利用北冰洋多光谱数据计算光合有效辐射的研究

光合有效辐射（PAR）是重要的生物光学量,与海洋浮游植物的初级生产过程有密切联系。PAR通常由单波段的PAR传感器直接测量,也可以由多光谱数据计算。在极区用多光谱数据计算PAR不仅面对不同谱宽度的问题,而且还有海冰的影响。本文研究了4种可能导致PAR计算误差的主要因素。多光谱仪器避开了大气对太阳辐射的主要吸收带,用多光谱数据计算会对PAR高估。实测数据分析表明多光谱计算的PAR与高光谱数据的计算结果非常接近,误差在1%以内。用本文建立的拟合函数进行校正,校正后的结果与高光谱数据计算的结果达到同样的精度。计算PAR的衰减率要用到进入海水表面的PAR（PAR0）,本文提出先确定表层衰减系数,再通过最小二乘拟合确定PAR0值,与水下观测数据有很好的衔接。海上同一站位不同时间的观测数据计算的PAR衰减系数相差很小,表明PAR的衰减系数是海水的光学性质,与辐射强度无关。在海冰覆盖的条件下,PAR的观测结果与无冰海水的PAR有明显差别。由于海冰选择性的吸收,穿透海冰进入海洋的PAR组分已经不同,海水对PAR的衰减系数也会相应变化。由此可以推断,不同海冰中成分的差别将导致进入海水中PAR的差别,影响PAR的衰减特性。通过本文的研究,解决了在极区用多光谱计算PAR的各种问题,使多光谱数据成为PAR的重要数据源。     

SEDIMENT RETENTION AND WATER QUALITY ENHANCEMENT IN DISTURBED WATERSHEDS

lPRoBLEMSTATEMENTANDOVERVIEWQualitywateriswithoutdoubtalimitingsubstance,notonlyforhumansbutforalllife.Yet,ashumanpopulation,activity,andpollutioncontinuetoincrease,naturalsourcesofreadilyuseablewateraredecliningatanalarmingfate.Humanscurrentlydiveftorregulatemorethanhalfofgloballyavailablefreshwaterrunofffortheirownpurposes(Posteletal.,l996),includingtheuseoflargedamsordiversionsonriversandthewidespreadcreationofotherartificialcatchments.Additionally,groundwatersourcesarebecomingin…     

The association of potassic trachytes and carbonatites at the Dicker Willem Complex, southwest Namibia: coexisting, immiscible, but not cogenetic magmas

The only significant silicate intrusive rock type in the Dicker Willem carbonatite complex is trachyte, forming, in places, an anastomosing array of minor intrusions cutting basement gneiss close to the carbonatite contact. Bodies are predominantly composite breccias, composed of trachyte clasts, commonly in the form of ellipsoidal pellets, enclosed within, and sharply delineated from, a matrix of carbonatite. Despite close temporal and spatial relationships to carbonatite magmatism, the ultrapotassic, quartz-normative composition and isotope systematics of the trachytes preclude any genetic derivation from the carbonatitic and ijolitic rocks of the central complex. Sr, Nd and Pb isotope ratios of trachytes strongly resemble those of the highest grade, potassic fenites, whose metasomatic trend converges from the unaltered basement gneiss towards the homogeneous signature of the nepheline sövite–sövite–ijolite suite. Trachytes are interpreted as forming by melting of a cupola of high-grade fenite in response to the advective heat flux from rising carbonatite magma or fluid. Mixed carbonatite and trachyte were emplaced in a fluidised system as contemporaneous, but genetically unrelated, immiscible magmas.     

Ecosystem dynamics of the Pacific-influenced Northern Bering and Chukchi Seas in the Amerasian Arctic

The shallow continental shelves and slope of the Amerasian Arctic are strongly influenced by nutrient-rich Pacific waters advected over the shelves from the northern Bering Sea into the Arctic Ocean. These high-latitude shelf systems are highly productive both as the ice melts and during the open-water period. The duration and extent of seasonal sea ice, seawater temperature and water mass structure are critical controls on water column production, organic carbon cycling and pelagic–benthic coupling. Short food chains and shallow depths are characteristic of high productivity areas in this region, so changes in lower trophic levels can impact higher trophic organisms rapidly, including pelagic- and benthic-feeding marine mammals and seabirds. Subsistence harvesting of many of these animals is locally important for human consumption. The vulnerability of the ecosystem to environmental change is thought to be high, particularly as sea ice extent declines and seawater warms. In this review, we focus on ecosystem dynamics in the northern Bering and Chukchi Seas, with a more limited discussion of the adjoining Pacific-influenced eastern section of the East Siberian Sea and the western section of the Beaufort Sea. Both primary and secondary production are enhanced in specific regions that we discuss here, with the northern Bering and Chukchi Seas sustaining some of the highest water column production and benthic faunal soft-bottom biomass in the world ocean. In addition, these organic carbon-rich Pacific waters are periodically advected into low productivity regions of the nearshore northern Bering, Chukchi and Beaufort Seas off Alaska and sometimes into the East Siberian Sea, all of which have lower productivity on an annual basis. Thus, these near shore areas are intimately tied to nutrients and advected particulate organic carbon from the Pacific influenced Bering Shelf-Anadyr water. Given the short food chains and dependence of many apex predators on sea ice, recent reductions in sea ice in the Pacific-influenced sector of the Arctic have the potential to cause an ecosystem reorganization that may alter this benthic-oriented system to one more dominated by pelagic processes.     

