Occurrence of 3-hydroxy acids in microalgae and cyanobacteria and their geochemical significance

3-Hydroxy acids were detected in pure cultured microalgae: Chlorophyta—Chlamydomonas reinhardtii and Chlorella pyrenoidosa and Rhodophyta—Cyanidium caldarium (two strains), and cyanobacteria (Cyanophyta)—Anacystis nidulans, Phormidium foveolarum, Anabaena variabilis and Oscillatoria sp. Normal and branched (iso and anteiso) 3-hydroxy acids in the ranges of C₈-C₂₆ were found in all the samples studied at concentrations ranging from 0.036 to 2.3 and 0.000 to 0.12 mg g^?1 of dry sample, respectively. The major constituents were generally even-carbon numbered normal acids with carbon chain lengths below C₂₀. Microalgae and cyanobacteria may be the important sources of 3-hydroxy acids in natural environments.     

Determination of Selenium in Twenty-Eight Geological Reference Materials by Atomic Absorption Spectrometry

Twenty-eight geological reference samples have been analysed for selenium using atomic absorption spectrometry with hydride generation and quartz cell atomizer and/or with solvent extraction and carbon tube atomizer. Data are presented for 5 CCRMP, 6 USGS, 3 NBS, 6 NIM and 8 GSJ reference materials.     

Determination of Bismuth in Eighty-Three Geochemical Reference Samples by Atomic Absorption Spectrometry

The bismuth content of eighty-three geochemical reference samples has been determined by atomic absorption spectrometry using either a hydride generation and heated quartz cell atomizer or a solvent extraction and carbon tube atomizer. The agreement between the present results and published data is generally good.     

Mineralogy and oxygen isotope systematics of magnetite grains and a magnetite‐dolomite assemblage in hydrated fine‐grained Antarctic micrometeorites

We report the mineralogy and texture of magnetite grains, a magnetite‐dolomite assemblage, and the adjacent mineral phases in five hydrated fine‐grained Antarctic micrometeorites (H‐FgMMs). Additionally, we measured the oxygen isotopic composition of magnetite grains and a magnetite‐dolomite assemblage in these samples. Our mineralogical study shows that the secondary phases identified in H‐FgMMs have similar textures and chemical compositions to those described previously in other primitive solar system materials, such as carbonaceous chondrites. However, the oxygen isotopic compositions of magnetite in H‐FgMMs span a range of ?¹⁷O values from +1.3‰ to +4.2‰, which is intermediate between magnetites measured in carbonaceous and ordinary chondrites (CCs and OCs). The δ¹⁸O values of magnetites in one H‐FgMM have a ~27‰ mass‐dependent spread in a single 100 × 200 μm particle, indicating that there was a localized control of the fluid composition, probably due to a low water‐to‐rock mass ratio. The ?¹⁷O values of magnetite indicate that H‐FgMMs sampled a different aqueous fluid than ordinary and carbonaceous chondrites, implying that the source of H‐FgMMs is probably distinct from the asteroidal source of CCs and OCs. Additionally, we analyzed the oxygen isotopic composition of a magnetite‐dolomite assemblage in one of the H‐FgMMs (sample 03‐36‐46) to investigate the temperature at which these minerals coprecipitated. We have used the oxygen isotope fractionation between the coexisting magnetite and dolomite to infer a precipitation temperature between 160 and 280 °C for this sample. This alteration temperature is ~100–200 °C warmer than that determined from a calcite‐magnetite assemblage from the CR2 chondrite Al Rais, but similar to the estimated temperature of aqueous alteration for unequilibrated OCs, CIs, and CMs. This suggests that the sample 03‐36‐46 could come from a parent body that was large enough to attain temperatures as high as the OCs, CIs, and CMs, which implies an asteroidal origin for this particular H‐FgMM.     

Origin of the metamorphosed clasts in the CV3 carbonaceous chondrite breccias of Graves Nunataks 06101, Vigarano,Roberts Massif 04143, and Yamato‐86009

We observed metamorphosed clasts in the CV3 chondrite breccias Graves Nunataks 06101, Vigarano, Roberts Massif 04143, and Yamato‐86009. These clasts are coarse‐grained polymineralic rocks composed of Ca‐bearing ferroan olivine (Fa_24–40, up to 0.6 wt% CaO), diopside (Fs_7–12Wo_44–50), plagioclase (An_52–75), Cr‐spinel (Cr/[Cr + Al] = 0.4, Fe/[Fe + Mg] = 0.7), sulfide and rare grains of Fe‐Ni metal, phosphate, and Ca‐poor pyroxene (Fs₂₄Wo₄). Most clasts have triple junctions between silicate grains. The rare earth element (REE) abundances are high in diopside (REE ~3.80–13.83 × CI) and plagioclase (Eu ~12.31–14.67 × CI) but are low in olivine (REE ~0.01–1.44 × CI) and spinel (REE ~0.25–0.49 × CI). These REE abundances are different from those of metamorphosed chondrites, primitive achondrites, and achondrites, suggesting that the clasts are not fragments of these meteorites. Similar mineralogical characteristics of the clasts with those in the Mokoia and Yamato‐86009 breccias (Jogo et al. 2012 ) suggest that the clasts observed in this study would also form inside the CV3 chondrite parent body. Thermal modeling suggests that in order to reach the metamorphosed temperatures of the clasts of >800 °C, the clast parent body should have accreted by ~2.5–2.6 Ma after CAIs formation. The consistency of the accretion age of the clast parent body and the CV3 chondrule formation age suggests that the clasts and CV3 chondrites could be originated from the same parent body with a peak temperature of 800–1100 °C. If the body has a peak temperature of >1100 °C, the accretion age of the body becomes older than the CV3 chondrule formation age and multiple CV3 parent bodies are likely.     

