The hydro geochemical characterization of ground waters in Tunisian Chott’s region.

Tunisian Chott’s region is one of the most productive artesian basins in Tunisia. It is located in the southwestern part of the country, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. The system is composed of an upper unconfined “Plio-Quaternary” aquifer with a varying thickness of 20–200 m, an intermediate confined/unconfined “Complex Terminal” aquifer about 100 m in thickness and a deeper “Continental Intercalaire” aquifer about 150 m in thickness separated by thick clay and marl layers. The dissolution of evaporites and carbonates explains part of the contained Na⁺, Ca²⁺, Mg²⁺, K⁺, SO₄²⁻ and Cl^-, but other processes, such carbonate precipitation, also contributes to the water composition. The stable isotope composition of waters establishes that the deep groundwater (depleted as compared to present corresponding local rainfall) is ancient water recharged probably during the late Pleistocene and the early Holocene periods. The relatively recent water in the Plio-Quaternary aquifer is composed of mixed waters resulting presumably from upward leakage from the deeper groundwater.     

Early Eocene orthophragminids and alveolinids from the Jafnayn Formation,N Oman: significance of Nemkovella stockari Less & Özcan, 2007 in Tethys

The upper member of the Jafnayn Formation in Wadi Rusayl and Al Khoud, Seeb Area in north Oman contains Nemkovella stockari Less & Özcan, 2007, an Early Eocene orthophragminid recorded here for the first time from the Arabian Peninsula. N. stockari, the only orthophragminid identified in Jafnayn Formation, is quite distinct from any other species from Tethys in having spiral and orbitoidiform chambers around the isolepidine embryon developed before the onset of annular chambers. The Oman specimens exhibit equal-sized principal auxiliary chambers and symmetrical spirals and are assigned to N. stockari bejaensis Özcan, Boukhalfa & Scheibner, 2014, an advanced form of the N. stockari lineage. The associated alveolinids, revised in this study, rotaliids and other age-diagnostic foraminiferal taxa in the transgressive basal part of the upper member have enabled us to revise the age as middle Ilerdian (Early Eocene), assignable to SBZ 7/8 and 8; OZ 3/4. Integrating a new record of this species from Arabian Plate margin in Belen, S Turkey, and previous records from north Africa, N. stockari appears to be a diagnostic marker for the Early Eocene along the southern peri-Tethys platforms, facilitating the Tethyan correlation by orthophragminids. The palaeobiogeographic distribution of N. stockari is discussed.     

Seismic damage to segmented buried pipelines

Seismic damage to segmented buried pipelines is investigated in this paper. Information on their performance during past earthquakes is reviewed briefly. An analytical model for evaluating the response of long straight runs of segmented buried pipelines to seismic wave propagation is presented. It takes into account the non-linearity as well as the variability of the system characteristics. Also, results from laboratory tests by others are used to establish the relative joint displacement which leads to leakage. These two elements are combined to predict the damage ratio (number of leaks per kilometre) for cast iron pipes with lead caulked joints subject to a joint pull-out failure mode.     

Analysis of continuous buried pipelines for seismic wave effects

An analysis procedure for seismic wave propagation effects on straight continuous buried pipelines is proposed. It shown that ground strain due to surface waves can be substantially larger than that due to body waves. An elastic model a buried pipeline surrounded by equivalent soil springs indicates that frictional slip between the pipeline and the surrounding soil springs is likely for high ground strains. A method for estimating ground strain due to surface waves, based on data from the 1971 San Fernando earthquake, reviewed. An analysis procedure, which utilizes frictional forces near the soil-pipeline interface, is proposed for surfae wave effects on straight buried continuous pipelines. The proposed procedure is illustrated with an example.     

