贵州省从江县地虎铜多金属矿床地球化学特征

地虎矿床为蚀变岩型铜多金属矿床,围岩普遍发生蚀变。矿石的主量元素和微量元素分析结果显示,矿石中TiO_2和K_2O含量较低,微量元素中Ta的含量也较低。除了Nb/U值有较大差别外,其余的Th/Hf、Th/Zr、Nb/Zr、Zr/Y等比值都比较接近。稀土元素总体富集轻稀土,LREE/HREE值和(La/Sm)N值分别为1.012 9.095、1.409 5.997,变化范围较大,说明LREE、HREE内部分馏较明显;δEu、δCe分别为0.613 1.507、0.99 1.54,Eu正负异常明显,Ce主要显示正异常;稀土元素球粒陨石标准化图解曲线表现为右倾型。这些地球化学特征与宰变镁铁-超镁铁质岩体的地球化学特征相似,说明地虎矿床中的部分成矿物质可能来源于宰变镁铁-超镁铁质岩体,地虎矿床的形成可能是在板内拉张过程中同时或稍晚形成。     

A GIS-based method of risk assessment on no. 11 coal-floor water inrush from Ordovician limestone in Hancheng mining area,China

The no. 11 coal seam in the deep area of Hancheng mining area is mining in recent years, which is threatened by the water inrush from the Ordovician limestone aquifer. Coal-floor water inrush is governed by the water abundance of coal-floor aquifer, the water-resisting performance of coal-floor aquitard, and the pathway connecting the water source and the working face. To make an accuracy risk assessment of water inrush from the no. 11 coal seam floor, a GIS-based vulnerability index method (VIM) is adopted for its superior comprehensive consideration of more controlling factors, powerful spatial analysis, and intuitively display functions. This study firstly established an index system including the water pressure of the coal-floor aquifer, the unit water inflow, the thickness, the core recovery percentage, the thickness ratio of brittle rocks to ductile rocks, the thickness of effective aquitard, and the accumulated length of faults and folds, of which the former six indexes governed the water abundance of the coal-floor aquifer which was combined with the last two factors to determine the risk of coal-floor water inrush. Secondly, the thematic map of each controlling factor is established by GIS using the geological prospecting data, and the weight of each factor is determined by the analytic hierarchy process (AHP) after consulting the expert review panel. At last, a vulnerability index is obtained and used to assess the risk of coal-floor water inrush of the no. 11 coal seam. The risk of water inrush of the no. 11 coal seam of the study area was ranked to three zones: the southeastern shallow area in red color is the dangerous zone, the wide northwestern area in green color is the safe zone, and the transition area in yellow color is the moderate-risk zone. Compared with the actual water-inrush incidents, the risk assessment result was verified to achieve an accuracy of 82.35%, which is proved to be a dependable reference for the prevention and controlling of coal-floor water inrush of the no. 11 coal seam in Hancheng mining area.     

微波消解-电感耦合等离子体质谱法测定海泡石中的稀土元素

海泡石是一种纤维状含水的富镁硅酸盐黏土矿,其中的稀土元素含量在1×10~(-7)～1×10~(-5)之间,目前还没有建立海泡石中稀土元素的国家标准分析方法。测定岩石中的稀土元素主要是采用电感耦合等离子体质谱法(ICP-MS),样品前处理一般采用封闭溶矿和碱熔,但这两种处理方法耗时较长,效率不高。本文通过比较硝酸-氢氟酸-过氧化氢、硝酸-氢氟酸、硝酸-过氧化氢三种样品前处理方法,确定使用硝酸-氢氟酸溶矿,然后进行微波消解同时赶去氢氟酸,避免氢氟酸与稀土元素生成难溶的氟化物,再采用ICP-MS法测定15种稀土元素的含量。由于海泡石中的镁含量较高,为降低基体效应,以~(103)Rh和~(185)Re作内标补偿基体效应和校正灵敏度漂移,各元素测定值的准确性显著提高,回收率为91. 2%～110. 9%,检出限为0. 002～0. 011μg/L,精密度≤2. 79%。本方法与封闭酸溶ICP-MS法的分析结果吻合较好,且用酸量少(7 mL),溶矿效率高(1 h),检出限更低。     

