Solar radiation variability spans a wide range in time, ranging from seconds to decadal and longer. The nearly 40 years of measurements of solar irradiance from space established that the total solar irradiance varies by \(\approx 0.1\%\) in phase with the Sun’s magnetic cycle. Specific intervals of the solar spectrum, e.g., ultraviolet (UV), vary by orders of magnitude more. These variations can affect the Earth’s climate in a complex non-linear way. Specifically, some of the processes of interaction between solar UV radiation and the Earth’s atmosphere involve threshold processes and do not require a detailed reconstruction of the solar spectrum. For this reason a spectral UV index based on the (FUV-MUV) color has been recently introduced. This color is calculated using SORCE SOLSTICE integrated fluxes in the FUV and MUV bands. We present in this work the reconstructions of the solar (FUV-MUV) color and Ca ii K and Mg ii indices, from 1749–2015, using a semi-empirical approach based on the reconstruction of the area coverage of different solar magnetic features, i.e., sunspot, faculae and network. We remark that our results are in noteworthy agreement with latest solar UV proxy reconstructions that exploit more sophisticated techniques requiring historical full-disk observations. This makes us confident that our technique can represent an alternative approach which can complement classical solar reconstruction efforts. Moreover, this technique, based on broad-band observations, can be utilized to estimate the activity on Sun-like stars, that cannot be resolved spatially, hosting extra-solar planetary systems.

     

Refinement of Near Earth Asteroids’ orbital elements via simultaneous measurements by two observers

The aspects of triangulation of Near Earth Asteroids by two arbitrarily positioned observers (one spaceborne and the other Earth-bound, as well as both spaceborne) are being investigated, and the resulting orbital elements are compared to those gained through common orbital determination and refinement techniques. The main advantages of the method proposed in this work are, that given the approximate position of an asteroid, high quality orbital elements can be acquired very rapidly using two observations only.     

Epiphytic orchids and their ecological niche under anthropogenic influence in central Himalayas,Nepal

The survival chance of epiphytic orchids today not only depends on the natural site conditions required by the orchids but also on anthropogenic changes in site conditions.This study answers two questions:(1) What is the ecological niche of the different epiphytic orchid species?(2) What are the ecological factors that threaten epiphytic orchid's population under anthropogenic disturbances? Our study area was the Kathmandu valley,Nepal,with its subtropical forest.We established 156 systematically selected sampling points in the Kathmandu area covering different types of ecosystems under human impacts such as densely populated area,agricultural land,mixed agricultural and settled area,old tree patches,and a natural forest in a national park.The ecological niche of the orchid species was analyzed with a principal component analysis(PCA).The correlations between the different site factors were statistically significant.Spearman's rank correlation matrices showed that the variables land-use intensities with altitude,and height with diameter in breast height(dbh) of host had the highest significant positive correlation coefficient(0.67 and 0.64 respectively).On the other hand,host bark p H and altitude as well as land use had a significantly strong negative correlation coefficient(-0.80 and-0.61,respectively).Different epiphytic orchid species interact differently with the given set ofenvironmental factors:for occurrence of Vanda cristata there is no single environmental factor of special influence,while for Rhynchostylis retusa high bark p H and high light availability are important.First two axis of the PCA explained more than 50% of the total variance.Most orchid species occupy a specific,narrow niche in this ecological space.The main causes of anthropogenic influence of orchid population in the Kathmandu Valley are loss of adequate host trees(species and size) and increasing air pollution,resulting in increasing host bark p H.     

Decadal prediction skill in the GEOS-5 forecast system

A suite of decadal predictions has been conducted with the NASA Global Modeling and Assimilation Office’s (GMAO’s) GEOS-5 Atmosphere–Ocean general circulation model. The hind casts are initialized every December 1st from 1959 to 2010, following the CMIP5 experimental protocol for decadal predictions. The initial conditions are from a multi-variate ensemble optimal interpolation ocean and sea-ice reanalysis, and from GMAO’s atmospheric reanalysis, the modern-era retrospective analysis for research and applications. The mean forecast skill of a three-member-ensemble is compared to that of an experiment without initialization but also forced with observed greenhouse gases. The results show that initialization increases the forecast skill of North Atlantic sea surface temperature compared to the uninitialized runs, with the increase in skill maintained for almost a decade over the subtropical and mid-latitude Atlantic. On the other hand, the initialization reduces the skill in predicting the warming trend over some regions outside the Atlantic. The annual-mean atlantic meridional overturning circulation index, which is defined here as the maximum of the zonally-integrated overturning stream function at mid-latitude, is predictable up to a 4-year lead time, consistent with the predictable signal in upper ocean heat content over the North Atlantic. While the 6- to 9-year forecast skill measured by mean squared skill score shows 50 % improvement in the upper ocean heat content over the subtropical and mid-latitude Atlantic, prediction skill is relatively low in the subpolar gyre. This low skill is due in part to features in the spatial pattern of the dominant simulated decadal mode in upper ocean heat content over this region that differ from observations. An analysis of the large-scale temperature budget shows that this is the result of a model bias, implying that realistic simulation of the climatological fields is crucial for skillful decadal forecasts.     

Fault gouge analyses: K–Ar illite dating,clay mineralogy and tectonic significance—a study from the Sierras Pampeanas,Argentina

We introduce a method for the detailed interpretation of K–Ar illite fine-fraction ages of fault gouges from non-sedimentary host rocks. Ages are cross-evaluated with several independent parameters, e.g. illite crystallinity, illite polytype quantification, grain size, mineralogical observations, K–Ar muscovite and biotite host-rock cooling ages as well as low-temperature thermochronological data (AFT, AHe, ZHe). This interpretation approach is applied to a regional study in order to constrain the ‘deformation path’ of the Eastern Sierras Pampeanas in NW Argentina. In the course of this study, a large number of gouge-bearing fault zones were systematically sampled and analysed. Obtained K–Ar illite fine-fraction ages range from Devonian to Cretaceous times, documenting a long-lasting brittle fault activity in this region. Ages >320 Ma are synchronous with a period of intra-Carboniferous compressional tectonism, whereas Permo-Triassic ages are contemporaneous to a flat-slab subduction episode of the Farallon plate beneath the South American plate. Middle to Late Permian and Early Triassic ages as well as Early Jurassic to Middle Cretaceous ages correlate with extensional tectonics in this region. Additionally, K–Ar illite ages reveal a propagation of brittle deformation from north to south in the Sierras de Córdoba and San Luis. Data integrity and consistency with other chronometers and geological evidence show that the here suggested interpretation is valid and can provide a powerful tool to evaluate cooling and deformation histories. Despite of that, we could show that the reliability of fault gouge data strongly depends on the regional cooling.