Characterization of dissolved organic matter fluorescence in the South Atlantic Bight with use of PARAFAC model: Interannual variability

Systematic water sampling for characterization of chromophoric dissolved organic matter (CDOM) in the coastal South Atlantic Bight, was conducted as part of the long term Coastal Ocean Research and Monitoring Program (CORMP). Water samples were collected during a 3.5 year period, from October 2001 until March 2005, in the vicinity of the Cape Fear River (CFR) outlet and in adjacent Onslow Bay (OB). During this study there were two divergent hydrological and meteorological conditions in the CFR drainage area: a severe drought in 2002, followed by the very wet year of 2003. CDOM was characterized optically by the absorption coefficient at 350 nm, the spectral slope coefficient (S), and by Excitation Emission Matrix (EEM) fluorescence. Parallel Factor Analysis (PARAFAC) was used to assess CDOM composition from EEM spectra and six components were identified: three terrestrial humic-like components, one marine humic-like component and two protein-like components. Terrestrial humic-like components contributed most to dissolved organic matter (DOM) fluorescence in the low salinity plume of the CFR. The contribution of terrestrial humic-like components to DOM fluorescence in OB was much smaller than in the CFR plume area. Protein-like components contributed significantly to DOM fluorescence in the coastal ocean of OB and they dominated DOM fluorescence in the Gulf Stream waters. Hydrological conditions during the observation period significantly impacted both concentration and composition of CDOM found in the estuary and coastal ocean. In the CFR plume, there was an order of magnitude difference in CDOM absorption and fluorescence intensity between samples collected during the drought compared to the wet period. During the drought, CDOM in the CFR plume was composed of equal proportions of terrestrial humic-like components (ca. 60% of the total fluorescence intensity) with a significant contribution of proteinaceous substances (ca. 20% of the total fluorescence). During high river flow, CDOM was composed mostly of humic substances (nearly 75% of total fluorescence) with minor contributions by proteinaceous substances. The impact of changes in fresh water discharge patterns on CDOM concentration and composition was also observed in OB, though to a lesser degree.     

Geochronology of Precambrian granites and associated U-Ti-Th mineralization,northern Olary province,South Australia

Proterozoic granitoids and metamorphic rocks in the Olary province of the Willyama block of South Australia host ore-grade amounts of U-Th-Ti and U-Fe-Ti-Th minerals. U-Pb-Th isotope analyses on zircons from all granitoids associated with the Crocker Well brannerite deposit indicate that these granitoids were intruded within a short time span, close to the 1579.2±1.5 m.y. age of the brannerite-bearing host-rock. Though the early Paleozoic Delamerian orogeny was intense in this region, the zircon isotopic systems remained unaffected; rather, the best-defined zircon chords on concordia plots show a welldefined lower intercept of 43.8±6.5 Ma, which can only be associated with early Tertiary block faulting. Pb-U-Th isotope analyses on brannerite from the Crocker Well deposit and davidite from the Mt. Victoria deposit and the Radium Hill deposit yield badly scattered and discordant apparent ages that suggest a primary age at least as old as the age of the Crocker Well granitoids, followed by a severe disturbance in the early Paleozoic.     

Lead isotopes in island arcs

New lead isotope data for calc-alkaline volcanic rocks from New Zealand and the Lesser Antilles, combined with published data for Japan and the Andes, show that the spread of isotopic composition in each volcanic arc region is small (2–4% range in Pb206/Pb204) compared to the range of values observed (8%). Pb207 and Pb206 increase systematically from Japan to the Andes to New Zealand to the Caribbean. Likewise Pb208 and Pb206 are positively correlated, but there is evidence of long term (10⁸ m.y.) differences of Th/U between the regions studied. The apparent U/Pb ratios of Peruvian, New Zealand and Caribbean calc-alkaline volcanics do not differ greatly from the apparent ratio for the single stage growth curve for stratiform Pb ores. In contrast the apparent U/Pb ratios for Japanese calc-alkaline volcanics are distinctly lower. Although the Japanese Pb has model ages near zero, the other volcanic arcs have negative (future) model ages, the Caribbean samples being most extreme in this respect. Published oceanic volcanic and sediment lead isotopic composition data and the new results are consistent with a model of volcanic arc evolution in which oceanic sediments are dragged into the mantle, mixed to some degree with mantle material, and partially melted to form calc-alkaline magmas. Either constant continental volume or continental growth are compatible with this process. The mixing of two separate « frequently mixed » leads is the minimum complexity required to explain volcanic are leads. Mathematically there are probably no single-stage leads but isotopic homogenization during earth history has caused lead isotopes to closely approximate a single stage growth. The use of lead isotopic composition as a « tracer » suggests that mantle — crust geochemical evolution involves an exchange of material and is not simply a one-way process. The Pb isotopic composition of the Auckland, New Zealand alkali basalts is apparently the result of incomplete mixing of two leads to give a linear array of Pb207/Pb204-Pb206/Pb204 data with negative slope.     