基于重力及重力梯度数据的位场偏移成像

为了验证位场偏移快速成像方法的有效性以及对比基于重力和重力梯度数据的偏移成像的效果,笔者利用MATLAB编写了重力及重力梯度数据位场偏移成像的算法,并进行了模型正演计算,发现基于梯度数据的偏移成像的横向分辨率、抗噪性和抗背景场能力好于重力数据的偏移成像,并且能够较好的确定模型的中心埋深。将此方法应用于葫芦岛市黑鱼沟的某铅锌矿洞的深度计算中,验证了该方法的有效性。     

准噶尔盆地吉木萨尔凹陷梧桐沟组层序地层划分

准噶尔盆地吉木萨尔凹陷二叠系梧桐沟组作为一套重要的储集岩,具有良好的油气成藏前景,但对其层序划分及地层沉积样式的认识一直存在争议。在构造背景分析的基础上,结合岩芯、测井及地震资料,对研究区梧桐沟组层序地层划分及地层沉积样式研究表明,梧桐沟组沉积时期构造强度较弱,地形较为平缓,地层在全区稳定分布;中晚二叠世盆地发生造山运动,吉木萨尔凹陷东南边缘区域经过构造抬升,上部地层遭受不同程度的剥蚀,形成了现今"底平顶削"的地层样式。以凹陷中部少数地层保存较全的井的地层叠加样式分析为基础,通过井-震结合识别不同类型界面,特别是最大湖泛面,建立了区域层序地层格架,即梧桐沟组为一个完整的长期基准面旋回(三级层序),并在其内部识别出5个中期旋回。梧桐沟组地层在不同的层序发育时期表现出不同的旋回叠加样式:下段沉积时期,即最大湖泛面以下,随着可容纳空间的增大,地层表现为明显的退积叠加样式;上段沉积时期,即最大湖泛面以上,随着可容纳空间的减小,地层表现为明显的进积叠加样式,符合沉积物体积分配原理。     

Mid-Cretaceous Hothouse Climate and the Expansion of Early Angiosperms

The remarkable transition of early angiosperms from a small to a dominant group characterized the terrestrial ecosystem of the Cretaceous. This transition was instigated and promoted by environmental changes. Mid-Cretaceous is characterized by major geological events that affected the global environment. δ18O, palaeothermometer TEX86, and other climatic indices from marine sediments suggest rapid temperature increase during mid-Cretaceous despite occasional short cooling events. Simultaneously, terrestrial deposits in East Asia changed from coal-bearing to shale, then to red beds and evaporites. Plant assemblages and other paleoclimate indicators point to rapid aridification for mid-Cretaceous terrestrial environments. In addition, the wildfires were frequently spread all over the earth by the numerous charcoal evidence during the Mid-Cretaceous. Thus, we speculate that the seasonally dry and hot conditions of mid-Cretaceous created a fiery hothouse world. Early angiosperms increased in abundance and diversity and evolved from a few aquatic species to terrestrial herbaceous and then to the diversified flora of today. Angiosperms showed rapid physiological evolution in vein density and leaf area that improved photosynthesis and water absorption. These ecophysiological changes made early angiosperms well adapted to the hot and dry environment in mid-Cretaceous. Moreover, these physiological changes facilitated the fire–angiosperm cycles in mid-Cretaceous that likely further stimulated the early angiosperm evolution.     

A MATLAB-based Kriged Kalman Filter software for interpolating missing data in GNSS coordinate time series

GNSS coordinate time series data for permanent reference stations often suffer from random, or even continuous, missing data. Missing data interpolation is necessary due to the fact that some data processing methods require evenly spaced data. Traditional missing data interpolation methods usually use single point time series, without considering spatial correlations between points. We present a MATLAB software for dynamic spatiotemporal interpolation of GNSS missing data based on the Kriged Kalman Filter model. With the graphical user interface, users can load source GNSS data, set parameters, view the interpolated series and save the final results. The SCIGN GPS data indicate that the software is an effective tool for GNSS coordinate time series missing data interpolation.     

