Hydrodynamic conditions and karst formation in the northwest part of Syria

The study of hydrodynamic zonation and karst formation in the northwest part of Syria is a topical hydrogeological problem. It is important to trace the history of karst formation and evaluate the spread of karst structures in the area and the rate of development of karst processes, as well as their influence on water supplies and irrigation. The solution of this problem was performed by integrated geophysical methods (electric and seismic exploration works) and data analysis of well-drilling, geological, hydro-geological, and subsurface territory explorations. The most detailed works were done near Ras Al-Ain. This paper is devoted to the results of the study of hydrodynamic conditions and karst formation.     

Space Weather: Physics,Effects and Predictability

The time varying conditions in the near-Earth space environment that may affect space-borne or ground-based technological systems and may endanger human health or life are referred to as space weather. Space weather effects arise from the dynamic and highly variable conditions in the geospace environment starting from explosive events on the Sun (solar flares), Coronal Mass Ejections near the Sun in the interplanetary medium, and various energetic effects in the magnetosphere–ionosphere–atmosphere system. As the utilization of space has become part of our everyday lives, and as our lives have become increasingly dependent on technological systems vulnerable to the space weather influences, the understanding and prediction of hazards posed by these active solar events have grown in importance. In this paper, we review the processes of the Sun–Earth interactions, the dynamic conditions within the magnetosphere, and the predictability of space weather effects on radio waves, satellites and ground-based technological systems today.     

Deep inside a neoproterozoic intra-oceanic arc: growth,differentiation and exhumation of the Amalaoulaou complex (Gourma,Mali)

We show here that the Amalaoulaou complex, in the Pan-African belt of West Africa (Gourma, Mali), corresponds to the lower and middle sections of a Neoproterozoic intra-oceanic arc. This complex records a 90–130-Ma-long evolution of magmatic inputs and differentiation above a subducting oceanic slab. Early c. 793 Ma-old metagabbros crystallised at lower crustal or uppermost mantle depths (25–30 km) and have geochemical characteristic of high-alumina basalts extracted from a depleted mantle source slightly enriched by slab-derived sedimentary components ((La/Sm)_N < 1; ε_Nd: +5.4–6.2; ⁸⁷Sr/⁸⁶Sr: 0.7027–0.7029). In response to crustal thickening, these mafic rocks were recrystallised into garnet-granulites (850–1,000°C; 10–12 kbar) and subject to local dehydration–melting reactions, forming trondhjemititic leucosomes with garnet–clinopyroxene–rutile residues. Slightly after the granulitic event, the arc root was subject to strong HT shearing during partial exhumation (detachment faults/rifting or thrusting), coeval with the emplacement of spinel- and garnet-pyroxenite dykes crystallised from a high-Mg andesitic parental magma. Quartz and hornblende-gabbros (700–660 Ma) with composition typical of hydrous volcanic rocks from mature arcs ((La/Sm)_N: 0.9–1.8; ε_Nd: +4.6 to +5.2; ⁸⁷Sr/⁸⁶Sr: 0.7028–0.7031) were subsequently emplaced at mid-arc crust levels (~15 km). Trace element and isotopic data indicate that magmas tapped a depleted mantle source significantly more enriched in oceanic sedimentary components (0.2%). Exhumation occurred either in two stages (700–660 and 623 Ma) or in one stage (623 Ma) with a final exhumation of the arc root along cold P-T path (550°C, 6–9 kbar; epidote–amphibolite and greenschist facies conditions) during the main Pan-African collision event (620–580 Ma). The composition of magmas forming the Cryogenian Amalaoulaou arc and the processes leading to intra-arc differentiation are strikingly comparable to those observed in the deep section of exposed Mezosoic oceanic arcs, namely the Kohistan and Talkeetna complex. This evolution of the Amalaoulaou oceanic arc and its accretion towards the West African craton belong to the life and closure of the Pharusian Ocean that eventually led to the formation of the Greater Gondwana supercontinent, a similar story having occurred on the other side of the Sahara with the Mozambique Ocean.     

Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution

Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions, but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation of Fe(OH)₃ on the surface of pyrite, reaction between Fe(OH)₃ and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration of silica.     

