Re–Os isotope systematics for the Lince–Estefanía deposit: constraints on the timing and source of copper mineralization in a stratabound copper deposit, Coastal Cordillera of Northern Chile

The Lince–Estefanía stratabound copper deposit in the Michilla district is one of the most important deposits in the Coastal Cordillera of northern Chile and is one of the most representative of this type of deposit. Chalcocite and bornite characterize the main stage of hypogene copper sulfide mineralization. Rhenium and osmium isotopes are used here to constrain the age of hypogene mineralization and the source of osmium contained in these ore minerals. A Re–Os isochron yielded an age of 160±16 Ma (2σ), with an associated initial ¹⁸⁷Os/¹⁸⁸Os ratio of 1.06±0.09 (mean square of weighted deviates=1.8). This age is consistent with available geochronological data from volcanic rocks that host the mineralization and associated alteration phases. The high initial ¹⁸⁷Os/¹⁸⁸Os ratio indicates a lower crustal component for the source of Os and, by inference, the Cu sulfides that contain this Os. Late hematite occurs as an isolated phase or, more commonly, is associated with the chalcocite–bornite and supergene chalcocite–covellite associations. Analyses performed on pure hematite indicate a disturbance of the Re–Os system, and hence, this mineral phase is not useful as a Re–Os geochronometer.     

Geology, Wall-rock Alteration and Vein Paragenesis of the Bilimoia Gold Deposit, Kainantu Metallogenic Region, Papua New Guinea

The Bilimoia deposit (2.23 Mt, 24 g/t Au), located in the eastern Central Mobile Belt of mainland Papua New Guinea, is composed of fault‐hosted, NW–NNW‐trending Irumafimpa–Kora and Judd–Upper Kora Au‐quartz veins hosted by Middle–Late Triassic basement that was metamorphosed to medium‐grade greenschist facies between Middle–Late Triassic and Early–Middle Jurassic. Mineralizing fluids were introduced during crustal thickening, rapid uplift, change of plate motions from oblique to orthogonal compression, active faulting and S₃ and S₄ events in an S₁–S₄ deformation sequence. The Bilimoia deposit is spatially and temporally related to I‐type, early intermediate to felsic and late mafic intrusions emplaced in Late Miocene (9–7 Ma). Hydrothermal alteration and associated mineralization is divided into 10 main paragenetic stages: (1) chlorite–epidote‐selvaged quartz–calcite–specularite vein; (2) local quartz–illite–pyrite alteration; (3) quartz–sericite–mariposite–fuchsite–pyrite wall‐rock alteration that delimits the bounding shears; (4) finely banded, colloform‐, crustiform‐ and cockade‐textured and drusy quartz ± early wolframite ± late adularia; (5) hematite; (6) pyrite; (7) quartz ± amethyst‐base metal sulfides; (8) quartz–chalcopyrite–bornite–Sn and Cu sulfides–Au tellurides and Te ± Bi ± Ag ± Cu ± Pb phases; (9) Fe ± Mn carbonates; and (10) supergene overprint. Fluid inclusions in stage 4 are characterized by low salinity (0.9–5.4 wt% NaCl equivalent), aqueous–carbonic fluids with total homogenization temperatures ranging from 210 to 330°C. Some of the inclusions that homogenized between 285 and 330°C host coexisting liquid‐ and vapor‐rich (including carbonic) phases, suggesting phase separation. Fluid inclusions in quartz intergrown with wolframite have low salinity (0.9–1.2 wt% NaCl equivalent), aqueous–carbonic fluids at 240–260°C, defining the latter’s depositional conditions. The ore fluids were derived from oxidized magmatic source initially contaminated by reduced basement rocks. Wall‐rock alteration and involvement of circulating meteoric waters were dominant during the first three stages and early part of stage 4. Stage 5 hematite was deposited as a result of stage 4 phase separation or entrainment of oxygenated groundwater. Gold is associated with Te‐ and Bi‐bearing minerals and mostly precipitated as gold‐tellurides during stage 8. Gold deposition occurred below 350°C due to a change in the sulfidation and oxidation state of the fluids, depressurization and decreasing temperature and activities of sulfur and tellurium. Bisulfides are considered to be the main Au‐transporting complexes. The Bilimoia deposit has affinities that are similar to many gold systems termed epizonal orogenic and intrusion‐related. The current data allow us to classify the Bilimoia deposit as a fault‐controlled, metamorphic‐hosted, intrusion‐related mesothermal to low sulfidation epithermal quartz–Au–Te–Bi vein system.     

Advanced Micro-XRF Method to Separate Sedimentary Rhythms and Event Layers in Sediments: Its Application to Lacustrine Sediment from Lake Suigetsu,Japan

Event-related sedimentary layers, which are deposited occasionally due to volcanic eruptions, earthquakes or heavy rains, are often contained in the rhythmical sequences of lacustrine and marine sediments. We have developed an analytical method for separating the sedimentary rhythms and the event layers identified using the scanning X-ray analytical microscope (SXAM) and obtained sequential profiles of seven elements Al, Si, K, Ca, Ti, Mn, and Fe in the lacustrine sediment from Lake Suigetsu, Japan. Two types of event layers could be detected from the elemental composition of 33 layers of sediment: three known volcanic ash layers and 30 clay layers containing 12 turbidites. The recurrence interval of the latter, which may potentially be initiated and archived by locally important earthquakes, is estimated to be an average of 640 ± 160 years by using Sompi event analysis (SEA) based on an autoregressive (AR) model. After removing those portions that represented event layers from the elemental profiles, we obtained event-removed (ER) temporal profiles based on the tephrochronology of the three volcanic ash layers. The ER temporal profiles of manganese and iron, probably representing the siderite content, showed a millennial-scale variation in the Holocene that corresponded well with ice-rafting events in the North Atlantic.     

