不同上覆水氟浓度对湖泊沉积物氟释放与微生物群落的影响

通过模拟沙湖沉积物-水系统,以沙湖原水氟离子（F^-）浓度为1倍浓度（0.69 mg/L）,设置0.5倍浓度、1倍浓度、1倍浓度灭菌、2倍浓度和4倍浓度共5个实验组,探究不同上覆水F^-浓度背景下沙湖沉积物中F^-的迁移.结果表明,沉积物F^-的释放量随上覆水F^-浓度的增加而呈下降的趋势,其中2倍和4倍浓度组的沉积物由释放F^-转变为吸附F^-.碱性水体有利于沉积物F^-的释放,即随着pH增大,F^-释放量也会增加.微生物的Beta多样性层次聚类分析表明,F^-会抑制Paenisporosarcina与Thiobacillus的相对丰度,但对Fusibacter的生命活动具有促进作用.根据各浓度组间优势菌属相对丰度与环境因子的冗余分析可得,Acinetobacter、Thiobacillus相对丰度与pH呈负相关;Fusibacter相对丰度与F^-浓度呈显著正相关,而Thiobacillus的相对丰度则与F^-表现出弱负相关.通过对各浓度组中重要离子的分析发现,0.5倍组和4倍组中F^-的迁移受Ca²⁺、HCO₃^-和SO₄^2-浓度影响较大;相关性分析表明0.5倍浓度组的Ca²⁺、HCO₃^-浓度与F^-浓度呈极显著正相关,而4倍组中F^-浓度和Ca²⁺、HCO₃^-浓度呈负相关,SO₄^2-浓度和F^-浓度的相关性则是0.5倍组呈负相关,4倍组呈极显著正相关.本文在不同上覆水F^-浓度背景下全面探究了沙湖沉积物中F^-释放和迁移机理,为沙湖及其他含氟地表水的氟污染防治提供理论支持.     

辽宁清河断裂以北新太古代变质表壳岩的发现及其地质意义

通过详实的地质填图,在辽宁开原地区清河断裂以北新发现一套变质表壳岩组合,主要岩性为斜长角闪岩、黑云角闪斜长变粒岩、黑云角闪斜长片麻岩、浅粒岩及角闪石岩的岩石组合,与红透山岩组基本可以对比。岩石地球化学特征表明,其原岩主要为一套中、中基性的火山岩建造,形成于岛弧环境。该套岩石组合普遍发生强烈的构造变形作用,常见构造样式包括透入性片麻理、石香肠构造、变质分异条带、肠状褶皱等一系列的固态流变构造。对该套变质表壳岩组合中的斜长角闪岩进行LA-ICP-MS锆石U-Pb测年,结果表明其形成于(2 524±18)Ma,变质年龄为(2 477±21)Ma,从形成到发生变质相隔约为47Ma。该套变质表壳岩组合的发现,表明了清河断裂以北也曾存在太古宙结晶基底,清河断裂与寇河断裂之间的区域在构造环境上与清原地区一样,均属于新太古代绿岩带。     

呼和浩特—包头盆地震源应力场状态分析

为了分析呼和浩特—包头盆地现今应力场状态,基于内蒙古地震台网记录的地震波形资料,运用振幅比方法获取2000—2016年该盆地及周边M_L≥2.7地震的震源机制解,计算其一致性参数,并反演区域应力场。结果表明,震源机制解特征主要表现为走滑特征,一致性参数空间分布处于低值状态,力轴方位基本与该区的应力场背景特征相符,即主压应力方位为北东、张应力方位为北西。     

Application of data assimilation for improving forecast of water levels and residual currents in Singapore regional waters

Hydrodynamic models are commonly used for predicting water levels and currents in the deep ocean, ocean margins and shelf seas. Their accuracy is typically limited by factors, such as the complexity of the coastal geometry and bathymetry, plus the uncertainty in the flow forcing (deep ocean tide, winds and pressure). In Southeast Asian waters with its strongly hydrodynamic characteristics, the lack of detailed marine observations (bathymetry and tides) for model validation is an additional factor limiting flow representation. This paper deals with the application of ensemble Kalman filter (EnKF)-based data assimilation with the purpose of improving the deterministic model forecast. The efficacy of the EnKF is analysed via a twin experiment conducted with the 2D barotropic Singapore regional model. The results show that the applied data assimilation can improve the forecasts significantly in this complex flow regime.     