Numerical simulation of migration–accumulation of oil resources

Numerical simulation of oil migration and accumulation is to describe the history of oil migration and accumulation in basin evolution. It is of great value to the evaluation of oil resources and to the determination of the location and amount of oil deposits. This thesis discusses the characteristics of petroleum geology and permeation fluid mechanics. For the three-dimensional problems of Dongying hollow of Shengli Petroleum Oil Field, it puts forward a new model and a kind of modified method of upwind finite difference fractional steps implicit interactive scheme. For the famous hydraulic experiment of secondary migration–accumulation, the numerical simulation test has been done, and both the computational and experimental results are basically identical. For the actual problem of Dongying hollow, the numerical simulation test and the actual conditions are basically coincident. Thus, the well-known problem has been solved.     

Hafnium isotopic variations in East Atlantic intraplate volcanism

The broad belt of intraplate volcanism in the East Atlantic between 25° and 37° N is proposed to have formed by two adjacent hotspot tracks (the Madeira and Canary tracks) that possess systematically different isotopic signatures reflecting different mantle source compositions. To test this model, Hf isotope ratios from volcanic rocks from all individual islands and all major seamounts are presented in this study. In comparison with published Nd isotope variations (6 εNd units), ¹⁷⁶Hf/¹⁷⁷Hf ratios span a much larger range (14 εHf units). Samples from the proposed Madeira hotspot track have the most radiogenic Hf isotopic compositions (¹⁷⁶Hf/¹⁷⁷Hf_m up to 0.283335), extending across the entire field for central Atlantic MORB. They form a relatively narrow, elongated trend on the Nd vs. Hf isotope diagram (stretching over > 10 εHf units) between a depleted N-MORB-like endmember and a moderately enriched composition located on, or slightly below, the Nd–Hf mantle array, which overlaps the proposed “C” mantle component of Hanan and Graham (1996). In contrast, all samples from the Canary hotspot track plot below the mantle array (¹⁷⁶Hf/¹⁷⁷Hf_m = 0.282943–0.283067) and form a much denser cluster with less compositional variation (~4 εHf units). The cluster falls between (1) a low Hf isotope HIMU-like endmember, (2) a more depleted composition, and (3) the moderately enriched end of the Madeira trend. The new Hf isotope data confirm the general geochemical distinction of the Canary and Madeira domains in the East Atlantic. Both domains, however, seem to share a common, moderately enriched endmember that has “C”-like isotope compositions and is believed to represent subducted, <1-Ga-old oceanic lithosphere (oceanic crust and possibly minor sediment addition). The lower ¹⁷⁶Hf/¹⁷⁷Hf ratio of the enriched, HIMU-like Canary domain endmember indicates the contribution of oceanic lithosphere with somewhat older recycling ages of ≥1 Ga.     

The Characteristic Patterns of Macrofaunal Fouling Assemblages in Nearshore Waters of the South China Sea

The spatio-temporal patterns of macrofaunal fouling assemblages were quantitatively investigated in the nearshore waters of the South China Sea. The work was undertaken by deploying seasonal panels at two sites (H-site, L-site) for one year, and the fouling communities on the panels were examined and analyzed. The results indicated that species composition of assemblages was obviously different between the two sites. At both sites the assemblages were characteristic with solitary dominant species throughout the year, with Amphibalanus reticulates dominating at H-site and Hydroides elegans at L-site. Shannon index and biomass of the assemblages varied with depth and season at both sites. At H-site the total biomass in summer and autumn were significantly higher than those in spring and winter, while at L-site the assemblage biomass also differed significantly among the four seasons, and the greatest biomass occurred at the depth of 2.0 m in winter. The abundance of all seasonal samples in non-metric multidimensional scaling was clustered as one group at L-site and three groups at H-site. The environmental factors were more likely to be related to the variation of fouling assemblages. Furthermore, it also suggests that in tropical seas the integrated adaptability would qualify a species for dominating a fouling assemblage despite its short life cycle, rather than the usually assumed only species with long life span. This study reveals the complexity and characteristic dynamics of macrofaunal fouling assemblages in the tropical habitats, and the results would provide valuable knowledge for biodiversity and antifouling research.     

