Hydrogeochemical processes affecting groundwater in an irrigated land in Central Tunisia

Detailed hydrogeochemical investigation has provided new information concerning the major factors and mechanisms controlling the groundwater chemistry of Chougafiya basin. The hydrogeochemical characteristics of groundwaters comprise three main types: Cl–SO₄–Ca, Cl–SO₄–Na and Cl–Na. Hydrochemical characteristics based on the bivariate diagrams of major (Cl^?, SO₄ ^2?, NO₃ ^?, HCO₃ ^?, Na⁺, Mg²⁺, K⁺ and Ca²⁺) and some trace (Br^? and Sr²⁺) ions, mineral saturation indices and hierarchical cluster analysis indicate different origins of groundwater mineralization. The water–rock interaction (dissolution of evaporitic minerals), followed by cation exchange reactions with clay minerals, constitute the main processes that control groundwater salinization. However, the chemical composition of brackish groundwater in the central and southern parts of the study area is influenced by a mixing process with Sabkhas salt groundwater. The mixing proportions inferred from chloride mass balance prove that the contribution of Sabkhas groundwater to Quaternary aquifer ranges between 2.7 and 9.1 %. These intrusion rates reflect the progress of the saltwater–freshwater interface, which is mainly controlled by the piezometric level variation and the distance to the Sabkhas.     

Late Cretaceous calcareous nannofossil and planktonic foraminiferal bioevents of the shallow-marine carbonate platform in the Mitla Pass, west central Sinai, Egypt

The first detailed biostratigraphic analyses of the Coniacian-middle Campanian shallow-marine carbonate successions exposed in the Mitla Pass, west central Sinai, Egypt have revealed the stratigraphic distribution of diverse calcareous nannofossil and planktonic foraminiferal species. Thirty-six calcareous nannofossils and thirty-two planktonic foraminifera are identified, indicating a Coniacian to middle Campanian age and four Tethyan planktonic foraminiferal and five calcareous nannofossil zones. A comparison of these bioevents from different palaeolatitudes shows considerable variation in age.Three sequence boundaries coincident with the Turonian/Coniacian, Coniacian/Santonian and Santonian/Campanian stage boundaries are recognized. A fourth sequence boundary is marked by a major upper Campanian to early Ypresian (early Eocene) unconformity. These sequence boundaries are primarily related to regional tectonism associated with the Syrian Arc Fold System and secondarily to eustatic sea-level fluctuations.     

Deciphering interaction of regional aquifers in Southern Tunisia using hydrochemistry and isotopic tools

Groundwater is the most important source of water supply in southern Tunisia. Previous hydrogeologic and isotopic studies carried out in this region revealed the existence of two major aquifer systems: the “Complex Terminal” (CT) and the “Continental Intercalaire” (CI). Turonian carbonates constitute one of the major aquifer levels of the CT multilayered aquifer. It extends over most of southern Tunisia, and its hydrodynamic regime is largely influenced by tectonics, lithology and recharge conditions. Forty-eight groundwater samples from the CI and Turonian aquifers were collected between January and April 2004 for chemical and isotopic analyses. Hydrochemistry and isotopic tools were combined to get an insight into the processes controlling chemical composition of groundwater and wide-scale interaction of these two aquifer systems. Analysis of the dissolved constituents revealed that several processes control the observed chemical composition: (i) incongruent dissolution of carbonate minerals, (ii) dissolution of evaporitic minerals, and (iii) cation exchange. Dissolution alone cannot account for the observed high supersaturation states of groundwater with respect to calcite and dolomite. The observed supersaturation is most probably linked to geogenic CO₂ entering water-bearing horizons of the CT and CI aquifers via deep tectonic faults and discontinuities and subsequent degassing in the exploitation wells. Presence of geogenic CO₂ in the investigated region was confirmed by C isotope data of the DIC reservoir. The radiocarbon content of the Turonian samples varied between 9.5 and 43 pmc. For CI samples generally lower values were recorded, between 3.8 and 22.5 pmc. Stable isotope composition of Turonian groundwater samples varied from −8.3 to −5.3‰ for δ¹⁸O and from −60 to −25‰ for δ²H. The corresponding ranges of δ values for the Continental Intercalaire samples were from −8.9‰ to −6.9‰ for δ¹⁸O and from −68.2‰ to −45.7‰ for δ²H. Stable isotope composition of groundwater representing CT and CI aquifers provide strong evidence for regional interaction between both systems.     

