长江口外海域三维水动力模拟结果及与观测的比较

Base on ECOMSED model, a theree-dimensional hydrodynamic model is developed in the offshore area near the Changjing Estuary in the East China Sea. This model in driven by tide and wind,as well as inflow and outflowcurrents such as Kuroshio,Changjing runoff. The horizontal resolution is 1/20_°. There have 11 layers on the verticaldirection. The numerical results of 4 main constituents of tide(M²,S²,K¹,O¹)and currents are in good agreement with observation data. Compared with 20 gauge stations,the mean absolute erroe between the caluclated M² tidal amplitude and the observed oned is only 6.72cm; the mean absolute error of phased-lag is 5.23_°.For S²,the mean absolute errors of amplitude and phased-lag are 3.67cm and 7.21_°,respectively. The mean absolute errors of amplitude and phased-lag for K¹ are 3.25cm and 6.63_° For O¹,the mean absolute error of calculation and observation is relatively small, amwith observation data measured during Aug., 2006 in the East China Sea.The correlation coeffiients of current between simulation and observation are greater than 0.75 generally. The three-dimensional hydrodynamic model develiped by this paper can well describe the characters of elevation and current in the offshore near the Changjiang Estuary and can be used as hydrodynamic background to simulate the suspend sediment transport in this sea area.     

Modelling hydrological processes influenced by soil,rock and vegetation in a small karst basin of southwest China

Hydrological processes in karst basins are controlled by permeable multimedia, consisting of soil pores, epikarst fractures, and underground conduits. Distributed modelling of hydrological dynamics in such heterogeneous hydrogeological conditions is a challenging task. Basing on the multilayer structure of the distributed hydrology‐soil‐vegetation model (DHSVM), a distributed hydrological model for a karst basin was developed by integrating mathematical routings of porous Darcy flow, fissure flow and underground channel flow. Specifically, infiltration and saturated flow movement within epikarst fractures are expressed by the ‘cubic law’ equation which is associated with fractural width, direction, and spacing. A small karst basin located in Guizhou province of southwest China was selected for this hydrological simulation. The model parameters were determined on the basis of field measurement and calibrated against the observed soil moisture contents, vegetation interception, surface runoff, and underground flow discharges from the basin outlet. The results show that due to high permeability of the epikarst zone, a significant amount of surface runoff is only generated after heavy rainfall events during the wet season. Rock exposure and the epikarst zone significantly increase flood discharge and decrease evapotranspiration (ET) loss; the peak flood discharge is directly proportional to the size of the aperture. Distribution of soil moisture content (SMC) primarily depends on topographic variations just after a heavy rainfall, while SMC and actual ET are dominated by land cover after a period of consecutive non‐rainfall days. The new model was able to capture the sharp increase and decrease of the underground streamflow hydrograph, and as such can be used to investigate hydrological effects in such rock features and land covers. Copyright © 2011 John Wiley & Sons, Ltd.     

成都市城市热岛特征初探

本文利用1986年夏季、1987年冬季市区观测资料和郊区气象站气候资料,分析了成都市热岛特征、热岛强度随时间的变化及绿化对城市小气候的影响。     

Relationship between structures of substituted indolic compounds and their degradation by marine anaerobic microorganisms

Degradation of selected indolic compounds including indole, 1-methylindole, 2-methylindole, and 3-methylindole was assessed under methanogenic and sulfate-reducing conditions using the serum-bottle anaerobic technique and marine sediment from Victoria Harbour, Hong Kong as an inoculum. Our results showed that indole degradation was achieved in 28 days by a methanogenic consortium and 35 days by a sulfate-reducing consortium. During degradation under both conditions, two intermediates were isolated, purified and identified as oxindole and isatin (indole-2,3-dione) suggesting that both methanogenic and sulfate-reducing bacteria use an identical degradation pathway. Degradation processes followed two steps of oxidation accomplished by hydroxylation and then dehydrogenation at 2- and then 3-position sequentially prior to the cleavage of the pyrrole ring between 2- and 3-positions. However, none of 1-methylindole or 2-methylindole was degraded under any conditions. 3-Methylindole (3-methyl-1H-indole, skatole) was transformed under methanogenic conditions and mineralized only under sulfate-reducing conditions. It is clear that methyl substitution on 1- or 2-position inhibits the initial attack by hydroxylation enzymes making them more persistent in the environment and posing longer toxic impact.     