Influence of Headland Breakwaters on Morphological Processes at Longfengtou Beach in Haitan Bay,Facing the Taiwan Strait

Breakwaters can be used as artificial headlands in beach nourishment to mitigate coastal erosion. Longfengtou Beach, located on the southwest coast of Haitan Bay facing the Taiwan Strait on the northeast, suffers severe erosion, where the monsoon causes significant season hydrodynamic variations. Headland breakwaters are intended to be employed to mitigate coastal erosion. A 2D sediment transport model is established using MIKE21 based on current-wave coupling and calibrated by measured data. Summer and winter wave conditions are chosen as characteristic weak and strong waves respectively. The numerical results of suspended sediment concentration and seasonal morphological evolution are compared under the conditions with and without the headland breakwaters. Sediment transport in summer can be regarded as mainly determined by current field, while in winter wave effect is strong enough to change current field. The northern breakwater, nearly perpendicular to the ebb current direction, obstructs the currents and decreases velocity of the ebb currents, and confines the water carrying sediments within the protection area during the flood period. The southern breakwater also breaks the waves in advance and significantly reduces the hydrodynamic effects during the flood period and maintains high suspended sediment concentration in the protection area. In general, two headland breakwaters decrease the erosion near the beach and enlarge the deposition area, which play a significant role in prevention of sediment loss in nearshore area and mitigate coastal erosion.     

Petrological considerations for the demineralization of Rajmahal coals with <Emphasis Type="Italic">Pseudomonas mendocina</Emphasis> B6-1

The present study entails the results of the petrological coniderations for demineralization of Rajmahal Gondwana coals with Psudomonas mendocina B6-1. Inertinite group macerals are the dominant constituents of these coals, followed by vitrinite group, while liptinite occurs in low concentration. The amount of Mineral matter is moderately high. The concentration of major, minor and trace elements is high when compared with Clarke values. After the treatment of these coals with Pseudomonas mendocina strain B6-1, a significant reduction in the elemental content of oxygen, hydrogen and sulphur was observed. A gradual reduction of pyrite phase due to bioleaching was identified and its signatures were reflected in the XRD spectra and FTIR absorption bands. Over 5 % reduction in the ash content and decrease of major, minor and trace element to variable degrees were also noticed. Fe, As, and Ca positively correlate with the ash removal percentage indicating that the samples with high concentration of these elements were prone to demineralization with Pseudomonas mendocina strain B6-1 whereas Ni, Zn, Cr and Cu, negatively correlate with the ash removal percentage and shows that their enrichment impeded the process of demineralization. With increasing concentration of vitrinite the removal of major/minor/trace elements also increased which is attributed to the possible association of these elements with the mineral matter occurring as superficial mounting and superficial blanketing over the vitrinite macerals. This could facilitate the bacterial access to the elements to act upon and remove it to the variable extent. Some minerals occur intergrown with inertinites causing restricted bacterial action owing to the nonexposure of the mineral particles and less surface area available to the bacteria for bioleaching. Sulfur removal strongly relates with increase in inertinite content and decrease in liptinite content. This appears that sulfur associated with liptinites have shown difficult removal condition. The maximum removal of the trace elements like Cd, Cu, Co, Zn and Pb was observed from the ‘banded dull coal’ samples of the Rajmahal basin while maximum removal of major/minor elements like Fe, Ca and Mg was noticed from the ‘banded bright coal’ samples. However, maximum removal of Mn and As was also observed in the samples of ‘banded coal’.     

Monitoring and prediction of land use/land cover changes using CA-Markov model: a case study of Ravansar County in Iran

Human‐induced land use/land cover (LULC) changes are among the most important processes that shape the dynamics of the earth’s surface. This phenomenon, which is occurring at an astonishing rate, and its consequential environmental impacts have become an important area of research for scientists.Therefore, a wide range of methods and models have been developed to detect and predict these alterations, among which cellular automata (CA) models such as the CA‐Markov model, due to their affinity to geographic information system (GIS) and remote sensing (RS), are appropriate for detailed resolution modelling and simulating dynamic spatial processes. In Iran, the district of Ravansar has undergone severe LULC changes recently, thus to take the necessary precautions, decision‐makers need to predict and determine the extent of these changes. In this study, using spatial analysis methods the LULC changes in Ravansar were investigated from 1992 to 2015. Subsequently, the CA‐Markov model was applied to simulate the spatial pattern changes of LULC until 2030. Our results indicated that from 1992 to 2015, this region has witnessed a noticeable increase in the areas of the built‐up and agricultural lands (both aquatic and non‐aquatic), resulting in the decrease of the gardens, range, and bare lands. The simulated LULC map showed that this trend will continue due to more urbanization and development of agricultural areas.