Use of Tunisian raw clay to remove dye from aqueous solution

This paper presents the first attempt to investigate the potential of Tunisian palygorskite-rich clay (Pal-clay) on the effectiveness of a textile dye “Direct orange 34” (DO34) removal. Important parameters which affect adsorption, such as initial solution pH, contact time, adsorbent mass, initial dye concentration, and temperature, were investigated. The raw Pal-clay was characterized using X-ray diffractometer (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), cation exchange capacity (CEC), specific surface area (SSA) analysis, and point of zero charge (PZC) determination. The results showed that the Pal-clay has a high selectivity for DO34 and had maximum removal efficiency reaching up to about 91 %. The highest adsorption capacity was obtained at 25 °C and pH of 2. The dye uptake process fitted well to the pseudo-second-order kinetic expression and was best described by the Langmuir and Freundlich isotherms. Intra-particle diffusion studies showed that the adsorption mechanism was not exclusively controlled by the diffusion step and was more likely to be governed by external mass transfer. Thermodynamic parameters such as change in free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were also calculated. The parameters revealed that the adsorption of dye by the raw clay is spontaneous and exothermic. The results indicate that the Pal-clay has a moderate adsorption capacity towards anionic dye.     

Study the feasibility of using PPP for establishing CORS network

Nowadays many continuously operating reference stations (CORS) network were established in Middle East to improve the surveying tasks. Establishing such geodetic control networks can be a costly business where multiple stations should be occupied simultaneously and post-processed with scientific software. Recently, precise point positioning (PPP) provides precise positioning values that may be an alternative to precise relative processing. The current research aims to investigate that PPP has a potential as a reliable absolute positioning technique operational simplicity as well as to investigate the capability of PPP approach to be a low cost alternative to the conventional positioning methods used in position determination of core networks stations. In comparison with common relative GPS techniques, the costs are reduced; because no base stations and no simultaneous observations are necessary, no need for control network maintenance which could be the most defective factors that Egypt HARN network suffered from. To see the feasibility study of using PPP for precise determination of the CORS, 14 days of GNSS data for the 14 Kuwait integrated with 27 IGS stations were processed by Bernese software to calculate the precise coordinates of Kuwaiti CORS network in the latest terrestrial geodetic frame. Three days of these data were processed by Trimble business center software and using PPP approach to calculate the precise coordinates of Kuwait network. In the current research, a comparable investigation was carried out between the coordinates obtained from Bernese software, Trimble business center, and PPP approach. The comparison proved high level of agreement between the coordinates which confirm that PPP approach can be applied for establishment of CORS network.     

Silver and silver-bearing minerals at the Um Samiuki volcanogenic massive sulphide deposit, Eastern Desert, Egypt

The Um Samiuki Zn–Cu–Pb–Ag mineralisation, south Eastern Desert, Egypt is hosted by felsic volcanic rocks which form part of the 712-Ma-old, east-west-trending Shadli Volcanic Belt. Two major occurrences of massive sulphides are present at the top of rhyolitic breccia in the Western and Eastern mine areas. In each occurrence, a bornite-bearing zone is overlain by a pyrite-chalcopyrite-bearing zone and underlain by a disseminated, Cu-depleted zone. In the massive sulphide ore, sphalerite, chalcopyrite, pyrite, galena, bornite and tetrahedrite–tennantite are major minerals, whereas arsenopyrite, pyrrhotite, molybdenite and magnetite are accessory phases. Covellite and digenite are common secondary minerals. Bornite, tetrahedrite–tennantite and covellite contain high amounts of silver (averages of 1.97, 1.39 and 1.82 wt% respectively). Based on mineralogical balance calculations, bornite and covellite accommodate 80% of silver in the Um Samiuki deposit. Ag was incorporated in the crystal structure of the early-crystallised copper sulphides and sulphosalts and silver minerals. The temperature, sequential precipitation of the fluids and the structure of the crystallising phases control the distribution of silver. Post-depositional deformation and metamorphic processes caused liberation, remobilisation and redeposition of silver within the massive sulphides.Editorial handling: D. Lentz     

Regional fracture analysis south Latitude 29° N of Egypt and their influence on earthquakes