Persistence of road runoff generation in a logged catchment in Peninsular Malaysia

Measurements of saturated hydraulic conductivity (K_s) and diagnostic model simulations show that all types of logging road/trail in the 14·4 ha Bukit Tarek Experimental Catchment 3 (BTEC3) generate substantial Horton overland flow (HOF) during most storms, regardless of design and level of trafficking. Near‐surface K_s(0–0·05 m) on the main logging road, skid trails and newly constructed logging terraces was less than 1, 2 and 34 mm h^?1, respectively. Near‐surface K_s on an abandoned skid trail in an adjacent basin was higher (62 mm h^?1), owing to the development of a thin organic‐rich layer on the running surface over the past 40 years. Saturated hydraulic conductivity measured at 0·25 m below the surface of all roads was not different (all <6 mm h^?1) and corresponded to the K_s of the adjacent hillslope subsoil, as most roads were excavated into the regolith more than 0·5–1 m. After 40 years, only limited recovery in near‐surface K_s occurred on the abandoned skid trail. This road generated HOF after the storage capacity of the upper near‐surface layer was exceeded during events larger than about 20 mm. Thus, excavation into low‐K_s substrate had a greater influence on the persistence of surface runoff production than did surface compaction by machinery during construction and subsequent use during logging operations. Overland flow on BTEC3 roads was also augmented by the interception of shallow subsurface flow traveling along the soil–saprolite/bedrock interface and return flow emerging from the cutbank through shallow biogenic pipes. The most feasible strategy for reducing long‐term road‐related impacts in BTEC3 is limiting the depth of excavation and designing a more efficient road network, including minimizing the length and connectivity of roads and skid trails. Copyright © 2007 John Wiley & Sons, Ltd.     

Spectral similarity between scalars at very low frequencies in the unstable atmospheric surface layer over the Tibetan plateau

Similarity between temperature and water vapour was investigated in the Fourier domain by using their coherency spectra, defined as the correlation coefficient between their Fourier modes, and the relative efficiency of their vertical transport. The class-averaged values of these indices were computed from the turbulence measurements over sparse grasslands on the Tibetan plateau during the intensive observations of GEWEX (Global Energy and Water Experiment) Asian Monsoon Experiment (GAME). It was found that the energy-containing eddies at scales up to 100z (z being height) are characterised by well-maintained similarity between these scalars. The scalars are highly correlated with each other, and their transport efficiencies are almost equal within this scale range. In contrast, similarity was not always maintained at scales larger than 1000z. Detailed analyses showed that this breakdown of similarity occurs occasionally or sporadically, suggesting that it is caused by events whose average return period is not much smaller than the current averaging time, i.e. 30 min. We speculate that entrainment of drier and warmer air at the top of the atmospheric boundary layer caused the scalar dissimilarity at this scale range.     

An assessment of uncertainties in VS profiles obtained from microtremor observations in the phased 2018 COSMOS blind trials

Journal of Seismology - Site response is a critical consideration when assessing earthquake hazards. Site characterization is key to understanding site effects as influenced by seismic site...     

Intergranular trace elements in mantle xenoliths from Russian Far East: Example for mantle metasomatism by hydrous melt

Based on both major and trace element chemistry, the occurrence of the intergranular component in mantle-derived xenoliths from far eastern Russia has been constrained. Whole-rock trace element measurements of one xenolith show apparent negative anomalies in Ce, Th, and high field strength elements on normalized trace element patterns. The trace element pattern of the whole rock differs from those of constituent minerals, indicating that the anomalies in the whole rock are attributable to the presence of an intergranular component. That assumption was confirmed using in situ analysis of trace elements in the intergranular substance and melt inclusion using laser ablation inductively coupled plasma–mass spectrometry. Both the intergranular component and the melt inclusions have identical trace element patterns, which mean that these materials are a cognate metasomatizing agent. The anomalies are regarded as mantle metasomatism related to an aqueous fluid. Hydrous minerals were observed on the wall of the melt inclusions using micro-Raman spectroscopy, indicating that the melt inclusions contained a large amount of water. Thus, this study reveals a trace element composition of a hydrous metasomatizing agent in the mantle.     

Stability of the Courses of the Warm Coastal Currents along the Kyushu Island Suggested by the Population Structure of the Japanese Turban Shell, Turbo (Batillus) Cornutus

The genetic structure of a population of the Japanese turban shell, Turbo (Batillus) cornutus at Sata-Misaki Point, on the southern coast of Kyushu Island, was determined on the basis of nucleotide sequences of mitochondrial DNA and compared with that of a population of the western coast of Kyushu Island. The significant genetic differentiation between these two populations suggests that the courses of the warm currents along the coast of the Kyushu Island have been relatively stable after the divergence between the two genetically distant groups of the Japanese turban shell, which was estimated to have occurred during some period in Pleistocene.