Vertical heat transfer based on direct microstructure measurements in the ice-free Pacific-side Arctic Ocean: the role and impact of the Pacific water intrusion

This study quantifies diapycnal mixing and vertical heat transfer in the Pacific side of the Arctic Ocean, where sea-ice cover has disappeared between July and September in the last few decades. We conducted microstructure measurements in the open water region around the Canada Basin from late summer to fall in 2009 and 2010 using R/V Mirai. In the study domain, the dissipation rate of turbulent kinetic energy, ε, is typically as low level as O(10^?10) W kg^?1, resulting in vertical heat diffusivity of O(10^?7) m² s^?1, which is close to the molecular diffusivity of heat, suggesting comparatively little predominance of mechanical turbulent mixing. An exception is the case at the Barrow Canyon, where the strong baroclinic throughflow generates substantial vertical mixing, producing ε > O(10^?7) W kg^?1, because of the shear flow instability. Meanwhile, in the confluence region, where the warm/salty Pacific water and the cold/fresh Arctic basin water encounter, the micro-temperature profiles revealed a localized enhancement in vertical diffusivity of heat, reaching O(10^?5) m² s^?1 or greater. In this region, an intrusion of warm Pacific water creates a horizontally interleaved structure, where the double-diffusive mixing facilitates vertical heat transfer between the intruding Pacific water and the surrounding basin waters.     

Predominant hosting lead(II) in ternary mixtures of heavy metal ions by a novel of diethylaminomethyl-calix[4]resorcinarene

Heavy metal ions from single and ternary systems of Pb(II), Cu(II), and Ni(II) adsorbed by calix[4]resorcinarenes in water–chloroform extraction were studied. Comparison was made of calix[4]resorcinarenes, 2,8,14,20-tetraundecyl calix[4]resorcinarene-4,6,10,12,16,18,22,24-octol, and diethylaminomethyl-calix[4]resorcinarene, 5,11,17,23-tetra(diethylaminomethyl)-2,8,14,20- tetraundecylcalix[4]resorcinarene-4,6,10,12,16,18,22,24-octol, for predominant extraction of their ions from the ternary mixture of aqueous solution at different pH in a water layer. The hosting of Pb(II) by the diethylaminomethyl-calix[4]resorcinarene occurred efficiently at pH 6–7. The hosting of Pb(II), Cu(II), and Ni(II) ions for the ternary aqueous mixture was applied to the Langmuir isotherm. Adsorption was studied using nuclear magnetic resonance spectroscopy in a water–deuterium chloroform extraction system. Results showed that as the heavy metal ions were included into the host cavity, the observation of shifted peaks of water molecules from downfield to higher field was visible in the nuclear magnetic resonance spectra, meaning that water molecules were included with heavy metal ion into the host cavity. The spectra also showed that the diethylamino group expressed formation of the coordination complex between the diethylaminomethyl-calix[4]resorcinarene and Pb(II) for the purpose of predominant hosting of Pb(II).     

Bimodal representation of the tropical intraseasonal oscillation

The tropical intraseasonal oscillation (ISO) shows distinct variability centers and propagation patterns between boreal winter and summer. To accurately represent the state of the ISO at any particular time of a year, a bimodal ISO index was developed. It consists of Madden-Julian Oscillation (MJO) mode with predominant eastward propagation along the equator and Boreal Summer ISO (BSISO) mode with prominent northward propagation and large variability in off-equatorial monsoon trough regions. The spatial–temporal patterns of the MJO and BSISO modes are identified with the extended empirical orthogonal function analysis of 31?years (1979–2009) OLR data for the December–February and June–August period, respectively. The dominant mode of the ISO at any given time can be judged by the proportions of the OLR anomalies projected onto the two modes. The bimodal ISO index provides objective and quantitative measures on the annual and interannual variations of the predominant ISO modes. It is shown that from December to April the MJO mode dominates while from June to October the BSISO mode dominates. May and November are transitional months when the predominant mode changes from one to the other. It is also shown that the fractional variance reconstructed based on the bimodal index is significantly higher than the counterpart reconstructed based on the Wheeler and Hendon’s index. The bimodal ISO index provides a reliable real time monitoring skill, too. The method and results provide critical information in assessing models’ performance to reproduce the ISO and developing further research on predictability of the ISO and are also useful for a variety of scientific and practical purposes.     

