Calculation of photosynthetically available radiation using multispectral data in the Arctic

Photosynthetically Available Radiation(PAR) is an important bio-optical parameter related to marine primary production.PAR is usually measured by a broadband sensor and can also be calculated by multispectral data.When the PAR is calculated by multispectral data in polar region,four factors are possible error sources.PAR could be overestimated as the wavelengths of multispectral instrument are usually chosen to evade main absorption zones of atmosphere. However,both PARs calculated by hyperspectral and m...     

Examining the physical components of boundary shear stress for water‐worked gravel deposits

It is argued in this commentary that, in order to understand better the physical mechanisms that generate boundary shear stress over water‐worked gravel beds, flow velocity data should be re‐evaluated by spatial averaging the Reynolds equations to produce time‐ and space‐averaged (double‐averaged) momentum equations. A series of laboratory experiments were conducted in which the flow velocities were measured using a PIV system over two water‐worked gravel deposits. Combined with detailed data on the bed surface topography and vertical porosity, the physical components of shear stress were obtained. This enabled the various momentum transfer mechanisms present above, within and at the interface of a porous, fluvial deposit, to be quantified. This included the examination of the relevant contributions of temporal and spatial fluctuations in velocity and surface drag to the overall momentum transfer. It is demonstrated that double‐averaging represents a logical framework for assessing the fluid forces responsible for sediment entrainment and for investigating intragravel flow and sediment–water interface exchange mechanisms within the roughness layer in water‐worked gravel deposits. By considering the physical components of shear stress and their relative sizes it was possible to provide a physically based explanation for existing observations of enhanced mobility of gravel–sand mixtures and the transfer of solutes into porous, gravel deposits. This analysis reveals the importance of obtaining co‐located, high quality spatial data on the flow field and bed surface topography in order to gain a physical understanding of the mechanisms which generate boundary shear stress. Copyright © 2010 John Wiley & Sons, Ltd.     

Cold-season soil respiration in response to grazing and warming in High-Arctic Svalbard

The influence of goose grazing intensity and open-topped chambers (OTCs) on near-surface quantities and qualities of soil organic carbon (SOC) was evaluated in wet and mesic ecosystems in Svalbard. This study followed up a field experiment carried out in 2003–05 (part of the project Fragility of Arctic Goose Habitat: Impacts of Land Use, Conservation and Elevated Temperatures). New measurements of soil CO₂ effluxes, temperatures and water contents were regularly made from July to November 2007. SOC stocks were quantified, and the reactivity and composition measured by basal soil respiration (BSR) and solid-state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Results reveal variations in soil carbon cycling, with significant seasonal trends controlled by temperature, water content and snow. Experimental warming (OTCs) increased near-surface temperatures in the growing season, resulting in significantly higher CO₂ effluxes. Different grazing intensities had no significant effects on observed soil respiration, but BSR rates at the mesic site (13–23 µg CO₂ g soil-C⁻¹ h⁻¹) were highest with moderate grazing and lowest in the absence of grazing. A limited effect of grazing on microbial respiration is consistent with a lack of significant differences in SOC quantity and quality. NMR data show that the composition of A-horizon SOC is dominated by O-N-alkyl C and alkyl C groups, and less by carboxyl C and aromatic C groups: but again no marked variation in response to grazing was evident. It can be concluded that two years after a goose grazing experiment, SOC cycling was less than the natural variation within contrasting vegetation types.     

Apparent dynamic stability of the southeast African coast despite sea level rise

The coast of southeast Africa is dominated by sandy beaches that tend to be confined within log‐spiral or headland‐bound embayments. Investigations using serendipitous air imagery data set have been previously undertaken and conclusions drawn about the stability of the coast. We show that conclusions drawn from this data, with respect to the high water mark (HWM) position are fraught with errors, which include tidal state, pressure regime, beach slope, high‐swell erosion, seasonal and multi‐annual changes. We highlight and discuss these sources of error, together with their magnitudes. The most significant of these are the high‐swell, seasonal and multi‐annual variations. From case studies we show that the seasonal beach rotation and long‐term beach width variation are responsible for tens of metres of unaccounted HWM variation, 30 to 50 m is common, with maximums reaching 60 to 100 m. Overall the southeast African coastline appears to be in a state of long‐term dynamic equilibrium. There is no evidence of any sea‐level rise‐forced transgression in the coastal sediment budget, despite sea‐level rise (SLR). If such a signal is, in fact present, it is lost within the beach width variation. Some southeast African coastal reaches are suffering chronic erosion, but these are related to anthropogenic impacts. The extreme difficulty of placing a HWM, with any temporal validity on this coast precludes the routine use of the Bruun Rule. Although no transgressive signature is found, there is evidence of a decreasing coastal sand budget as a result of anthropogenic or natural climate change, or both. This decrease in the coastal sand volume is likely to result in increased future erosion. Copyright © 2016 John Wiley & Sons, Ltd.     