Hydrochemical and isotopic study of groundwater in Wadi El Hechim–Garaa Hamra basin, Central Tunisia

Hydrochemical and isotopic study of Miocene and Mio-Plio-Quaternary (M-P-Q) aquifers in Wadi El Hechim?CGaraa Hamra basin, Central Tunisia was undertaken in order to investigate recharge mode and processes leading to mineralization of groundwater as well as interaction between both systems. The results revealed striking differences between the two aquifer systems. While the Miocene aquifer contains recently recharged waters with generally low mineralization (around 0.5?g?L^?1), stemming mainly from dissolution of carbonate minerals, the M-P-Q aquifer reveals TDS values reaching 3?g?L^?1, controlled mainly by dissolution of evaporitic minerals. Isotopic data indicate that the Miocene aquifer contains water recharged in past several decades (bomb tritium and bomb radiocarbon detected). The M-P-Q system appears to be much slower, with time scales of groundwater flow possibly reaching some thousands of years. Sharp discontinuity of hydrochemical and isotope characteristic of groundwater observed across the major tectonic fault separating the Miocene and M-P-Q aquifers supports the idea of very limited (if any) hydraulic interconnection between both studied systems. This in turn calls for revision of existing conceptual models of groundwater flow in the region postulating significant groundwater fluxes crossing the fault in the direction of M-P-Q aquifer and adjacent aquifers in the Wadi al Fakka plain.     

Application of environmental tracers to study groundwater recharge in a semi-arid area of Central Tunisia

Abstract

Groundwater of the Tertiary-Quaternary Formations in the Jeloula basin (Central Tunisia), together with rain and surface waters, were analysed to investigate the mineralization processes, the origin of the water and its recharge sources. The water samples present a large spatial variability of chemical facies which is related to their interaction with the geological formations. The main sources of the water mineralization are the dissolution of evaporitic and carbonate minerals and cation exchange reactions. Stable isotopes indicate that most groundwater samples originate from infiltration of modern precipitation. Surface water samples from small dam reservoirs show a ¹⁸O/²H enrichment, which is typical of water exposed to open-surface evaporation in a semi-arid region. Considerable data of ³H and ¹⁴C allow the qualitative identification of the present-day recharge that is probably supplied by infiltration of recent flood waters in the Wadi El Hamra valley, and by direct infiltration of meteoric water through the local carbonate outcrops.

Editor D. Koutsoyiannis; Associate editor S. Faye     

Deciphering groundwater flow between the Complex Terminal and Plio-Quaternary aquifers in Chott Gharsa plain (southwestern Tunisia) using isotopic and chemical tools

Abstract

The Complex Terminal (CT) and Plio-Quaternary (P-Q) aquifers in the Chott Gharsa plain in southwestern Tunisia have been investigated with the aid of chemical and isotopic tools. It has been demonstrated that groundwater from the CT is mainly of palaeo-origin, especially in the western and central parts of the plain where the most negative values of δ¹⁸O and δ²H were observed (between??8.1 and??7.6‰ for δ¹⁸O, and??60 to??57‰ for δ²H), combined with low concentrations of radiocarbon (6.8–7.5 pmc) and absence of tritium. Modern recharge of the aquifer occurs only in the eastern part of the system where younger waters were observed, as indicated by their stable isotope composition, relatively high radiocarbon content and presence of tritium. Groundwater from the P-Q multi-layer aquifer represents mixtures of ascending deep CT waters and modern water recharging the P-Q aquifer system. Isotope mass balance was used to quantify mixing proportions. The calculations showed that the contribution of deep CT groundwater to the P-Q aquifer system reaches about 75% in the western and central parts of the plain where the CT aquifer remains strongly artesian. This contribution decreases to about 15% towards the eastern part of the plain, as a consequence of significant reduction of artesian pressure in this area of the CT aquifer. Chemical data suggest that mineralization of the studied groundwater systems is controlled mainly by dissolution of evaporative minerals (halite, anhydrite and gypsum) and cation exchange reactions with the matrix, possibly enhanced by recent anthropogenic disturbance of the system caused by lowering of the water table due to heavy exploitation and return flow of saline irrigation water into the P-Q aquifer.

