Solubility controlled noble gas fractionation during magmatic degassing: Implications for noble gas compositions of primary melts of OIB and MORB

Noble gas abundances in basaltic glasses from ocean islands (OIBs) are generally lower than those of mid-oceanic ridge basalts (MORBs), contrary to most geodynamic models which usually require that the source of OIBs is less degassed (resulting in higher primordial noble gas abundances) and more trace element enriched (resulting in higher radiogenic noble gas abundances) than the MORB source. Therefore, noble gas abundances in OIBs are often thought to have been reduced by extensive gas loss from the magma before eruption.The extent of magmatic degassing can be tested as it will cause characteristic changes in the composition of the volatiles; notably the ⁴He/⁴⁰Ar* ratio (where ⁴⁰Ar* is ⁴⁰Ar corrected for atmospheric contamination) will increase in residual volatiles due to the higher solubility of He relative to Ar. The degree of He-Ar fractionation for a given fraction of gas loss depends on the ratio of the solubilities, S_He/S_Ar, which is sensitive to (among other things) the CO₂ and H₂O content of the basalt at the time of degassing.From a global database of OIB and MORB glasses, we show that ⁴He/⁴⁰Ar* ratios of MORB glasses are broadly consistent with degassing of a magma with an initial ⁴⁰Ar of ≈1.5 × 10⁻⁵ ccSTP/g, i.e., similar to that of the “popping rock.” However, OIB glasses generally have lower ⁴⁰Ar* concentration for a given ⁴He/⁴⁰Ar*. While this would appear to require lower ⁴⁰Ar* abundances in the undegassed OIB magmas, the higher volatile contents of OIBs will reduce S_He/S_Ar (relative to MORBs) during degassing. By modeling S_He/S_Ar in OIBs, it is possible to show that extensive degassing of OIBs can occur without dramatically increasing the ⁴He/⁴⁰Ar* ratio. We show that undegassed ⁴⁰Ar concentrations of OIB magmas were probably similar to those of MORBs.     

Rapid tectonics of the Late Miocene Boso accretionary prism related to the Izu–Bonin arc collision

Abstract   The structure, paleomagnetism and biostratigraphy of the Nishizaki and Kagamigaura formations on the southern Boso Peninsula, central Japan, were investigated to determine the chronographic constraints on the accretion, post-Late Miocene rotation and regional tectonics in the Izu–Bonin island arc collision zone. The geological structures on the southern Boso Peninsula are characterized by an east–west trending and south-verging fold and thrust belt that curves toward the northwest–southeast in the northwest extent of the Nishizaki Formation. Two stages of tectonic rotation were revealed by paleomagnetic and structural studies. The first is believed to have occurred after the accretion of the Nishizaki Formation and before the deposition of the Kagamigaura Formation, while the second is confidently correlated with the 1 Ma Izu block collision. The northwest extent of the Nishizaki Formation was rotated clockwise by approximately 65–80°, whereas the rotation was only 25–30° in the east, and 11–13° in the overlying Kagamigaura Formation. Radiolarian biostratigraphy suggests a depositional age of 9.9–6.8 Ma (Upper Miocene period) for the Nishizaki Formation and 4.19-3.75 Ma (Pliocene period) for the lower Kagamigaura Formation. These results indicate that the age of accretion and first-stage rotation of the Nishizaki Formation can be constrained to the interval of 6.80–3.75 Ma. This structure most likely represents the northward bending caused by collisions of the Tanzawa and Izu blocks with the Honshu island arc, and suggests rapid processes of accretion, collision, uplift and the formation of new sedimentary basins within a relatively short period of time (2.61–3.05 my).     

The rate of fluvial incision during the Late Quaternary period in the Abukuma Mountains, northeast Japan, deduced from tephrochronology

Abstract River incision into bedrock results in the decrease of burial depths, which can be of critical importance, for example, in the safe long‐term storage of high‐level radioactive waste. For the long‐term prediction of river erosion, it is essential to know the rate of incision during the Late Quaternary period. In the Abukuma Mountains on the forearc side of northeast Japan, a low‐relief peneplain that was uplifted in the Pliocene period is widely developed. Degradational fluvial terraces that are discontinuously distributed along draining rivers are scattered in the study area. The fluvial sediments were mainly transported from the summit regions as debris flows or hyperconcentrated flows. The terrace deposits are capped by a series of eolian veneers containing key tephra beds. From the oldest to the youngest, these tephra beds are the 150–125 ka Iizuna–Kamitaru tephra, the 135–125 ka Hiuchigatake–Tagashira tephra, the 120 ka Adatara–Dake tephra, the 70–80 ka Bandai–Hayama‐2 tephra, the 45 ka Numazawa–Mizunuma tephra and the 42 ka Bandai–Hayama‐1 tephra. Using tephrochronological data, the terraces are divided into three groups: higher, middle and lower. The ages of formation of the higher, middle and lower terraces are estimated to be within marine isotope stage (MIS) 6, MIS 5.4–5.2 and MIS 3 to MIS 2, respectively. The incision rate, calculated from the relative height between the terrace surface and present‐day valley floor fill, is 1.5–0.8 m/10 000 years in the elevations from 350 to 700 m. The calculated rate does not show significant differences between the higher, middle and lower terraces. All the relative heights decrease with increasing elevation, because the erosional rates of streams in the upper reaches are lower than those in downstream reaches where the discharge rates are higher. This value can be regarded as an estimate of the rate of incision in granitic mountains where there is no volcanic or distinct tectonic activity.     