Reductive Dechlorination of PCBs Using Photocatalyzed UV Light

Feasibility of photocatalytic dechlorination of PCB‐138 and Aroclor‐1254 using platinum loaded TiO₂ (P25) in an alkaline 2‐propanol medium has been investigated. Experiments were conducted in batch mode using a Rayonet photo‐reactor under aerated and deaerated conditions with black lamps emitting around 350 nm as light source. Two forms of platinum deposition were investigated: Photochemically loaded P25 as well as addition of potassium hexachloroplatinate into the reaction medium. Partial dechlorination of PCBs was observed after 7 h of irradiation with pure TiO₂ as catalyst when the reaction vessel was kept open to air. Complete dechlorination was observed after 5 h of irradiation in a deaerated environment. Enhanced photocatalytic efficiency was observed when platinum deposited P25 was used as catalyst, with the best result being obtained when aqueous potassium hexachloroplatinate was added into the reaction medium. Lower potassium hexachloroplatinate concentration (0.1 mM) yielded better performance.     

Constraints on the nature of the subvolcanic reservoir at South Sister volcano,Oregon from U-series dating combined with sub-crystal trace-element analysis of plagioclase and zircon

We present sub-crystal-scale ²³⁸U–²³⁰Th zircon ages and ²³⁸U–²³⁰Th–²²⁶Ra plagioclase ages of bulk mineral separates from the Holocene (2.0–2.3 ka) eruptions of the Rock Mesa (RM) and Devil's Hills (DH) rhyolites at South Sister volcano, Oregon. We link these age data with sub-crystal trace-element analyses of zircon and plagioclase to provide insight into the subvolcanic system at South Sister, as an example of a small-volume continental arc volcano. Our results document the presence of coeval yet physically-distinct regions within the magma reservoir and constrain the timescales over which these heterogeneities existed. Zircons from the RM and DH dominantly record ages from 20 to 80 ka, with some grains recording ages > 350 ka, whereas plagioclase records ²³⁰Th–²²⁶Ra ages of 2.3–6.8 ka (RM) and 4.0–9.6 ka (DH-3) and a ²³⁸U–²³⁰Th age of 10 ± 34 ka (DH-3). We interpret zircons with ages < 350 ka as antecrysts inherited from a longer lived upper-crustal magma reservoir from which the rhyolites were generated, based on crystallization ages coeval with earlier periods of silicic volcanism at South Sister, the undersaturated nature of the RM and DH magmas with respect to zircon, and Ti-in-zircon temperatures consistent with low-temperature (< 815 °C) crystallization. In contrast, plagioclase ages are near the eruption age and dominantly preserve information about the recent (< 10 ka), higher-temperature evolution of the host magmas. Although zircon and plagioclase record different crystallization ages, each phase crystallized over the same time period in the RM compared to DH rhyolites. Linking these crystal age data with sub-crystal trace-element analyses demonstrates that zircon and plagioclase have distinct trace-element characteristics between eruptions, which require that the RM and DH crystals (and therefore magmas) were derived from distinct regions that had evolved independently for > 50 ka within a heterogeneous magmatic system and coexisted as physically-distinct, dominantly-liquid bodies prior to eruption. Thus, we favor a model where rhyolites are generated in independent batches by accumulation of evolved liquids in a heterogeneous, largely crystalline reservoir. Similarities in crystal age and chemical data to that at other young silicic systems (e.g., Mount St. Helens, Okataina Caldera Complex) suggest that this model may be more generally applicable to silicic magmas.     

Systematic tapping of independent magma chambers during the 1 Ma Kidnappers supereruption

The 1.0 Ma Kidnappers supereruption (~ 1200 km³ DRE) from Mangakino volcanic centre, Taupo Volcanic Zone, New Zealand, produced a large phreatomagmatic fall deposit followed by an exceptionally widespread ignimbrite. Detailed sampling and analysis of glass shards and mineral phases have been undertaken through a proximal 4.0 m section of the fall deposit, representing the first two-thirds of erupted extra-caldera material. Major and trace element chemistries of glass shards define three distinct populations (types A, B and C), which systematically change in proportion through the fall deposit and are inferred to represent three magma types. Type B glass and biotite first appear at the same level (~ 0.95 m above base) in the fall deposit suggesting later tapping of a biotite-bearing magma. Plagioclase and Fe–Ti oxide compositions show bimodal distributions, which are linked to types A and B glass compositions. Temperature and pressure (T–P) estimates from hornblende and Fe–Ti oxide equilibria from each magma type are similar and therefore the three magma bodies were adjacent, not vertically stacked, in the crust. Most hornblende model T–P estimates range from 770 to 840 °C and 90 to 170 MPa corresponding to storage depths of ~ 4.0–6.5 km. Hornblende model T–P estimates coupled with in situ trace element fingerprinting imply that the magma bodies were individually well mixed, and not stratified. Compositional gaps between the three glass compositional types imply that no mixing between these magmas occurred. We interpret these data, coupled with the systematic changes in shard compositional proportions through the fall deposit, to reflect that three independent melt-dominant bodies of magma contributed large (A, ~ 270 km³), medium (B, ~ 90 km³) and small (C, ~ 40 km³) volumes (as reflected in the fall deposits) and were systematically tapped during the eruption. We propose that the systematic evacuation of the three independent magma bodies implies that there was tectonic triggering and linkage of eruptions. Our results show that supereruptions can be generated by near simultaneous multiple eruptions from independent magma chambers rather than the evacuation of a large single unitary magma chamber.     