Editor D. Koutsoyiannis; Associate editor E. Custodio

Citation Yangui, H., Abidi, I., Zouari, K., and Rozanski, K., 2012. Deciphering groundwater flow between the Complex Terminal and Plio-Quaternary aquifers in Chott Gharsa plain (southwestern Tunisia) using isotopic and chemical tools. Hydrological Sciences Journal, 57 (5), 967–984.     

Marine Sr (Ca) input in Quaternary volcanic rock weathering profiles from the Mediterranean coast of Morocco: Sr isotopic approach

Carbonate commonly accumulates in weathering profiles developed on noncalcareous parent material under arid and semiarid climatic conditions. Such weathering profile types are widespread in Morocco, making it critical to know the sources of the calcium in order to understand the genesis of carbonate-rich soils. In this study, we use ⁸⁷Sr/⁸⁶Sr as a geochemical tracer of the Ca sources in weathering profiles developed on volcanic rocks (basalt, tuff, andesite and latite) in the Mediterranean coast of Morocco. The results show that the most of the Sr, and hence Ca, is of an external origin, derived from (i) sea-water for the profiles located near to the coast or (ii) sea-water plus Liassic carbonate outcropping in the catchment for the profiles more distant from the coastline. The contribution of the host rock is small, being less than 25%. The ratio of the Sr (Ca) from the parent material to that from the external sources is controlled by the degree of porosity developed in the profile.     

Integrated planktonic stratigraphy and paleoenvironments of the Lower-Middle Miocene successions in the central and southern parts of the Gulf of Suez,Egypt

Lower to Middle Miocene successions in three offshore wells named GS 160-2, QQ-89, and Ras Elush-2 located in the central and southern parts of the Gulf of Suez were examined for their planktonic foraminifera, calcareous nannofossil assemblages, and paleoenvironments. These successions are subdivided from older to younger into Aquitanian Nukhul, Burdigalian-Langhian Rudeis, Langhian Kareem, and Serravallian Belayim formations. The identified foraminifera includes 54 benthic species belonging to 25 genera and 47 planktonic species belonging to 11 genera, in addition to 64 calcareous nannofossil species belonging to 21 genera. The stratigraphic distribution of these assemblages suggests classifying the studied successions into seven planktonic foraminiferal and six calcareous nannoplankton biozones. The planktonic foraminiferal and calcareous nannoplankton biozones are integrated. Different environments ranging from shallow inner to outer shelf are recognized. This is based on quantitative analyses of foraminifera including benthic biofacies, planktonic/benthonic ratio, and diversity. Syn-rift tectonics played an important role in configuration of the Miocene depositional history in the Gulf of Suez region.     

Weakly nonlinear dust ion- acoustic double- layers in a dusty plasma with nonextensive electrons

Weak dust ion-acoustic (DIA) double- layers (DLs) in a dusty plasma with nonextensive electrons are addressed. A generalized Korteweg-de Vries equation with a cubic nonlinearity is derived. It is shown that under certain conditions, the effect of electron nonextensivity can be quite important. In particular, it may be noted that due to the net negative dust charge and electron nonextensivity, the present dusty plasma model may admit compressive as well as rarefactive weak DIA-DLS. Considering the wide relevance of nonlinear oscillations in space dusty plasmas, our investigation may be taken as a prerequisite for the understanding of the nonlinear structures observed in the ionosphere and the auroral acceleration regions.     

Rotational excitation of aluminium monofluoride (AlF) by?He?atom at low temperature

We report on the calculation of collision induced rotational excitation cross sections and rate coefficients of AlF by He atom at low temperature. These quantities were obtained by first computing the interaction potential energy surface (PES) of the AlF(X  ¹Σ⁺)-He(¹ S) van der Waals complex at the ab initio Coupled Cluster with Single and Double and perturbative Triple excitations [CCSD(T)] level of theory. The aug-cc-pVQZ Gaussian basis, to which was added a set of bond functions, was used for that purpose. The calculations account for basis set superposition errors (BSSE). The interaction potential presents a minimum of ∼24 cm⁻¹ below the AlF-He dissociation limit. The PES was fitted on a basis of Legendre polynomial functions to allow for the calculation of cross sections in the close-coupling (CC) approach. By averaging these cross sections over a Maxwell-Boltzmann velocity distribution, rate coefficients were inferred at low temperatures (T≤300 K). From our computations, a propensity towards ΔJ=1 transitions is observed.