Egypt had been subjected to earthquakes of various degrees but earthquake observation in this country started only in 1899. Earthquakes were found in the locations where fractures have relatives high densities.The Fracture pattern of Egypt south Latitude at 29° N was studied regionally based on Landsat images and aerial photomosaics. Fractures in the Eastern Desert have the prominent trends, NW, EW, NNW and ENE, showing high density in the northern and southern parts. These fractures control the distribution of mineral deposits and radioactivity in the basement rocks.Fractures in Western Desert are less remarkable with the main trend NNW, E-W, N-S and NW, showing high density in the central part. The NNW trending fractures have the same direction of sand dunes which cover larger areas in the northwestern part of Western Desert.Based on the geographical distribution of earthquakes in the seismic maps and centers of high fractures density on the structural contour maps, the area south of latitude 29° N of Egypt was divided into three regions: The Red Sea, Western Desert and Aswan Environs. This correlation led to the conclusion that the fractures have an effect on earthquake activity, are trending ENE and WNW in the Red Sea, NW and N-S in the Western Desert and E-W and NNW in Aswan Environs.It should be emphasized that fractures with higher density are more susceptible to earthquakes in the locations characterized by two dominant sets of fractures especially at their intersections.     

Effect of Water and Leachate on Hydraulic Behavior of Compacted Bentonite,Calcareous Sand and Tuff Mixtures for Use as Landfill Liners

Compacted soil–bentonite liners, consisting of a sandy soil mixed with bentonite as backfill, are used extensively as engineered barriers for contaminant containment. This paper studies the valorization of local materials containing calcareous sand, tuff obtained from Laghouat region (in the South Algeria), to associate with bentonite in order to improve their hydraulic characteristics for use as landfill liner material. Firstly, a geotechnical characterization of mixtures chooses from a fixed percentage to 10% bentonite and different percentages of calcareous sand and tuff so that they are complementary to 90% by not 10%. Thereafter, the determination of saturated hydraulic conductivity at falling-head permeability (K_v) and oedometer (K_id, indirect Measure) tests of all compacted mixtures at Optimum Normal Proctor have been carried out using both permeates by tap water and a landfill leachate in order to simulate long-term conditions. The results showed that the saturated hydraulic conductivity of tap water is relatively lower than the one saturated by leachate in the falling-head test, unlike the oedometer test. The B₁₀CS₂₀T₇₀ mixture has satisfied the hydraulic conductivity criterion of bottom barriers (i.e. water permeated: k_v20° = 1.97 × 10^?9 and k_id from 7 × 10^?9 to 1.83 × 10^?10 < 10^?9m/s; leachate permeated: k_v20° = 2.91 × 10^?9 and k_id from 7 × 10^?9 at 1.44 × 10^?10 < 10^?9 m/s). Finally, a comparison between direct measurements of the saturated hydraulic conductivity by triaxial (K_d) test and oedometer test (K_id) in the range of effective stress applied 100–800 kPa led to propose equations of correlations between these two methods. In conclusion, adopted formulation B₁₀CS₂₀T₇₀ perfectly meets the regulatory requirements in force and constitutes an economic product based on available local materials for engineers barriers.     

Intelligent methods for predicting nuclear magnetic resonance of porosity and permeability by conventional well-logs: a case study of Saharan field

In the well-log data processing, the principal advantage of the nuclear magnetic resonance (NMR) method is the measurement of fluid volume and pore size distribution without resorting to parameters such as rock resistivity. Preliminary processing of the well-log data allowed first to have the petrophysical parameters and then to evaluate the performances of the transverse relaxation time T ₂ NMR. Petrophysical parameters such as the porosity of the formation as well as the effective permeability can be estimated without having recourse the fluid type. The well-log data of five wells were completed during the construction of intelligent models in the Saharan oil field Oued Mya Basin in order to assess the reliability of the developed models. Data processing of NMR combined with conventional well data was performed by artificial intelligence. First, the support vector regression method was applied to a sandy clay reservoir with a model based on the prediction of porosity and permeability. NMR parameters estimated using intelligent systems, i.e., fuzzy logic (FL) model, back propagation neural network (BP-NN), and support vector machine, with conventional well-log data are combined with those of NMR, resulting in a good estimation of porosity and permeability. The results obtained during the processing are then compared to the FL and NN regression models performed by the regression method during the validation stage. They show that the correlation coefficients R ² estimated vary between 0.959 and 0.964, corresponding to the root mean square error values of 0.20 and 0.15.