Modeling the risk of robbery in the city of Tshwane,South Africa

ABSTRACT

In this study, we model the risk of robbery in the City of Tshwane in South Africa. We use the collective knowledge of two prominent spatial theories of crime (social disorganization theory, and crime pattern theory) to guide the selection of data and employ rudimentary geospatial techniques to create a crude model that identifies the risk of future robbery incidents in the city. The model is validated using actual robbery incidences recorded for the city. Overall the model performs reasonably well with approximately 70% of future robbery incidences accurately identified within a small subset of the overall model. Developing countries such as South Africa are in dire need of crime risk intensity models that are simple, and not data intensive to allocate scarce crime prevention resources in a more optimal fashion. It is anticipated that this model is a first step in this regard.     

Pilot study using SPOT satellite imagery over Apalachicola national forest to determine appropriate spatial scale for area-wide aggregation of surface fluxes

Summary High resolution radiances from SPOT satellite imagery converted to Normalized Difference Vegetation Indices (NDVI) over a 16×16 km² mixed ground cover study-area in the Apalachicola National Forest in northwest Florida, along with in situ measurements from a Bowen ratio surface flux monitoring system and physical modeling techniques, are used to determine the length manifold beyond which degraded resolution satellite imagery fails to capture flux variability over the scene. The investigation is relevant to an understanding of how bias error is generated in methods designed to produce scale-invariant surface flux estimates from satellite measurements. Error estimates are based on assigning characteristic NDVI values to the four predominant types of ground cover found within the study-area. An open site near the center of the study-area, which satisfies the conditions for surface flux monitoring, is used for obtaining input data for a biosphere-atmosphere exchange model designed to calculate representative fluxes for the different ground covers. Continuous 6-minute meteorological and surface flux measurements were made at the monitoring site for a period of 22 days. These measurements are used in conjunction with surface layer theory to provide surface layer profile estimates of wind speed, temperature, and relative humidity at the tops of the forested sites. The measured and derived meteorological parameters, together with representative biophysical parameters, are used as input to the biosphere-atmosphere exchange model. By representing sensible and latent heat flux distributions due to the variable ground cover with characteristic NDVI values at 20-m resolution, baseline area-wide sensible and latent heat flux quantities are calculated. Error-growth curves as a function of spatial resolution for the fluxes are found by degrading the resolution of the SPOT radiances used to calculate NDVI, and rationing the associated area-wide fluxes to the baseline values. The point at which an error-growth curve becomes invariant represents the edge of a length manifold beyond which the satellite input no longer contains information on surface flux variability, even though NDVI variability continues at all scales up to that of the complete SPOT scene. The error-growth curves are non-linear, with all the error build-up taking place between 20 m and 1.6 km. Decreasing the spatial resolution of the NDVI information down to or below 1.6 km, introduces bias errors in the area-wide surface flux estimates of 10% for sensible heat and 8% for latent heat. The underlying assumptions and modeling produce uncertainty in estimating the manifold limits, however, the principal objective is to show that in using satellite data for scale-invariant surface flux retrieval, there is an optimal spatial resolution factor that can be objectively quantified.With 10 Figures     

Estimation of hydroxyl radical concentrations in the marine atmospheric boundary layer using a reactive atmospheric tracer

Hydroxyl radical (OH) concentrations in the atmospheric boundary layer over a number of remote ocean locations are calculated from the measured diurnal variation in atmospheric dimethylsulfide (DMS). By using averaged DMS data sets from extended periods, the calculation yields OH concentrations averaged over periods from several days to weeks. These average OH concentrations range from 7×10⁵ to 2.9×10⁶ molecules cm^-3, corresponding to midday maxima of 3 to 12×10⁶ molecules cm^-3. The lowest values correspond to studies with the lowest light intensity (Antarctic summer and South Atlantic winter), and the highest values to regions with probable anthropogenic influence. In addition to the long term averages, daily average OH levels can be calculated for most days in a two week period from a cruise in the tropical eastern Pacific. These calculations are in good argeement with global average OH levels derived from other tracers, and are consistent with model OH calculations when allowance is made for variation in ambient ozone levels between the studies. Estimates of gas exchange made from the diurnal variation of DMS suggest that either the gas exchange coefficient of DMS or the boundary layer mixing depth may have been overestimated in past analyses.