塔里木盆地西北缘皮羌辉长岩体的时代讨论

皮羌辉长岩体位于塔里木盆地柯坪断隆西部,皮羌村北约15 km处。该岩体的围岩包括志留系、泥盆系和石炭系—二叠系,新近系不整合覆盖其上。采集该辉长岩样品进行单矿物分离,取分离出的斜长石进行Ar-Ar定年。700～1 400 ℃的8个加热阶段析出的39Ar为总量的95.89％,在坪谱图上得到一个较稳定的坪,坪年龄为265.5±1.2 Ma; 与之相对应的等时线年龄为267.29±5.62 Ma。结合区域地质分析,皮羌辉长岩体的侵入时代为中二叠世早期; 是塔里木二叠纪岩浆活动的一部分。其侵入后基本未受后期构造热事件影响。     

定水头注水引起的含水层水平运动和应变

基于含水层固体颗粒与孔隙水不可压缩的假设 ,本文导出了单井注水情况下泰斯承压含水层水平运动速度与水头之间的基本关系式。然后利用注水井壁处的应力、应变边界条件 ,进一步导出了单井定水头注水引起的泰斯承压含水层水平运动速度、位移和应变解析表达式。该水平位移与应变由两部分组成 :一部分为由注水压力本身引起的经典弹性力学解项 ,它仅随半径而变化 ,与注水时间无关 ;另一部分为由地下水头变化引起的水动力学位移和应变解项。其中 ,含水层水动力学水平位移随时间加长呈指数增长特征 ,水动力学径向应变则表现为近井处拉张、远井处挤压的分区特征 ,且近井拉张区随时间加长逐渐向外扩展。单井注水含水层水动力学水平位移、应变解的导出 ,完善和发展了单孔内压经典弹性平面力学问题解     

Content and distribution of trace metals in surface sediments from the northern Bering Sea, Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06-168.21 mg kg(-1) for Zn, 8.91-46.94 mg kg(-1) for Cr, 2.69-49.39 mg kg(-1) for Cu, 32.46-185.54 mg kg(-1) for V, 0.09-0.92 mg kg(-1) for Cd, and 0.95-15.25 mg kg(-1) for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

淮河流域洪水极值非平稳性特征

基于淮河流域9个水文站的月径流量数据,采用Pettitt非参数检验法、GAMLSS模型与洪水频率分析模型等方法,揭示了淮河中上游洪水频率的演变规律,分析基于平稳性和非平稳性条件下的洪水发生强度及洪涝灾害所带来的影响.研究发现:潢川、横排头和蚌埠站点未发生明显变异,其余6个站点发生均值或方差变异,变异时间主要集中在2000年左右.淮河流域的最优拟合分布函数是Weibull;班台、蒋家集和横排头站适宜于非平稳性模型,其余站点选择平稳性模型.各站点非平稳性条件下10年和20年一遇设计流量值与平稳性条件下皮尔逊Ⅲ型分布设计流量值相差不大,但30年一遇、50年一遇和100年一遇的设计流量相差逐渐变大.横排头站和蚌埠站洪水放大因子随着时间增加呈上升趋势且大于1,百年一遇重现期不足80年.各站点年最大洪峰流量与淮河流域、安徽省水灾面积通过了95%或99%的显著性检验.     

湘江中下游农田土壤和蔬菜的重金属污染

A total of 219 agricultural soil and 48 vegetable samples were collected from the midstream and downstream of the Xiangjiang River（the Hengyang-Changsha section）in Hunan Province.The accumulation characteristics,spatial distribution and potential risk of heavy metals in the agricultural soils and vegetables were depicted.There are higher accumulations of heavy metals such as As,Cd,Cu,Ni,Pb and Zn in agricultural soils,and the contents of Cd（2.44 mg kg^-1 ）,Pb（65.00 mg kg^-1 ）and Zn（144.13 mg kg^-1 ）are 7.97,3.69 and 1.63 times the corresponding background contents in soils of Hunan Province,respectively. 13.2%of As,68.5%of Cd,2.7%of Cu,2.7%of Ni,8.7%of Pb and 15.1%of Zn in soil samples from the investigated sites exceeded the maximum allowable heavy metal contents in the China Environmental Quality Standard for Soils（GB15618-1995,Grade Ⅱ）.The pollution characteristics of multi-metals in soils are mainly due to Cd.The contents of As,Cd,Cu,Pb and Zn in vegetable soils are significantly higher than the contents in paddy soils.95.8%, 68.8%,10.4%and 95.8%of vegetable samples exceeded the Maximum Levels of Contaminants in Foods（GB2762-2005）for As,Cd,Ni and Pb concentrations,respectively.There are significantly positive correlations between the concentrations of Cd,Pb and Zn in vegetables and the concentrations in the corresponding vegetable soils（p〈0.01）.It is very necessary to focus on the potential risk of heavy metals for food safety and human health in agricultural soils and vegetables in the midstream and downstream of the Xiangjiang River,Hunan Province of China.     

近邻景区的联动与溢出效应研究——以黄山、西递、宏村为例

空间邻近性是地理学第一定律,近邻旅游地相互作用定量化研究对丰富旅游地理学理论与实践意义重大.以近邻旅游地黄山、西递和宏村作为案例地,在格兰杰因果分析的基础上,运用当前经济研究中使用极为广泛的DY溢出指数(Diebold&Yilmaz spillover index)分析近邻旅游地的溢出效应.结果表明:宏村和黄山、西递和...