粤西河台金矿田糜棱岩XRD特征及其地质意义

粤西河台金矿区位于钦州湾—杭州湾（钦—杭）结合带南段的云开地区,是典型的受韧性剪切带控制的金矿。然而,对于剪切带中有利于金成矿的地质环境及其成矿过程仍然存在争议。本文在对河台矿区高村矿床进行详细野外地质调查的基础上,通过X射线衍射（XRD）对含金剪切带中各类糜棱岩系列岩石进行系统研究,建立应力变化—成分变异的对比序列,从而进一步揭示剪切变形与金矿化的关系。结果显示,剪切带中白（绢）云母的含量在9%~40%,并且在初糜棱岩、无矿糜棱岩、含矿糜棱岩、无矿超糜棱岩、含矿超糜棱岩中含量呈现出逐渐递增的趋势。白（绢）云母主要为2M1型,b0值分布在0.55505~0.99002 nm之间,在初糜棱岩、无矿糜棱岩和无矿超糜棱岩中逐渐增高,分别形成在低压、中压和高压环境。可见,从初糜棱岩到超糜棱岩,随着变形强度的增加,热液活动也随之增强,从而新生成了大量白（绢）云母。然而,在含矿的糜棱岩和超糜棱岩中还存在一些低压白云母,推测其可能是在后期脆性裂隙中由于流体活动所新形成的。因此,成矿可能经历了两个阶段,即早期的韧性剪切变形阶段导致金的初步富集,后期叠加的脆性破裂阶段形成具有工业品位的矿体。另外,无矿超糜棱岩的石英含量（29.8%）明显低于糜棱岩（44.2%）,推测在形成石英脉型矿体过程中,部分热液可能来自于其围岩超糜棱岩。因此,相对于初糜棱岩和糜棱岩,超糜棱岩中更有利于金矿的形成。     

渤海湾盆地大型基岩潜山储层特征及其控制因素——以渤中19- 6凝析气田为例

渤中19-6气田是渤海湾盆地近期发现的规模最大的深层变质基岩凝析气田,探明储量超过千亿立方米,气柱高度超1000 m,现今埋深大于4000 m,储层规模大但非均质性强.基于三维地震、钻井、测井以及薄片资料,明确了基岩潜山储层的发育特征,并探讨了优质储层形成的主控因素.结果表明:基岩潜山以太古宇变质花岗岩为主要的储集岩性,储集空间主要为构造裂缝,同时发育沿裂缝溶蚀形成的孔隙及构造破碎粒间孔,平均孔隙度为5％,平均渗透率为6.48×10-3μm2.脆性岩石、构造挤压以及风化作用共同控制了规模性储层的形成:① 研究区90％的岩石为低抗压强度的变质花岗岩,为裂缝的形成提供了物质基础;② 印支期强烈的挤压为规模性裂缝的形成提供了外部动力,是大规模储层发育最为关键的因素;不同构造位置裂缝发育程度不同,造成了储层平面分布的非均质性;③ 长期的风化作用使得潜山上部300 m以内的储集物性得到进一步改善,控制了潜山垂向上储层的非均质性.     

四川盆地喜马拉雅期张扭性断裂构造特征及形成机制

前人对四川盆地盆缘冲断带及川中高-磨地区断裂系统进行了系统性研究,但对于盆地其他区块断裂发育特征、形成演化及应力背景的认识尚不充分.发现了梓潼-成都-威远-华蓥山-广安地区震旦系-下三叠统地层中发育的一套区域性张扭性断裂,主要自震旦系及以下地层向上延伸切穿二叠系地层,多为高陡、小断距正断层,部分形成负花状构造.根据该断裂系统的剖面产状、纵向穿层特征及盆地范围内体现出的分异性,推断该断裂系统形成于喜马拉雅期.物理模拟实验研究发现该断裂体系应发育于扭张性应力环境中,该断裂体系的发育指示了四川盆地内部新生代存在南西-北东向张应力,可能与四川盆地新生代发生的逆时针旋转有关.