The DEEP2 Galaxy Redshift Survey: the role of galaxy environment in the cosmic star formation history

Using galaxy samples drawn from the Sloan Digital Sky Survey and the DEEP2 Galaxy Redshift Survey, we study the relationship between star formation and environment at   z ∼ 0.1  and 1. We estimate the total star formation rate (SFR) and specific star formation rate (sSFR) for each galaxy according to the measured [O  ii ]λ 3727 Å nebular line luminosity, corrected using empirical calibrations to match more robust SFR indicators. Echoing previous results, we find that in the local Universe star formation depends on environment such that galaxies in regions of higher overdensity, on average, have lower SFRs and longer star formation time-scales than their counterparts in lower density regions. At   z ∼ 1  , we show that the relationship between sSFR and environment mirrors that found locally. However, we discover that the relationship between total SFR and overdensity at   z ∼ 1  is inverted relative to the local relation. This observed evolution in the SFR–density relation is driven, in part, by a population of bright, blue galaxies in dense environments at   z ∼ 1  . This population, which lacks a counterpart at   z ∼ 0  , is thought to evolve into members of the red sequence from   z ∼ 1  to ∼0. Finally, we conclude that environment does not play a dominant role in the cosmic star formation history at   z < 1  : the dependence of the mean galaxy SFR on local galaxy density at constant redshift is small compared to the decline in the global SFR space density over the last 7 Gyr.     

Old Faithful model for radiolytic gas-driven cryovolcanism at Enceladus

A new model is presented on how chemically driven cryovolcanism might contribute to episodic outgassing at the icy moon Enceladus and potentially elsewhere including Europa and Kuiper Belt Objects. Exposed water ices can become oxidized from radiolytic chemical alteration of near-surface water ice by space environment irradiation. In contact with primordially abundant reductants such as NH₃, CH₄, and other hydrocarbons, the product oxidants can react exothermically to produce volatile gases driving cryovolcanism via gas-piston forces on any subsurface liquid reservoirs. Radiolytic oxidants such as H₂O₂ and O₂ can continuously accumulate deep in icy regoliths and be conveyed by rheological flows to subsurface chemical reaction zones over million-year time scales indicated by cratering ages for active regions of Enceladus and Europa. Surface blanketing with cryovolcanic plume ejecta would further accelerate regolith burial of radiolytic oxidants. Episodic heating from transient gravitational tides, radioisotope decay, impacts, or other geologic events might occasionally accelerate chemical reaction rates and ignite the exothermic release of cumulative radiolytic oxidant energy. The time history for the suggested “Old Faithful” model of radiolytic gas-driven cryovolcanism at Enceladus and elsewhere therefore consists of long periods of chemical energy accumulation punctuated by much briefer episodes of cryovolcanic activity. The most probable sequence for detection of activity in the current epoch is a long evolutionary phase of slow but continuous oxidant accumulation over billions of years followed by continuous but variable high activity over the past 10⁷-10⁸ years. Detectable cryovolcanic activity could then later decline due to near-total oxidation of the rheologically accessible ice crust and depletion the accessible reductant abundances, as may have already occurred for Europa in the more intense radiation environment of Jupiter's magnetosphere. Astrobiological potential of Enceladus could correspondingly be higher than at Europa due to a less extreme state of oxidation and greater residual abundance of organics.     

The potential impacts of sea level rise on the coastal region of New Jersey,USA

This study presents an assessment of the potential impacts of sea level rise on the New Jersey, USA coastal region. We produce two projections of sea level rise for the New Jersey coast over the next century and apply them to a digital elevation model to illustrate the extent to which coastal areas are susceptible to permanent inundation and episodic flooding due to storm events. We estimate future coastline displacement and its consequences based on direct inundation only, which provides a lower bound on total coastline displacement. The objective of this study is to illustrate methodologies that may prove useful to policy makers despite the large uncertainties inherent in analysis of local impacts of climate and sea level change. Our findings suggest that approximately 1% to 3% of the land area of New Jersey would be permanently inundated over the next century and coastal storms would temporarily flood low-lying areas up to 20 times more frequently. Thus, absent human adaptation, by 2100 New Jersey would experience substantial land loss and alteration of the coastal zone, causing widespread impacts on coastal development and ecosystems. Given the results, we identify future research needs and suggest that an important next step would be for policy makers to explore potential adaptation strategies.