High-pressure transformations of ilmenite to perovskite, and lithium niobate to perovskite in zinc germanate

In-situ X-ray powder diffraction measurements conducted under high pressure confirmed the existence of an unquenchable orthorhombic perovskite in ZnGeO₃. ZnGeO₃ ilmenite transformed into perovskite at 30.0 GPa and 1300±150 K in a laser-heated diamond anvil cell. After releasing the pressure, the lithium niobate phase was recovered as a quenched product. The perovskite was also obtained by recompression of the lithium niobate phase at room temperature under a lower pressure than the equilibrium phase boundary of the ilmenite–perovskite transition. Bulk moduli of ilmenite, lithium niobate, and perovskite phases were calculated on the basis of the refined X-ray diffraction data. The structural relations among these phases are considered in terms of the rotation of GeO₆ octahedra. A slight rotation of the octahedra plays an important role for the transition from lithium niobate to perovskite at ambient temperature. On the other hand, high temperature is needed to rearrange GeO₆ octahedra in the ilmenite–perovskite transition. The correlation of quenchability with rotation angle of GeO₆ octahedra for other germanate perovskites is also discussed.     

Lignin and fatty acid records in Lake Baikal sediments over the last 130 kyr: A comparison with pollen records

A 10 m sediment core from Academician Ridge in Lake Baikal was analyzed for its molecular composition using on-line TMAH (tetramethylammomium hydroxide) thermochemolysis. Major products are lignin phenols, n-C₁₄ to C₃₀ fatty acids (alkanoic acids), cutin acids, hydroxy acids and aliphatic dicarboxylic acids. Lignin phenols are abundant in warmer periods (the interglacial: marine isotope stage (MIS) 5e and MIS 1), but extremely low in the other (colder) periods. This result coincides well with pollen records reported for a core near the present site, where an expansion of coniferous forests in sub-stage 5e and MIS 1 was implied. Normal C₂₄–C₃₀ alkanoic acids, important components of plant wax esters, are abundant in 5e and MIS 1 and are present in significant amounts in the other (colder) periods, unlike the lignin phenols. A high abundance of n-C₂₄ to C₃₀ alkanoic acids relative to lignin phenols in the Bølling–Allerød warm period suggests an enhanced development of herbs.It is implied from comparison of the sedimentary lignin phenol record with fossil pollen records and lignin phenol analysis of modern pollen that the ratio of cinnamyl phenols to vanillyl phenols may serve as an indicator of pollen contribution to sedimentary organic matter.     

Estimation or simulation? That is the question

The issue of smoothing in kriging has been addressed either by estimation or simulation. The solution via estimation calls for postprocessing kriging estimates in order to correct the smoothing effect. Stochastic simulation provides equiprobable images presenting no smoothing and reproducing the covariance model. Consequently, these images reproduce both the sample histogram and the sample semivariogram. However, there is still a problem, which is the lack of local accuracy of simulated images. In this paper, a postprocessing algorithm for correcting the smoothing effect of ordinary kriging estimates is compared with sequential Gaussian simulation realizations. Based on samples drawn from exhaustive data sets, the postprocessing algorithm is shown to be superior to any individual simulation realization yet, at the expense of providing one deterministic estimate of the random function.     

Neoproterozoic glaciation in the mid-oceanic realm: An example from hemi-pelagic mudstones on Llanddwyn Island, Anglesey, UK

We report the first occurrence of ice-rafted dropstones in mid-oceanic sediments belonging to an ocean plate stratigraphy within a Neoproterozoic accretionary complex on Llanddwyn Island, Wales, UK. Dropstones of sandstone, chert, and basalt occur as matrix-supported exotic clasts in a 1 m-thick, hemi-pelagic mafic mudstone; the largest clast is 20 × 25 cm across. These dropstones occur specifically in hemi-pelagic mafic mudstone that is located at the structural top of ocean plate stratigraphy that records a ridge-trench transition; they are supplementary to dropstones associated with extensive tillites reported in shallow marine sequences of continental shelf facies and in back-arc basins.     

Expected changes in future agro-climatological conditions in Northeast Thailand and their differences between general circulation models

We have studied future changes in the atmospheric and hydrological environments in Northeast Thailand from the viewpoint of risk assessment of future cultural environments in crop fields. To obtain robust and reliable estimation for future climate, ten general circulation models under three warming scenarios, B1, A1B, and A2, were used in this study. The obtained change trends show that daily maximum air temperature and precipitation will increase by 2.6°C and 4.0%, respectively, whereas soil moisture will decrease by c.a. 1% point in volumetric water content at the end of this century under the A1B scenario. Seasonal contrasts in precipitation will intensify: precipitation increases in the rainy season and precipitation decreases in the dry season. Soil moisture will slightly decrease almost throughout the year. Despite a homogeneous increase in the air temperature over Northeast Thailand, a future decrease in soil water content will show a geographically inhomogeneous distribution: Soil will experience a relative larger decrease in wetness at a shallow depth on the Khorat plateau than in the surrounding mountainous area, reflecting vegetation cover and soil texture. The predicted increase in air temperature is relatively consistent between general circulation models. In contrast, relatively large intermodel differences in precipitation, especially in long-term trends, produce unwanted bias errors in the estimation of other hydrological elements, such as soil moisture and evaporation, and cause uncertainties in projection of the agro-climatological environment. Offline hydrological simulation with a wide precipitation range is one strategy to compensate for such uncertainties and to obtain reliable risk assessment of future cultural conditions in rainfed paddy fields in Northeast Thailand.