Characteristics of phosphate adsorption onto granulated coal ash in seawater

The deterioration of sediments is a serious environmental problem. Controlling nutrient release fluxes from sediments is important to alleviating eutrophication and to reducing terrigenous nutrient loads. The purpose of this study was to evaluate the phosphate removal performance of granulated coal ash (GCA) from seawater, which is produced from coal thermal electric power generation. Batch experiments were carried out to investigate the removal kinetics of phosphate from seawater under both oxic and anoxic conditions. Phosphate was removed well from seawater under both oxic and anoxic conditions. The adsorption isotherm for phosphate revealed that GCA could remove phosphate effectively from seawater above a concentration of 1.7 μmol L⁻¹. GCA can reduce the concentration of phosphate in seawater effectively under anoxic conditions where iron type adsorbents cannot be applied. Therefore, GCA could potentially be used to adsorb phosphate in the organically-enriched sediment, which generally occurs under highly reductive conditions.     

Automated cloud tracking system for the Akatsuki Venus Climate Orbiter data

Japanese Venus Climate Orbiter, Akatsuki, is cruising to approach to Venus again although its first Venus orbital insertion (VOI) has been failed. At present, we focus on the next opportunity of VOI and the following scientific observations.We have constructed an automated cloud tracking system for processing data obtained by Akatsuki in the present study. In this system, correction of the pointing of the satellite is essentially important for improving accuracy of the cloud motion vectors derived using the cloud tracking. Attitude errors of the satellite are reduced by fitting an ellipse to limb of an imaged Venus disk. Next, longitude–latitude distributions of brightness (cloud patterns) are calculated to make it easy to derive the cloud motion vectors. The grid points are distributed at regular intervals in the longitude–latitude coordinate. After applying the solar zenith correction and a highpass filter to the derived longitude–latitude distributions of brightness, the cloud features are tracked using pairs of images. As a result, we obtain cloud motion vectors on longitude–latitude grid points equally spaced. These entire processes are pipelined and automated, and are applied to all data obtained by combinations of cameras and filters onboard Akatsuki. It is shown by several tests that the cloud motion vectors are determined with a sufficient accuracy. We expect that longitude–latitude data sets created by the automated cloud tracking system will contribute to the Venus meteorology.     

Issues of Globalization and Reflexivity in the Japanese Tourism Production System: The Case of Whistler,British Columbia

This article examines contemporary Japanese overseas tourism from a supplier‐side perspective using the concept of production systems. We first outline characteristics of the evolving structure of Japanese overseas tourism, with an emphasis on the global spread of Japanese travel companies. This provides a frame for presenting an empirical account of the transactional relationships in the Japanese package tour production system in Whistler, British Columbia, where Japanese tour operators play a pivotal role. We conclude that the recent expansion of Japanese travel companies is fostering the functional integration of the global tourism production system and exhibits increasing reflexivity.     

Construction and Visualization of a Three Dimensional Geologic Model Using GRASS GIS

The present work aims at introducing a basic theory, implementing methodology and algorithms for 3‐D modeling, and visualizing a geologic model using the Open Source Free GIS GRASS environment. A 3‐D geologic model is constructed from the boundary surfaces of geologic units and the logical model of geologic structure. The algorithms for construction and visualization of the proposed model are based on the geologic function g . The geologic function g assigns a unique geologic unit to every point in the objective 3‐D space. The boundary surface that divides the objective space into two subspaces is estimated using data from field survey. The logical model showing the hierarchical relationship between these boundary surfaces and geologic units can be automatically generated based on the stratigraphic sequence and knowledge of geologic structures. Based on these algorithms, a 3‐D geologic model can be constructed virtually in the GRASS GIS. Applying this model, various geologic surfaces and section models can be visualized in the GRASS GIS environment. “Nviz” was used for dynamic visualization of geologic cross‐sections and generation of animated image sequences. Further, the described algorithms and methods are applied and an online 3‐D geologic modeling system is developed.     

Nonlinear behavior of high-damping rubber bearings under horizontal bidirectional loading: full-scale tests and analytical modeling

Horizontal bidirectional loading tests are conducted for real-sized high-damping rubber (HDR) bearings with diameters of 700 mm (HDR700) and 1300 mm (HDR1300). The hysteresis loops of these bearings under bidirectional horizontal loadings are compared with those under unidirectional loadings. The results show that the bearing force measurement in the primary direction of loading increases when there is displacement in the orthogonal direction. Unusually, the maximum restoring force in the orthogonal direction to the primary loading direction occurs near zero displacement. On the basis of the observations of the restoring forces, a rate-independent model is proposed. This model simulates well the test results under both bidirectional loading and unidirectional loading. It can reproduce the irregular restoring forces characteristics around zero displacement as described above. Bidirectional loading induced twist deformation in the HDR bearings that increased local shear strains. This phenomenon results in an early failure as observed in HDR700. The additional shear strain is estimated based on the twist deformation measured by video image analysis. The comparison of the nominal total shear stress demonstrates that the increase of shear stress because of bidirectional loading occurs when the average shear strain is larger than about 200%. The larger the shear strain, the greater the bidirectional effect. It is shown that the nominal total shear stress of average strain of 350% under bidirectional circular loading pattern is approximately the same as the average shear strain of 400% under unidirectional loading. This means that the average shear strain of 350% under a bidirectional circular loading corresponds to a local shear strain of 400%. Copyright © 2012 John Wiley & Sons, Ltd.     

The chemical composition and nickel,cobalt, copper,zinc and lead contents of Nanao Bay sediments

The contents of major and some of the minor elements, nickel, cobalt, copper, zinc and lead were studied on sediments collected from three inlets of Nanao Bay located at eastern side of Noto Peninsula. Little variation was found on the average contents of silicon, iron, titanium, aluminum, manganese, magnesium and potassium among the sediments of West, South and North Bays in Nanao Bay. Whereas significant difference was found on the contents of calcium, chlorine, sulfur and nitrogen among sediments of three bays.As to the minor elements, the average contents of nickel (20±5 ppm), cobalt (5±1 ppm), copper (18±5 ppm) and lead (17±8 ppm) are relatively low but zinc content is high in these sediments comparing with those of coastal deposit around Japan Island. From the results obtained here, it became clear that no environmental contamination of nickel, cobalt, copper and lead, and a little organic pollution were found in Nanao Bay sediments.     

Mixing of magmatic CO2 into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.     

Amorphous interstellar grains: Wavelength dependence of far-infrared emission efficiency

It is shown theoretically that the emission efficiency of amorphous grains with radii smaller than 100 Å has a _-1-dependence in the wavelength region longer than 100 , whereas those of crystalline, metallic, and larger amorphous grains are proportional to _-2 in far infrared. Astrophysical implications of the amorphous grains are discussed.