Mineralogical and Geochemical Characteristics of the Utanobori Gold Deposit in Northern Hokkaido,Japan

The Utanobori gold deposit is a low‐sulfidation, epithermal vein‐type deposit located in northern Hokkaido, Japan. The deposit is hosted by conglomerate, sandstone, and tuff of the Middle to Late Miocene Esashi Formation. These rocks were hydrothermally altered. Silica sinters and quartz‐adularia veins are common in the deposit. The quartz‐adularia veins either contain a ginguro band, which corresponds to the main gold‐bearing vein (Type 1 Veins), or do not contain a ginguro band but contain minor adularia (Type 2 Veins). Type 1 Veins are divided into three stages with 12–14 substages. Ore minerals identified include electrum, naumannite, chlorargyrite, bromargyrite, an unidentified Fe‐Sb mineral, and an Fe‐(Sb)‐As mineral. These ore minerals formed in the main mineralization stages I (bands I‐b and I‐d) and II (band II‐a). Scanning electron microscopy with cathodoluminescence images show that cathodoluminescence‐dark microcrystalline quartz exhibiting colloform (ghost‐sphere) texture is closely associated with ore minerals in the Type 1 Vein and Type 2 Vein, and the Al and K contents of such quartz are commonly >1000 ppm. This indicates that the ore minerals were crystallized from alkaline, silica‐saturated fluids at temperatures <200°C, which initially deposited amorphous silica that was recrystallized to microcrystalline quartz. The average Au content of electrum is 52.5 at% Au (n = 10), 65.7 at% Au (n = 20), and 55.5 at% Au (n = 5) in bands I‐b, I‐d, and II‐a, respectively, of Type 1 Veins. The δ³⁴S_CDT values of two fine‐grained disseminated pyrites in the altered conglomerate and bedded tuff in the argillic altered zone are ?4.3 and ?4.2‰. Ar‐Ar dating on adularia yielded 13.6 ± 0.06 Ma, 13.6 ± 0.07 Ma, and 13.6 ± 0.06 Ma for the stages I, II, and III of the Type 1 Vein, respectively. K‐Ar ages determined on adularia in the silica sinter and on whole‐rock of glassy rhyolite of the Esashi Formation are 15.0 ± 0.4 Ma and 14.6 ± 0.4 Ma, respectively. These radiometric ages indicate that silica sinter associated with the rhyolitic volcanic rocks formed prior to the main gold mineralization.     

On the Complete System of Integrals in Celestial Mechanics

A partially translative one-parameter continuous transformation group is derived, and used in order to get the system of integrals of celestial mechanics.     

Rare Earth Elements in Hydrothermally Altered Granitic Rocks in the Ranong and Takua Pa Tin‐Field,Southern Thailand

Geochemical studies were conducted on the hydrothermally altered granitic rocks in the Ranong and Takua Pa tin‐fields in southern Thailand in order to investigate the mode of occurrence of REE (rare earth elements), with emphasis placed on a potential REE resource associated with granitic rocks in the Southeast Asian Tin Belt. The total REE (ΣREE) content of altered granitic rocks ranges from 130 to 350 ppm at Haad Son Paen (which is presently mined for kaolin clay) in the Ranong tin‐field, and that of altered granitic rocks and kaolinite veinlets reaches up to 424 ppm and 872 ppm, respectively, at Nok Hook in the Takua Pa tin‐field. Rare earth elements in the altered granitic rocks and kaolinite veinlets show a relatively flat chondrite‐normalized pattern, thus enriched in heavy REE compared with the original granitic rocks and their weathered crusts. At Nok Hook (Takua Pa), the ΣREE content of kaolinite separated from an altered granitic rock by elutriation is 1313 ppm, a ΣREE amount about four times higher than that of whole‐rock composition of the altered granitic rock. Chondrite‐normalized REE patterns of the elutriated kaolinite and of the altered granite are relatively flat. Sequential extraction experiments suggest that 41 and 85 percent of REE are present as ion exchangeable‐form in the altered granitic rock, and in the kaolinite veinlets, respectively. In addition, more than 90% of REE in the kaolinite veinlets are present as the acid‐soluble state. On the other hand, the ΣREE content of kaolinite veinlets and of the kaolinite concentrated by elutriation from an altered granitic rock at Haad Som Paen (Ranong) is 70 ppm and 75 ppm, respectively, thus enrichment of REE in kaolinite was not confirmed. In addition, by the sequential extraction experiments, 23% and 4% of REE were extracted from the altered granitic rock and the kaolinite veinlets at Haad Som Paen. In the altered granitic rocks at Haad Som Paen, REE are present as refractory phases, and REE in the acid‐soluble states had been leached by hydrothermal fluid.