The Southern Annular Mode and opposite-phased Basin Mode of the Southern Ocean circulation

Over the Southern Ocean the dominant modes of the atmospheric field are known as the Southern Annular Mode (SAM) or Antarctic Oscillation, and the Pacific South American (PSA) pattern. Statistical analysis of sea surface wind (SSW) from satellite observation revealed two leading modes of SAM-like and PSA patterns. In the high latitudes, the SAM-like pattern of the SSW had a large amplitude over the Bellingshausen Basin and Australian-Antarctic Basin, with opposite phase between the two basins. On the intraseasonal time scale, large-scale sea surface height (SSH) also had notable variability, showing a basin-scale anti-phase mode over the two basins. To explain the response of oceanic variations to these atmospheric modes, we analyzed the relationship between the dominant modes of wind stress and large-scale SSH on the intraseasonal time scale. The SAM-like pattern of wind stress was correlated with the SSH variation over the two basins. The SSH basin mode was most simply explained by a simple barotropic response to the SAM-like mode of wind stress, with the curl of opposite phase between the two basins. We conclude that the zonal asymmetry of the wind field of the SAM plays an important role in driving the antiphase SSH basin modes.     

Northwest Africa 8418: The first CV4 chondrite

Northwest Africa (NWA) 8418 is an unusual chondrite whose properties do not exactly match those of any other known chondrite. It has similarities to the CV (Vigarano group), CK (Karoonda group), and CL (Loongana group) chondrites, but its abundance of large calcium-aluminum-rich inclusions (CAIs) and the low NiO content (<0.2 wt%) of its matrix olivine ally it most closely with the CV group. The absence of grossular, monticellite, wollastonite, and sodalite from the alteration products of the CAIs; the magnesium-rich nature of the matrix olivines (Fa₃₈) relative to that of the CV3 chondrites (~Fa₅₀); and the presence of secondary Na-bearing plagioclase and chlorapatite indicate a metamorphic temperature >600 °C. NWA 8418 contains kamacite, taenite, and troilite, and lacks magnetite and pentlandite. We propose that NWA 8418 be reclassified as a reduced CV4 chondrite, which makes it the first CV chondrite of petrologic type 4.     

Holocene East Asian monsoon variation inferred from species assemblage and shell chemistry of the ostracodes from Hulun Lake, Inner Mongolia

A sediment core from Hulun Lake, Inner Mongolia was analyzed for species assemblages and shell chemistry of ostracodes to investigate changes in the hydrology and climate of the East Asian summer monsoon margin during the Holocene. Darwinula stevensoni was abundant, Ilyocypris spp. scarce, littoral ostracodes absent and Mg/Ca, Sr/Ca and δ¹⁸O were low 11,100 to 8300 yr ago, indicating high lake levels and cool/fresh waters. Darwinula stevensoni declined largely, Ilyocypris spp. throve, littoral ostracodes were rare and chemical indicators remained in low values 8300 to 6200 yr ago, suggesting that the lake continued high stands but water became warm. The lake then contracted and water became cool/brackish 6200 to 4300 yr ago. Littoral ostracodes flourished 4300 to 3350 yr ago, marking the lowest lake levels of the entire Holocene. The lake level recovered and water salinity decreased 3350 to 1900 yr ago. From 1900 to 500 yr ago, the lake maintained the preceding status albeit lowered stands and increased salinities 1100 to 800 yr ago. During the recent 500 yr, the lake expanded and water salinity decreased. The data imply that the East Asian summer monsoon did not intensify until 8300 yr ago and weakened dramatically 4300 to 3350 yr ago.     

Galactic cosmic-ray anisotropy and its heliospheric modulation, inferred from the sidereal semidiurnal variations observed in the rigidity range 300–600 GV with multidirectional muon telescope at Sakashita underground station

The existence of sidereal semidiurnal variation of cosmic-ray intensity in a rigidity region 10²-10³ GV has been reported by many researchers, but there is no consensus of opinion on its origin. In this paper, using the observed semidiurnal variations in a rigidity range (300–600 GV) with 10 directional muon telescopes at Sakashita underground station (geog. lat. = 36°, long. = 138°E, DEPTH = 80 m.w.e.), the authors determine the magnitudes (η₁, η₂) and directions (a₁, a₂) of the first- and second-order anisotropies in the following galactic cosmic-ray intensity distribution (j)

jdp = j₀{1 + η₁P₁(cos χ₁) + η₂P₂(cos χ₂)}dp

, where P_nis the nth order spherical function and χ_n is the pitch angle of cosmic rays with respect to a_n. For the determination, the influence of cosmic-ray's heliomagnetospheric modulation, geomagnetic deflection and nuclear interaction with the terrestrial material and also of the geometric configuration of the telescopes are taken into account. Usually, the semidiurnal variation is produced by the second-order anisotropy. The present observation, however, requires also the first-order anisotropy which usually produces only the diurnal variation, but can produce also the semidiurnal variation as a result of the heliospheric modulation. The first- and second-order anisotropies are characterized with η₁) > 0 and η₂ < 0 have almost the same direction (a₁ a₂) specified by the right ascension ( 0.75 h) and declination (δ 50°S) and, therefore, they can be expressed, as a whole, by an axis-symmetric anisotropy of loss-cone type (i.e. deficit intensities in a cone). It is noteworthy that this anisotropy approximately coincides with that inferred from the air shower observation at Mt Norikura in the rigidity region 10⁴ GV.