太阳系尘埃等离子体研究

综述了太阳系尘埃等离子体中的充电机制和波动过程以及与之有关的若干空间物理现象,内容包括太阳系等离子体中尘埃表面的平衡电势,带电尘埃在空间环境中的受力与运动,行星环内沿的弥漫扩散,轮辐结构的成困,彗星环境中尘埃的静电爆裂,尘埃彗尾的形态演化,天王星窄环的稳定性等问题．     

用GPS位移资料计算应变方法的讨论

目前使用相同或类似的GPS资料求应变,不同研究者给出的结果会有显著差别。为此,对用GPS位移(或速度)资料计算应变(或应变速率)的方法进行了研讨。分析后认为,应变计算可以归结成两大类第一类是利用测点附近资料直接求微分或微分的加权平均值的直接计算法;第二类是用解析曲线拟合观测的位移,然后根据该曲线提供的总的趋势求测点的微分值的位移拟合法,这类方法在拟合中又可以分成整体拟合和分片拟合两种。应变计算应该在球面坐标系下进行,根据研究对象和要求,选择适当的方法。     

Long-term monitoring of the individual self-feeding behavior of rainbow trout Oncorhynchus mykiss

Self-feeding device is extensively used in aquaculture farms, but for salmonids the individual feeding behavior has seldom been continuously observed. In this article, the individual self-feeding behavior of 10 rainbow trout was continuously monitored with a PIT tag record for 50 days with three replicates. The fish fell into three categories according to their feeding behavior, i.e. high triggering fish (trigger behavior more than 25% of the group, HT), low triggering fish (1%–25%, LT) and zero triggering fish (less than 1%). The results showed that in a group of 10 individual 1–2 HT fish accounted for most of the self-feeding behavior (78.19%–89.14%), which was far more than they could consume. The trigger frequency of the fish was significantly correlated with the initial body weight (P <0.01), however, no significant difference in growth rate among the HT, LT, and ZT fish was observed (P >0.05). Cosinor analysis showed that the two HT fish in the same group had similar acrophase. Though some of the HT fish could be active for 50 d, there were also HT fish decreased triggering behavior around 40 d and the high trigger status was then replaced by other fish, which was first discovered in salimonds. Interestingly, the growth of the group was not affected by the alternation triggering fish. These results provide evidence that in the self-feeding system the HT fish didn’t gain much advantage by their frequent self-feeding behavior, and high trigger status of the HT fish is not only an individual character but also driven by the demand of the group. In the self-feeding system, the critical individual should be closely monitored.

     

The suitability of using leaf area index to quantify soil loss under vegetation cover

Soil erosion by water under forest cover is a serious problem in southern China. A comparative study was carried out on the use of leaf area index (LAI) and vegetation fractional coverage (VFC) in quantifying soil loss under vegetation cover. Five types of vegetation with varied LAI and VFC under field conditions were exposed to two rainfall rates (40 mm h⁻¹ and 54 mm h⁻¹) using a portable rainfall simulator. Runoff rate, sediment concentration and soil loss rate were measured at relatively runoff stable state. Significant negative exponential relationship (p < 0.05, R² = 0.83) and linear relationship (p < 0.05, R² = 0.84) were obtained between LAI and sediment concentration, while no significant relationship existed between VFC and sediment concentration. The mechanism by which vegetation canopy prevents soil loss was by reducing rainfall kinetic energy and sediment concentration. LAI could better quantify such a role than VFC. However, neither LAI nor VFC could explain runoff rate or soil loss rate. Caution must be taken when using LAI to quantify the role of certain vegetation in soil and water conservation.     

Synthesis and protein tyrosine phosphatase 1B inhibition activities of two new synthetic bromophenols and their methoxy derivatives

3-bromo-4,5-bis(2,3-dibromo-4,5-dihydroxybenzyl)-1,2-benzenediol (1) is a natural bromophenol isolated from the red algae Rhodomela confervoides that exhibits significant inhibition against protein tyrosine phosphatase 1B (PTP1B). Based on its activity, we synthesized two new synthetic bromophenols and their methoxy derivatives from vanillin using the structure of natural bromophenol 1 as a scaffold. The structures of these bromophenols were elucidated from 1H NMR, 13C NMR, and high resolution electron ionization mass spectrometry as 2,3-dibromo-1-(2p-bromo-6p-(3q,4q-dimethoxybenzyl)- 3p,4p-dimethoxybenzyl)-4,5-dimethoxybenzene(2),2,3-dibromo-1-(2p-bromo-6p-(2q-bromo-4q,5q-dimethoxy-benzyl)-3p,4p-dimethoxybenzyl)-4,5-dimethoxybenzene(3),3,4-dibromo-5-(2p-bromo-6p-(2q-bromo-4q,5q-dihydroxybenzyl)-3p,4p-dihydroxybenzyl)pyrocatechol(4)and 3,4-dibromo-5-(2p-bromo-6p-(3q,4q-dihydroxybenzyl)-3p,4p-dihydroxybenzyl)pyrocatechol (5).PTP1B inhibition activities of these compounds were evaluated using a colorimetric assay,and compounds 3 and 4 demonstrated interesting activity against PTP1B.     

Properties and organic activation of ocean clay in the East Pacific

In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5% (volume) of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.